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2007 Fiscal Year Annual Research Report

放射光X線散乱法による量子物質相の精密結晶構造と電子状態の研究

Research Project

Project/Area Number 16076202
Research InstitutionTohoku University

Principal Investigator

村上 洋一  Tohoku University, 大学院・理学研究科, 教授 (60190899)

Co-Investigator(Kenkyū-buntansha) 澤 博  高エネルギー加速器研究機構, 物質構造科学研究所, 教授 (50215901)
前川 禎通  東北大学, 金属材料研究所, 教授 (60005973)
Keywords電荷秩序 / 軌道秩序 / 有機導体 / マンガン酸化物薄膜 / 共鳴X線散乱 / 磁性半導体 / 中間スピン状態 / フラストレーション
Research Abstract

KEK/Photon FactoryのビームラインBL-3A,BL-4Cにおいて,(共鳴)X線回折実験を,またSPring-8のBL11XU,BL22XUにおいて,共鳴(非弾性)X線散乱実験を行い,下記の系に関して電子自由度秩序と物性の関連性を明らかにした.一方,新しい試みとして磁性半導体に関する理論を構築した.
1.コバルト酸化物LaCoO_3やSr_3YCo_4O_<10.5>において,そのスピン・軌道状態を調べた.前者に関しては,中間スピン状態に伴う軌道秩序の探索を試みたが,実験誤差範囲で観測されなかった.一方,後者の最低温相においては,軌道秩序を伴う中間スピン状態と高スピン状態が交替していることを明らかにした.
2.幾何学的フラストレーションを内蔵した希土類硼化物HoB_4において,その多極子構造を決定した.また,この系に特徴的な非常に広い散漫散乱を観測し,これは磁気秩序と軌道秩序の競合により生じていることを明らかにした.
3.ペロブスカイト酸化物(Oll)基板上に成長させた(Nd,Pr)_<0.5>Sr_<0.5>MnO_3薄膜の軌道状態を明らかにし,その軌道秩序形成機構について考察した.
4.擬2次元有機導体α-(BEDT-TTF)_2I_3において,水平ストライプ構造の電荷秩序状態が実現していることを示し,その金属絶縁体転移機構を明らかにした.
5.透明磁石やスピンエレクトロニクスの材料として近年注目を集めている,遷移金属イオンを含む酸化物等の磁性半導体に関する理論構築を行った.特に,磁性半導体の強磁性発現機構に関する理論構築と,その物性の数値シミュレーション法の開発を行った.

  • Research Products

    (34 results)

All 2008 2007 2006 Other

All Journal Article (23 results) (of which Peer Reviewed: 23 results) Presentation (8 results) Book (1 results) Remarks (2 results)

  • [Journal Article] Magnetic Compton Profile Study of Orbital Ordering State of 3d Electrons in YTiO32008

    • Author(s)
      N. Tsuji, M. Ito, H. Nakao, Y. Murakami, et. all
    • Journal Title

      J. Phys. Soc. Jpn 77

      Pages: 0237051-4

    • Peer Reviewed
  • [Journal Article] Non-collinear magnetic structure of TbB_42007

    • Author(s)
      T. Matsumura, D. Okuyama and Y. murakami
    • Journal Title

      J. Phys. Soc. Jpn. 76

      Pages: 015001-1-2

    • Peer Reviewed
  • [Journal Article] Momentum-dependent charge excitations of a two-leg ladder: Resonant inelastic x-ray scattering of (La, Sr, Ca)_<14>Cu_<24>O_<41>2007

    • Author(s)
      K. Ishii, K. Tsutsui, T. Tohyama, T. Inami, J. Mizuki, Y. Murakami, Y. Endoh, S. Maekawa
    • Journal Title

      Phys. Rev. B 76

      Pages: 045124-1-7

    • Peer Reviewed
  • [Journal Article] Coherent X-ray Diffraction for Domain Observation2007

    • Author(s)
      K. Ohwada, K. Namikawa, Y. murakami, et. all
    • Journal Title

