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2006 Fiscal Year Final Research Report Summary

Auger-Electron-Probe Time-Resolved Surface XAFS Technique and Its Application to Study of Surface Dynamics

Research Project

Project/Area Number 16072205
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionThe University of Tokyo

Principal Investigator

KONDOH Hiroshi  The University of Tokyo, Graduate School of Science, Associate Professor (80302800)

Co-Investigator(Kenkyū-buntansha) AMEMIYA Kenta  High-Energy Acceleration Organization, Institute of Materials Structure Science, Associate Professor (80313196)
Project Period (FY) 2004 – 2006
KeywordsTime resolved / XAFS / XPS / reaction dynamics / reaction kinetics / reaction mechanism
Research Abstract

We have developed a fast surface x-ray absorption fine structure(XAFS)technique where solid substrates are irradiated by energy-dispersed synchrotron-radiation x rays and auger electrons emitted from x-ray absorbing surface species are collected at once with a spatially resolved way. In this project we aimed further development of this technique and its application to mechanistic studies on chemical reactions on solid substrates. The present improvement enabled us to trace changes in both surface and gas-phase species simultaneously every approximately 1 s. If this technique is applied to repeatable processes, we can detect submonolayer surface species with a time resolution of 10 ms by using a time gate for the detector. Furthermore we extended this technique to the undulator-based time-resolved x-ray photoelectron spectroscopy, which enabled us to observe dynamic processes of submonolayer surface species with a time resolution of 2 ms.
Real-time monitoring of surface reaction kinetics based on these techniques provided following three major achievements in research that have never been achieved by previous methods.
(1) Finding of a novel reaction pathway involving a NO dimer as a reaction intermediate under the reaction condition of NO reduction on Rh
(2) Elucidation of cirrelation between phase transition of surface oxygen and reactivity under the reaction condition of CO oxidation on Pd
(3) Detection of a transient high-density adsorption state with a life time of less than millisecond order induced by NO pulsed molecular beam
The present development of the fast observation technique for surface species and its application to surface dynamic processes open a way to study novel dynamic processes that have not been detected with previous static surface techniques.

  • Research Products

    (34 results)

All 2006 2005 2004

All Journal Article (24 results) (of which Peer Reviewed: 9 results) Presentation (10 results)

  • [Journal Article] N+NO Reaction on Rh(lll)Surfaces Studied with Fast Near-edge X-ray Absorption Fine Structure Spectroscopy : Role of NO Dimer as an Extrinsic Precursor2006

    • Author(s)
      I. Nakai, et al.
    • Journal Title

      J. Phys. Chem. B 110

      Pages: 25578-25581

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Structural Study of NO Adsorbed on the Reconstructed Pt(110)-(1×2)Surface with X-ray Photoelectron Diffraction and Near-edge X-ray Absorption Fine Structure Spectroscopy2006

    • Author(s)
      T. Shimada, et al.
    • Journal Title

      J. Phys. Chem. B 110

      Pages: 20507-20512

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Mechanism of CO Oxidation Reaction on O-covered Pd(lll)Surfaces Studied with Fast XPS: Change of Reaction Path Accompanying Phase Transition of O Domains2006

    • Author(s)
      I. Nakai, et al.
    • Journal Title

      J. Chem. Phys. 124

      Pages: 224712 1-8

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Infrared Photodissociation Spectroscopy of Protonated AmmoniaCluster Ions, NH_4^+(NH_3)_n(n=5-8), by using Infrared Free Electron Laser2006

    • Author(s)
      K. Tono, et al.
    • Journal Title

      J. Chem. Phys. 125

      Pages: 224305 1-5

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] 吸着プリカーサーと表面反応2006

    • Author(s)
      近藤 寛
    • Journal Title

      表面科学 27

      Pages: 332-340

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] 分散型軟X線吸収分光法による表面化学反応追跡2006

    • Author(s)
      近藤 寛 等
    • Journal Title

      放射光 19

      Pages: 167-177

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Adsorption States of Thienylalkanethiol on Au(lll)2006

