2017 Fiscal Year Final Research Report
Design and synthesis of concerted supported molecular catalysts by precise living polymerization
| Project/Area Number |
15K14225
|
|---|
| Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Catalyst/Resource chemical process
|
|---|
| Research Institution | Tokyo Metropolitan University |
|---|
Principal Investigator |
|
|---|
| Project Period (FY) |
2015-04-01 – 2018-03-31
|
| Keywords | 触媒設計 / 精密重合 / 遷移金属錯体触媒 / 環境調和型合成法 / 固定化分子触媒 / リビング重合 |
|---|
| Outline of Final Research Achievements |
The project concern design of concerted reaction sphere by placement of different functionalities on the surface of star-shaped polymers prepared by the living polymerization technique. We have succeeded in controlled synthesis of star-shaped polymers with more arms (branching) and the exclusive end modification under optimized conditions by adopting living ring-opening metathesis polymerization using molybdenum-alkylidene catalyst. The method enables us introduction of different ligand precursors on the star surface as well as synthesis of functional materials by intra-molecular interaction with two different functionalities on the surface.
|
| Free Research Field |
触媒化学・合成化学
|