      Trans. Mater. Res. Soc. Jpn. 72

      Pages: 7-10

    • Peer Reviewed
  • [Journal Article] Orbital Ordered Structure of a Manganite Thin Film Observed by K-edge Resonant X-ray scattering2007

    • Author(s)
      Y. Wakabayashi, D. Bizen, H. Nakao, Y. murakami, et. all
    • Journal Title

      AIP Conf. Proc. 879

      Pages: 1711-1714

    • Peer Reviewed
  • [Journal Article] Magnetic phase transition in HoB_4 studied by neutron diffraction2007

    • Author(s)
      D. Okuyama, T. Matsumura, K. Iwasa and Y. murakami
    • Journal Title

      J. Magn. Magn. Mater. 310

      Pages: e152-e154

    • Peer Reviewed
  • [Journal Article] Magnetic properties of LaMnO_<3+δ> nanocrystals in MCM-41 mesoporous silica2007

    • Author(s)
      H. Kira, H. Tamura, Y. Ando, M. Onodera, H. Nakao, Y. murakami, et. all
    • Journal Title

      J. Magn. Magn. Mater. 310

      Pages: 2480-2482

    • Peer Reviewed
  • [Journal Article] Mechanism of resonant X-ray scattering to observe the orbital ordering2007

    • Author(s)
      Y. murakami, H. Nakao, T. Matsumura and H. Ohsumi
    • Journal Title

      J. Magn. Magn. Mater. 310

      Pages: 723-729

    • Peer Reviewed
  • [Journal Article] Metal-insulator transition in Y_<1-x>Ca_xTiO_3 studied by X-ray scattering2007

    • Author(s)
      H. Nakao, S. Kodama, K. Kiyoto, D. Bizen, Y. murakami, et. all
    • Journal Title

      J. Magn. Magn. Mater. 310

      Pages: 895-897

    • Peer Reviewed
  • [Journal Article] Orbital ordering and the dilute effect in copper fluoride2007

    • Author(s)
      N. Tatami, Y. Ando, S. Niioka, H. Kira, M. Onodera, H. Nakao, K. Iwasa, Y. murakami, et. all
    • Journal Title

      J. Magn. Magn. Mater 310

      Pages: 787-789

    • Peer Reviewed
  • [Journal Article] Pressure effects on the orbital ordered state of RVO_3(R=Y, Tb)2007

    • Author(s)
      D. Bizen, K. Nakatsuka, H. Naka, Y. murakami, et. all
    • Journal Title

      J. Magn. Magn. Mater 310

      Pages: 785-786

    • Peer Reviewed
  • [Journal Article] Resonant x-ray magnetic diffraction experiments on SmB_2C_22007

    • Author(s)
      T. Inami, T. Honma, S. Tsutsui, H. Nakao, Y. murakami, et. all
    • Journal Title

      J. Magn. Magn. Mater. 310

      Pages: 748-750

    • Peer Reviewed
  • [Journal Article] Resonant X-ray scattering PrRu_4P_<12>2007

    • Author(s)
      K. Ishii, S. Tsutusi, L. Hao, K. Iwasa, Y. murakami, et. all
    • Journal Title

      J. Magn. Magn. Mater. 310

      Pages: e178-e180

    • Peer Reviewed
  • [Journal Article] High-Magnetic-Field X-ray Absorption Spectroscopy of Field-Induced Valence Transition in YbInCu42007

    • Author(s)
      Y. H. Matsuda, T. Inami, K. Ohwada, H. Nojiri, Y. Murakami, et. all
    • Journal Title

      J. Phys. Soc. Jpn. 76

      Pages: 0347021-6

    • Peer Reviewed
  • [Journal Article] X-ray anomalous scattering of diluted magnetic oxide semiconductors: Possible evidence of lattice deformation for high temperature ferromagnetism2007

    • Author(s)
      T. Matsumura, D. Okuyama, S. Niioka, H. Ishida, T. Satoh, Y. Murakami, et. all
    • Journal Title

