2017 Fiscal Year Final Research Report
Preparation of high efficient luminescence materials using multi-coordination complex structures
| Project/Area Number |
15K05611
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic and hybrid materials
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| Research Institution | Kyushu Institute of Technology |
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Principal Investigator |
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Keywords | 金属錯体 / 縮環芳香族 / 配位子 / 電気伝導性 / 蛍光 |
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| Outline of Final Research Achievements |
Many ligands carrying fused aromatics such as naphthalene anthracene, pyrene, perylene, etc. can be synthesized using condensation reaction. And, the desired complexes were successfully obtained by complexation of the ligands with 3d or 4f ions in good yields.
Structures of the complexes were determined using single crystal structure analyses. The ligand units in the complexes were oriented by bulkiness of the ligands. And it is also affected by intramolecular weak interaction such as CH-pai interaction. Further, in conc. solution only monomer emission was observed. But in crystal or solid state, eximer emission was observed due to intermolecular interaction such as pai-pai interaction.
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| Free Research Field |
有機化学
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