2017 Fiscal Year Final Research Report
Synthesis of pi-conjugated cmopounds based on heteroaromatics such as carbazole and their application to host molecules
| Project/Area Number |
15K05415
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Gunma University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
加藤 真一郎 滋賀県立大学, 工学部, 准教授 (70586792)
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Keywords | ヘテロ環 / カルバゾール / シクロファン / ホスト / 大環状化合物 / 錯形成 / 光物性 / ドナー |
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| Outline of Final Research Achievements |
Acyclic host compounds (molecular receptors) possessing ethynylcarbazole moieties at 1,8-positions of carbazole were systematically synthesized, and the complexation behavior with some acceptors was investigated. Conjugated macrocycles composed of carbazole and triazole or triazolium moieties were successfully synthesized by click reactions, and their self-association and complexation with anions such as iodide ion were clarified. Cyclophanes bearing carbazole or dibenzofuran bridged by disiloxane or disilane linkages were synthesized, and their structure-property relationship was disclosed.
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| Free Research Field |
構造有機化学
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