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2017 Fiscal Year Final Research Report

Development of self-cleaning pH electrodes and disposable pH electrodes

Research Project

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Project/Area Number 15K06439
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionMie University

Principal Investigator

Hashimoto Tadanori  三重大学, 工学研究科, 准教授 (10271016)

Co-Investigator(Kenkyū-buntansha) 那須 弘行  三重大学, 工学研究科, 准教授 (20189179)
石原 篤  三重大学, 工学研究科, 教授 (60212908)
Project Period (FY) 2015-04-01 – 2018-03-31
KeywordspH応答ガラス / セルフクリーニング機能 / メンテナンスフリー / 撥水性 / 電子伝導ガラス / ゾル-ゲルコーティング / ステンレス電極 / ディスポーザブル電極
Outline of Final Research Achievements

Commercially available pH electrodes have fatal problem that pH response is deteriorated by the accumulation of stain easily. In order to solve this problem, we developed two types of maintenance-free pH responsive electrodes which guarantees pH response performance by maintaining a clean state. Such pH electrodes cannot be realized with commercially available pH-responsive glass electrode. As for the development of a Li-free electronically conductive glass electrode having a self-cleaning function based on anti-fouling property (hydrophobicity), we developed Fe2O3-Bi2O3-GeO2 glasses with higher contact angle with water compared with the previously reported Fe2O3-Bi2O3-B2O3 glasses. In addition, the stainless electrode sol-gel coated with transition metal oxide showed high pH sensitivity and fast pH response. This stainless electrodes with excellent processability are candidate for a disposable pH electrode.

Free Research Field

工学

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Published: 2019-03-29  

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