Development of Catalytic Reactions using sigma Electron Acceptor Ligand

2017 Fiscal Year Final Research Report

• Project/Area Number: 15K05458
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Inorganic chemistry
• Research Institution: Osaka Prefecture University
• Principal Investigator: Kameo Hajime 大阪府立大学, 理学(系)研究科(研究院), 准教授 (50597218)
• Research Collaborator: NAKAZAWA Hiroshi ; SAKAKI Shigeyoshi ; BOURISSOU Didier
• Project Period (FY): 2015-04-01 – 2018-03-31
• Keywords: 無機化学 / 錯体化学 / 有機金属化学 / σ電子受容性配位子 / シラン / ボラン / フッ素 / 結合切断

Outline of Final Research Achievements

Main purpose of this research project is to gain deep understanding of properties and functions concerning σ electron acceptor (Z-type) ligands. Three important results are described here. (1) Roles of Z-type (Pt→B) interaction in B-F bond activation of BF3 were revealed. (2) E-F (E = Si, Ge, Sn) bond activation was achieved by forming Z-type interaction. (3) E-F bond cleavage reactions were expanded to catalytic reactions. These findings may provide a novel strategy for the synthesis of heavier Group 14 compounds.

Free Research Field

無機化学