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2017 Fiscal Year Final Research Report

Linear Acene Proton Conductors for Molecular Protonics

Research Project

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Project/Area Number 15K13684
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Functional solid state chemistry
Research InstitutionNational Institute for Materials Science

Principal Investigator

HILL Jonathan  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 主席研究員 (30421431)

Co-Investigator(Renkei-kenkyūsha) Labuta Jan  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 独立研究者 (00720690)
Matsushita Yoshitaka  国立研究開発法人物質・材料研究機構, 技術開発・共用部門 材料分析ステーション 化学分析・X線回折グループ, グループリーダー (70422441)
Wakayama Yutaka  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点 量子デバイス工学グループ, グループリーダー (00354332)
Project Period (FY) 2015-04-01 – 2018-03-31
KeywordsAcene / Proton conductor / Pyrazinacene
Outline of Final Research Achievements

A class of linear acenes containing up to 14 nitrogen atoms has been prepared. These are the longest ‘pyrazinacene’ compounds prepared to date. The compounds have been characterized by chemical methods and crystallography. If compounds contained reduced rings (i.e. have hydrogen atoms) they were found to be delocalized, as predicted. Several compounds were studied for self-assembly on surfaces and were found to form polymeric structures. Some of the compounds were found to be useful for solar cell applications. The compounds were also found to be highly useful as organic catalysts based on the presence of the exchangeable protons and photosensitivity, as discovered in this work.

Free Research Field

化学

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Published: 2019-03-29   Modified: 2019-05-15  

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