2017 Fiscal Year Final Research Report
Multistep switchable materials based on the assembly of photofunctional metal complexes
| Project/Area Number |
15K17827
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Hokkaido University |
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Principal Investigator |
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| Research Collaborator |
KATO Masako
KOBAYASHI Atsushi
SHITAMA Hotaka
NAKAJIMA Airi
SAMEERA W. M. C.
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Keywords | 錯体化学 / 光物性 |
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| Outline of Final Research Achievements |
In this work, we tried to investigate the development of stimuli-responsive materials driven by the self-assembly/dissociation of photofunctional Pt(II) complexes. As a result, we have discovered (i) the multistep electrochromic material based on the self-assembled mixed-valent platinum complex by the introduction of hydrogen bonds, and (ii) the post-synthetically color-tunable electrochromic material based on the coordination/dissociation of guest molecules on the redox-bistable mixed-valent platinum complex. These results provide the new strategy to construct multifunctional electronic devices based on the self-assembly of Pt(II) complexes.
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| Free Research Field |
錯体化学
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