    • Author(s)
      T. Nakamura, et al.
    • Journal Title

      Trans. MRS Jpn. 31

      Pages: 589-591

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] N+NO Reaction on Rh(111) Surfaces Studied with Fast Near-edge X-ray Absorption Fine Structure Spectroscopy : Role of NO Dimer as an Extrinsic Precursor2006

    • Author(s)
      I. Nakai, H. Kondoh, T. Shimada, M. Nagasaka, R. Yokota, K. Amemiya, T. Ohta
    • Journal Title

      J. Phys. Chem. B 110

      Pages: 25578-25581

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Structural Study of NO Adsorbed on the Reconstructed Pt(110)-(1x2) Surface with X-ray Photoelectron Diffraction and Near-edge X-ray Absorption Fine Structure Spectroscopy2006

    • Author(s)
      T. Shimada, H. Kondoh, M. Iwasaki, I. Nakai, M. Nagasaka, K. Amemiya, H. Orita, T. Ohta
    • Journal Title

      J. Phys. Chem. B 110

      Pages: 20507-20512

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Mechanism of CO Oxidation Reaction on O-covered Pd(111) Surfaces Studied with Fast XPS : Change of Reaction Path Accompanying Phase Transition of O Domains2006

    • Author(s)
      I. Nakai, H. Kondoh, T. Shimada, A. Resta, J. N. Andersen, T. Ohta
    • Journal Title

      J. Chem. Phys. 124

      Pages: 224712 1-8

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Infrared Photodissociation Spectroscopy of Protonated Ammonia Cluster Ions, NH_4^+(NH_3)_n (n = 5-8), by using Infrared Free Electron Laser"2006

    • Author(s)
      K. Tono, K. Bito, H. Kondoh, T. Ohta, K. Tsukiyama
    • Journal Title

      J. Chem. Phys. 125

      Pages: 224305 1-5

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] "Adsorption precursor and surface reaction" (Japanese)2006

    • Author(s)
      H. Kondoh
    • Journal Title

      J. Surf. Sci. Soc. Jpn 27

      Pages: 332-340

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] "Real-time trace of surface reaction by energy-dispersive soft-x-ray absorption spectroscopy" (Japanese)2006

    • Author(s)
      H. Kondoh, I. Nakai, M. Nagasaka, K. Amemiya, T. Ohta
    • Journal Title

      J. Jpn. Soc. Synchrotron Rad. Research 19

      Pages: 167-177

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Adsorption States of Thienylalkanethiolon Au(111)2006

    • Author(s)
      T. Nakamura, K. Ueki, H. Sakai, M. Matsumoto, M. Abe, I. Nakai, H. Kondoh, T. Ohta
    • Journal Title

      Trans. MRS Jpn. 31

      Pages: 589-591

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Reactive adsorption of thiophene on Au(lll)from solution2005

    • Author(s)
      E. O. Sako, et al.
    • Journal Title

      Chem. Phys. Lett. 413

      Pages: 267-271

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Water formation reaction on Pt(lll): Role of the proton transfer2005

    • Author(s)
      M. Nagasaka, et al.
    • Journal Title

      J. Chem. Phys. 122

      Pages: 204704 1-6

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Nanometer-Scale Mapping of Local Work Function with a Photon-Assisted STM Technique2005

    • Author(s)
      Y. Nakayama, et al.
    • Journal Title

      Appl. Surf. Sci. 241

      Pages: 18-22

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Anomalous Decrease of the Work Function of a Carbide-Modified W(110)Surface Induced by Hydrogen Chemisorption2005

    • Author(s)
      K. Tono, et al.
    • Journal Title

      Chem. Lett. 34

      Pages: 1470-1471

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] シンクロトロン放射光を用いた表面反応キネティクスの実時間追跡2005

    • Author(s)
      近藤 寛 等
    • Journal Title

      分光研究 54

      Pages: 306-308

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Reactive adsorption of thiophene on Au(111) from solution2005

    • Author(s)
      E. O. Sako, H. Kondoh, I. Nakai, A. Nambu, T. Nakamura, T. Ohta
    • Journal Title

      Chem. Phys. Lett. 413

      Pages: 267-271

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Water formation reaction on Pt(111) : Role of the proton transfer2005

