2016 Fiscal Year Final Research Report
Creation of Efficient NIR Emission compounds based on confused cyclic oligomer
| Project/Area Number |
15K13646
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Kyushu University |
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Principal Investigator |
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| Project Period (FY) |
2015-04-01 – 2017-03-31
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| Keywords | 近赤外色素 / BODIPY / 環状体 / 多量体 / 混乱結合 / ナノリング / ストークスシフト / 発光 |
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| Outline of Final Research Achievements |
In this research, a new strategy "Cyclic oligomerization method" for the construction of functional molecules applicable for the NIR laser dyes and bio-imaging probes was proposed and its effectiveness was demonstrated.
Complexation of novel multiply N-confused expanded calix[n]phyrins with boron difluoride afforded a new class of cyclic BODIPY (boron-dipyrromethene) arrays. The structures of circularly-arranged BODIPY subunits linked in an N-confused fashion give rise to such photophysical properties unique to the macrocycles as redshifted emission wavelengths along with apparent large Stokes shifts, long emission lifetimes and solid-state lasing. The DFT calculations support the size-dependent excited-state dynamics of the macrocycles.
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| Free Research Field |
有機機能分子化学
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