2018 Fiscal Year Final Research Report
Development of Rationally Designed Multimetallic Catalysts
| Project/Area Number |
15KT0059
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Multi-year Fund |
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| Section | 特設分野 |
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| Research Field |
Transition State Control
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
Takaya Jun 東京工業大学, 理学院, 准教授 (60401535)
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| Project Period (FY) |
2015-07-10 – 2019-03-31
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| Keywords | 有機合成化学 |
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| Outline of Final Research Achievements |
We have rationally designed and synthesized multimetallic complexes having a metal-metal bond. We also demonstrated these complexes can catalyze efficient reactions of unreactive molecules such as carbon dioxide and clarified their unique catalysis through theoretical calculations.
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| Free Research Field |
有機合成化学
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| Academic Significance and Societal Importance of the Research Achievements |
本研究によって，高周期14族・13族元素を配位子とする異種二核遷移金属錯体の合成法を確立し，二酸化炭素などの不活性分子変換反応におけるそれらの触媒機能を明らかにした。これらの結果は，金属錯体触媒の新しい分子設計を確立し，次世代の物質合成法開発の嚆矢となる効率的分子変換反応を実現したものであり，遷移状態制御による反応開発の有用性を実証したものとして意義深い。
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