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2007 Fiscal Year Final Research Report Summary

Construction of Electro-functional Space Using Interfacial Bottom-up Synthesis of Coordination Bond Network

Research Project

Project/Area Number 16074204
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionThe University of Tokyo

Principal Investigator

NISHIHARA Hiroshi  The University of Tokyo, Graduate School of Science, Professor (70156090)

Co-Investigator(Kenkyū-buntansha) YAMANOI Yoshinori  The University of Tokyo, Graduate School of Science, Assistant Professor (20342636)
KUME Shoko  The University of Tokyo, Graduate School of Science, Assistant Professor (30431894)
YONEZAWA Tetsu  The University of Tokyo, Graduate School of Science, Associate Professor (90284538)
Project Period (FY) 2004 – 2007
Keywordssurface properties / nanometerial / micro-nano-device / quantum wire / molecular machine
Research Abstract

In this project, we aim at the construction of electro-functional interfacial space by assembling pi-conjugated and/or redox active metal complex molecular chains in one, two, or three dimensions. Bottom-up approach using successive coordination bond formation is utilized in order to create the space in which potential distribution can be controlled by external stimuli such as electrons and photons.
Films of linear and branched oligomer wires of Fe (tpy)2 (tpy = 2,2' :6',2" -terpyridine) were constructed on a gold electrode surface by the interfacial stepwise coordination method employing a surface-anchoring ligand, (tpy-C6H4N=NC6H4-S) 2 (1), two bridging ligands, 1,4-C6H4(tpy)2 (3) and 1,3,5-C6H3(C・C-tpy)3 (4), and metal ions. The quantitative complexation of the ligands and FeII ions was monitored by electrochemical measurements in linear oligomers of 3 up to eight complexation cycles and in branched oligomers of 4 up to four cycles. STM observation of branched oligomers at low surface coverage showed an even distribution of nanodots having uniform size and shape, suggesting the quantitative formation of dendritic structures.
The electron transport mechanism and kinetics for the redox reaction of the films of linear and branched oligomer wires were analyzed by potential step chronoamperometry (PSCA). The unique i-t behavior, obtained similarly in all conditions indicates that electron conduction occurs not by diffusional motion but by successive electron hopping between neighboring redox sites within a molecular wire. This is the first observation of redox conduction in a single molecular wire in redox polymer films.
Other studies such as fabrication of Co-Ru wires and anthraquinone-bridged metal complex molecular wires were also reported.
We also constructed a ferrocenylabozenezene SAM which can undergo reversible isomerization with a single green light source and a redox reaction.

  • Research Products

    (9 results)

All 2007

All Journal Article (7 results) (of which Peer Reviewed: 4 results) Presentation (1 results) Book (1 results)

  • [Journal Article] Synthesis of Molecular Wires of Linear and Branched Bis(terpyridine) Complex Oligomers and Electrochemical Observation of Through-bond Redox Conduction2007

    • Author(s)
      Y. Nishimori, K. Kanaizuka, M. Murata, H. Nishihara
    • Journal Title

      Chem. Asian J. 2

      Pages: 367-376

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Protonation-induced Cyclocondensation Reaction of 1-Arylethynylanthraquinones to form Oxodihydrodibenzochromenylium ions and Valence Tautomerism of 2-Ferrocenyloxodihydrodibenzochromenylium2007

    • Author(s)
      M. Kondo, M. Uchikawa, W. -W. Zhang, K. Namiki, S. Kume, M. Murata, Y. Kobayashi, H. Nishihara
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 6271-6274

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Reversible Photochromism of a Ferrocenylazobenzene Monolayer Controllable by a Single Green Light Source2007

    • Author(s)
      K. Namiki, A. Sakamoto, M. Murata, S. Kume, H. Nishihara
    • Journal Title

      Chem. Commun.

      Pages: 4650-4652

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Construction of Redox- and Photo-functional Molecular Systems on Electrode Surface for Application to Molecular Devices2007

    • Author(s)
      H. Nishihara, K. Kanaizuka, Y. Nishimori, Y. Yamanoi
    • Journal Title

      Coord. Chem. Rev. 251

      Pages: 2674-2687

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Synthesis of Molecular Wires of Linear and Branched Bis (terpyridine) Complex Oligomers and Electrochemical Observation of Through-bond Redox Conduction2007

    • Author(s)
      Y. Nishimori, K. Kanaizuka, M. Murata, H. Nishihara
    • Journal Title

      Chem. Asian J. 2(3)

      Pages: 367-376

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Protonation-induced Cyclocondensation Reaction of 1-Arylethynylanthraquinones to form Oxodihydrodibenzochromenylium ions and Valence Tautomerism of 2-Ferrocenyloxodihydrodibenzochromenylium2007

    • Author(s)
      M. Kondo, M. Uchikawa, W.-W. Zhang, K. Namiki, S. Kume, M. Murata. Y. Kobayashi, H. Nishihara
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 6271-6274

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] "Construction of Redox- and Photo-functional Molecular Systems on Electrode Surface for Application to Molecular Devices2007

    • Author(s)
      H. Nishihara, K. Kanaizuka, Y. Nishimori, Y. Yamanoi
    • Journal Title

      Coord. Chem. Rev. 251

      Pages: 2674-2687

    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Surface Bottom-up Synthesis of Metal Complex Oligomers and Polymers and Their Electrofunctionalities2007

    • Author(s)
      H. Nishihara, Y. Nishimori
    • Organizer
      234th American Chemical Society National Meeting & Exposition
    • Place of Presentation
      Boston
    • Year and Date
      2007-08-01
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] “Redox-based functionalities of multinuclear metal complex systems," Frontiers in Transition Metal-Containing Polymers2007

    • Author(s)
      H. Nishihara
    • Total Pages
      369-397
    • Publisher
      John Wiley & Sons, Inc
    • Description
      「研究成果報告書概要(和文)」より

URL: 

Published: 2010-06-09  

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