    • Author(s)
      M. Nagasaka, H. Kondoh, T. Ohta
    • Journal Title

      J. Chem. Phys. 122

      Pages: 204704 1-6

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Nanometer-Scale Mapping of Local Work Function with a Photon-Assisted STM Technique2005

    • Author(s)
      Y. Nakayama, H. Kondoh, T. Ohta
    • Journal Title

      Appl. Surf. Sci. 241

      Pages: 18-22

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Anomalous Decrease of the Work Function of a Carbide-Modified W(110) Surface Induced by Hydrogen Chemisorption2005

    • Author(s)
      K. Tono, J. Ikeuchi, H. Kondoh, T. Ohta
    • Journal Title

      Chem. Lett. 34

      Pages: 1470-1471

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] "Real-time trace of surface reaction kinetics using synchrotron radiation" (Japanese)2005

    • Author(s)
      H. Kondoh, K. Amemiya, T. Ohta
    • Journal Title

      Bunko Kenkyu 54

      Pages: 306-308

    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Surface chemistry using synchrotron radiation in soft x-ray region : structures and dynamic processes of surface molecules2006

    • Author(s)
      H. Kondoh, K. Amemiya, T. Shimada, I. Nakai, M. Nagasaka, R. Yokota, T. Ohta
    • Organizer
      Pacifichem2005
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2006-12-16
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Fast NEXAFS Study of NO Reduction over Rh(lll): Role of NO Dimer as a Reaction Intermediate2006

    • Author(s)
      H. Kondoh
    • Organizer
      New Zealand Institute of Chemistry Conference 2006
    • Place of Presentation
      Rotorua, New Zealand
    • Year and Date
      2006-12-02
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Fast NEXAFS Study of NO Reduction over Rh(111) : Role of NO Dimer as a Reaction Intermediate2006

    • Author(s)
      H. Kondoh
    • Organizer
      New Zealand Institute of Chemistry Conference 2006
    • Place of Presentation
      Rotorua, New Zealand
    • Year and Date
      2006-12-02
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Surface chemistry using synchrotron radiation in soft x-ray region: structures and dynamic processes of surface molecules2005

    • Author(s)
      H. Kondoh, et al.
    • Organizer
      Pacifichem2005
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2005-12-16
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] エネルギー分散型表面XAFS法で見る表面反応-表面キネティクスの直接観測によるアプローチ-2005

    • Author(s)
      近藤 寛
    • Organizer
      分子構造総合討論会2005
    • Place of Presentation
      東京
    • Year and Date
      2005-09-22
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] "Surface reaction studied by energy-dispersive surface XAFS technique -approach from direct observation of surface kinetics -" (Japanese)2005

    • Author(s)
      H. Kondoh
    • Organizer
      Discussion on Molecular Structure 2005
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2005-09-22
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] In-situ observation of surface reactions with a fast NEXAFS technique2005

    • Author(s)
      H. Kondoh
    • Organizer
      Gordon Research Conference on Chemical Reactions at Surfaces
    • Place of Presentation
      Ventura, USA
    • Year and Date
      2005-02-14
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Chemical Reactions on Metal Surfaces Studied with Energy Dispersive Surface XAFS2005

    • Author(s)
      H. Kondoh
    • Organizer
      Frontier Conference on Synchrotron Radiation and Related Methods in Advanced Materials Science
    • Place of Presentation
      Lund, Sweden
    • Year and Date
      2005-01-19
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Surface reaction and adsorbate configuration: X-ray absorption spectroscopy study2004

    • Author(s)
      H. Kondoh
    • Organizer
      The 15th CRC International Symposium on Catalytic Reaction Dynamics and Surface Nano-structures
    • Place of Presentation
      Sapporo, Japan
    • Year and Date
      2004-10-27
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Surface reaction and adsorbate configuration : X-ray absorption spectroscopy study2004

    • Author(s)
      H. Kondoh
    • Organizer
      The 15th CRC International Symposium on Catalytic Reaction Dynamics and Surface Nano-structures
    • Place of Presentation
      Sapporo, Japan
    • Year and Date
      2004-10-27
    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2010-06-09  

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