2016 Fiscal Year Final Research Report
Development of carbon dioxide fixation methods by using heterogeneous and homogeneous catalysts
| Project/Area Number |
15K13755
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Green/Environmental chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Project Period (FY) |
2015-04-01 – 2017-03-31
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| Keywords | 二酸化炭素 / 均一系触媒 / 不均一系触媒 / コバルト / マグネシウム |
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| Outline of Final Research Achievements |
Transformation that regenerates carbon dioxide into organic resources is one of important research subjects. In this research, we have studied aiming at the development of a catalyst system driven by light energy. We developed cobalt and nickel catalyzed carboxylation reaction of alkenyl and aryl triflates using carbon dioxide. We also found that magnesium chloride, which is inexpensive and easily available, is a useful catalyst for the synthesis of cyclic carbonate from epoxide and carbon dioxide.
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| Free Research Field |
有機金属化学
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