2017 Fiscal Year Final Research Report
Development of photo-functional polyhedron-shaped supramolecular complexes and applied them as the high efficient hydrogen evolution catalysts
| Project/Area Number |
15K17897
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Energy-related chemistry
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| Research Institution | Shimane University |
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Principal Investigator |
KATAOKA Yusuke 島根大学, 総合理工学研究科, 助教 (20725543)
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| Research Collaborator |
HANDA Makoto
YANO Natsumi
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Keywords | 水素発生 / 金属錯体 / 超分子錯体 / 量子化学計算 |
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| Outline of Final Research Achievements |
In this project, the polyhedron-shape metal complexes with paddlewheel-type dirhodium nodes as a building block have developed and applied as a hydrogen evolution catalyst (HEC) for photochemical water reduction. Molecular structures of their complexes were determined by the single crystal X-ray diffraction analyses. These complexes evolved molecular hydrogen in the presence of cyclometalated iridium complex and triethylamone, which were worked as a photosensitizer and a reducing agent, respectively.
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| Free Research Field |
錯体化学
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