Synthesis and functionality of hydride-based coordination framework

2016 Fiscal Year Final Research Report

• Project/Area Number: 15K13657
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Multi-year Fund
• Research Field: Inorganic chemistry
• Research Institution: Kyoto University
• Principal Investigator: HORIKE SATOSHI 京都大学, 物質－細胞統合システム拠点, 准教授 (70552652)
• Project Period (FY): 2015-04-01 – 2017-03-31
• Keywords: 配位高分子 / X線回折 / ヒドリド / ガス吸着

Outline of Final Research Achievements

Anion form of hydrogen atom is hydride (H-) and H- is widely used as a reductant agent for organic reaction. They are used in liquid state, whereas the control of reactivity and mobility of H- in solid state is a challenge. We incorporated H- species in solid state by use of coordination polymer crystal composed of metal ions and bridging ligands. Optimized synthetic condition of coordination polymer enabled to accommodate H- with different reactivity, and some materials showed high reductant activity for CO2 and other small gases in solid state.

Free Research Field

錯体化学