2016 Fiscal Year Final Research Report
Exploitation of porphyrinoids for secondary batteries
| Project/Area Number |
15K13639
|
|---|
| Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Organic chemistry
|
|---|
| Research Institution | Nagoya University |
|---|
Principal Investigator |
|
|---|
| Project Period (FY) |
2015-04-01 – 2017-03-31
|
| Keywords | ポルフィリン / 二次電子 / 蓄電池 / 酸化還元 / 反芳香族 / 活物質 / π電子化合物 |
|---|
| Outline of Final Research Achievements |
We have attempted to control the redox property of antiaromatic norcorrole derivatives by introducing a variety of substituents. Introduction of two electron-donating aryl groups or electron-withdrawing aryl groups significantly destabilized norcorroles. However, installation of both electron-donating and electron-withdrawing aryl groups allowed isolation of novel norcorrole derivatives as stable compounds. We have also elucidated redox properties of norcorrole derivatives, which were substantially influenced by the introduced substituents.
|
| Free Research Field |
有機化学
|
