2017 Fiscal Year Final Research Report
Rational aggregation of thiolato metal clusters using structural deficiency
| Project/Area Number |
15K21127
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
Nanostructural chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
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| Research Collaborator |
KONNO Takumi 大阪大学, 大学院理学研究科, 教授
IGASHIRA Asako 明治学院大学, 法学部, 准教授
KUWAMURA Naoto 大阪大学, 大学院理学研究科, 助教
KAWANO Masaki 東京工業大学, 理学院, 教授
KOJIMA Tatsuhiro 大阪大学, 大学院理学研究科, 助教
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Keywords | 金属多核錯体 / 構造変換 / 熱分解 / 金属引き抜き反応 / キラリティ / 含硫アミノ酸 / 結晶構造 |
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| Outline of Final Research Achievements |
In this research project, new synthetic methodology for the structural conversion from stable coordination compounds that involve saturated atoms to reactive products that contain unsaturated atoms was developed using multinuclear metal complexes. As a result, a thermal-induced ligand-dissociation reaction on a luminescent digold(I) complex ([Au2(dppm)3]2+) and a ligand-induced rhodium atom abstraction reaction on an octanuclear complex cation ([Rh4Zn4(aet)12O]6+) were achieved.
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| Free Research Field |
錯体化学、超分子化学
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