2017 Fiscal Year Final Research Report
Utilizing carbonated water for catalytic reaction systems and the elucidation of role of proton
| Project/Area Number |
15K05579
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Green/Environmental chemistry
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| Research Institution | Iwate University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
七尾 英孝 岩手大学, 理工学部, 准教授 (50312509)
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Keywords | 炭酸水 / 高温水 / 高圧二酸化炭素 / プロトン / 酸触媒 |
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| Outline of Final Research Achievements |
The effect of carbonated water to homogeneous reaction systems and heterogeneous hydrogenations using supported metal catalysts were studied. We found that (1) the dehydration of erythritol to 1, 4-unhydroerythritol proceeded in high-temperature carbonated water, (2) benzyl methyl ether was produced in aqueous methanol solution under high-pressured carbon dioxide, and (3) hydrogenation of furfuryl alcohol and furfural proceeded over Pd/C in water solvent and the initial reaction rates were enhanced by the addition of carbon dioxide and the rates were increased with an increase in carbon dioxide pressure.
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| Free Research Field |
触媒化学
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