Synthesis of boron-containing organic materials by novel nucleophilic borylation

2016 Fiscal Year Final Research Report

• Project/Area Number: 15K13633
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Multi-year Fund
• Research Field: Organic chemistry
• Research Institution: Hokkaido University
• Principal Investigator: ITO Hajime 北海道大学, 工学研究院, 教授 (90282300)
• Project Period (FY): 2015-04-01 – 2017-03-31
• Keywords: シリルボラン / ホウ素化 / ケイ素化

Outline of Final Research Achievements

Organoboron compounds are vital synthetic intermediates for many organic transformations such as Suzuki coupling. Organoboron compounds are also important for organic materials. The researcher previously developed silyl boron/base reaction system for their efficient synthesis. In this research, the reaction has been expanded by the mechanistic insight obtained by calculation studies. New synthetic procedures for hetero-aromatic organoboron compounds, functionalized organoboron compounds, triaryl boron compounds have been developed.

Free Research Field

有機合成化学