2017 Fiscal Year Final Research Report
Transition state analysis of [2+2] cycloaddition-retroelectrocyclization
| Project/Area Number |
15KT0140
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Multi-year Fund |
|---|
| Section | 特設分野 |
|---|
| Research Field |
Transition State Control
|
|---|
| Research Institution | Tokyo Institute of Technology |
|---|
Principal Investigator |
|
|---|
| Project Period (FY) |
2015-07-10 – 2018-03-31
|
| Keywords | クリックケミストリー / [2+2]付加環化 / ドナーアクセプター構造 |
|---|
| Outline of Final Research Achievements |
Click chemistry is a highly efficient addition reaction. In this study, [2+2] cycloaddition-retroelectrocyclization between electron-rich alkynes and electron-deficient alkenes was investigated. Reaction mechanism and product structures were studied in terms of the steric and electronic factors of the reactants. Also, the donor-acceptor products showed potent redox activities and intense charge-transfer bands. These features were successfully applied to thin film devices, such as photovoltaic cells, and specific metal ion sensors.
|
| Free Research Field |
高分子化学
|
