2017 Fiscal Year Final Research Report
Construction of Library of Molecular Arrangements Consisting of Tetracene Derivatives having Substituents and Investigation of their Optical Properties
| Project/Area Number |
15K05482
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional solid state chemistry
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| Research Institution | The University of Shiga Prefecture |
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Principal Investigator |
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Keywords | 光物性 / 芳香族炭化水素 / 構造物性相関 |
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| Outline of Final Research Achievements |
To clarify the mechanism between the molecular arrangement and the solid-state optical properties, molecular libraries consisting of diesteretetracene (having ester groups on outside benzene ring) and dialkynyltetracene (having alkynyl groups on inside benzene ring). The former of which contained propyl and butyl ester groups. In the latter of which, the carbon number was ranging from 5 to 10. Absorption spectra in the solid state and X-ray crystallographic analysis were researched. From the X-ray analysis of dialkylnyltetracenes, it was revealed that the molecules with smaller carbon number took more effective pi-overlap in the crystal.
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| Free Research Field |
化学
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