2016 Fiscal Year Final Research Report
Synthesis and characterization of highly fused compounds based on C3 symmetrical triarylbenzene
| Project/Area Number |
15K21343
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
Functional solid state chemistry
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| Research Institution | Chiba Institute of Technology |
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Principal Investigator |
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| Project Period (FY) |
2015-04-01 – 2017-03-31
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| Keywords | 有機合成化学 / 構造有機化学 / 機能物質化学 / 光物性 / 酸化還元特性 / 星型構造 / 低分子量ゲル化剤 |
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| Outline of Final Research Achievements |
An acyl group is introduced to an aromatic compound by a Friedel-Crafts reaction, followed by reductive trimerization reaction of acyl groups with a Lewis acid or protonic acid catalyst was afforded star-shaped 1,3,5-triarylbenzenes in good yield. The photophysical and electrochemical properties of triarylbenzenes were investigated by UV-vis and fluorescent and CV.
Moreover, we found that the 1,3,5-trischolesteryloxycarbonylbenzene was displayed higher gelation ability in comparison with 1,3- and 1,4-bis analogues even though it has no hydrogen bonding moiety.
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| Free Research Field |
構造有機化学
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