      Phys. Rev. B 76

      Pages: 1153201-5

    • Peer Reviewed
  • [Journal Article] Structural relations between two ground states of NaV205 under high pressure A synchrotron x-ray diffraction study2007

    • Author(s)
      K. Ohwada, Y. Fujii, H. Nakao, Y. Murakami, et. all
    • Journal Title

      Phys. Rev. B 76

      Pages: 0941131-10

    • Peer Reviewed
  • [Journal Article] Orbital Ordering Structures in (Nd, Pr) 0.5Sr0.5Mn03 Manganite Thin Films on Perovskite (011) Substrates2007

    • Author(s)
      Y. Wakabayashi, D. Bizen, H. Nakao, Y. Murakami, et. all
    • Journal Title

      J. Phys. Soc. Jpn 77

      Pages: 0147121-7

    • Peer Reviewed
  • [Journal Article] Generalization of Faraday's Law to Include Nonconservative Spin Forces2007

    • Author(s)
      S.E. Barnes and S. Maekawa
    • Journal Title

      Phys. Rev. Lett. 98

      Pages: 246601-1,246601-4

    • Peer Reviewed
  • [Journal Article] Charge ordering in α-(BEDT-TTF)2I3 by synchrotron X-ray diffraction2007

    • Author(s)
      T. Kakiuchil, Y. Wakabayashi, H. Sawa, et. al.
    • Journal Title

      J. Phys. Soc. Jpn. 76

      Pages: 113702(1-4)

    • Peer Reviewed
  • [Journal Article] Domain formation in the structural phase transition of the organic superconductorκ_λ-(DMEDO-TSeF)2[Au(CN)4](THF)2007

    • Author(s)
      T. Kawamoto T. Mori T. Kakiuchi H. Sawa
    • Journal Title

      Phys. Rev. B 76

      Pages: 134517(1-6)

    • Peer Reviewed
  • [Journal Article] Superconductivity of doped Ar@C602007

    • Author(s)
      K. Yakigaya, A. Takeda, Y. Yokoyama, S. Ito, T. Miyazaki, H. Sawa
    • Journal Title

      New Journal of Chemistry 31

      Pages: 973-979

    • Peer Reviewed
  • [Journal Article] Manganese (III, IV) and Manganese (I, II) Oxide Clusters Trapped by Copper (II) Complexes2007

    • Author(s)
      S. Yamashita, T. Shiga, M. Kurashima, M. Nihei, H. Nojiri, H. Sawa
    • Journal Title

      Inorganic Chemistry 46

      Pages: 3810-3812

    • Peer Reviewed
  • [Journal Article] Supercurrent Pumping in Josephson Junctions with a Half-Metallic Ferromagnet2007

    • Author(s)
      S. Takahashi, S. Hikino, M. Mori, J. Martinek, S. Maekawa
    • Journal Title

      Phys. Rev. Lett. 99

      Pages: 057003-1、057003-4

    • Peer Reviewed
  • [Presentation] 超伝導体中のスピン流2008

    • Author(s)
      前川禎通
    • Organizer
      日本物理学会第63回 年次大会
    • Place of Presentation
      大阪・近畿大学
    • Year and Date
      2008-03-23
  • [Presentation] Tunnel Magnetoresistance, Spin Accumulation, and Spin Hall Effect2008

    • Author(s)
      前川禎通
    • Organizer
      American Physical Sciety March Meeting 2008
    • Place of Presentation
      アメリカ・ニューオリンズ
    • Year and Date
      2008-03-14
  • [Presentation] 室温強磁性体Sr3YCo4010.5におけるCoの軌道状態2008

    • Author(s)
      村上 洋一
    • Organizer
      科研費特定領域「異常量子物質の創製-新しい物理を生む新物質-」の成果報告会
    • Place of Presentation
      名古屋大学・野依記念学術交流館
    • Year and Date
      2008-01-06
  • [Presentation] Orbital ordering and the impurity effect in copper fluoride2007

    • Author(s)
      Y. Murakami
    • Organizer
      Internal Conference on Magnetic Materials
    • Place of Presentation
      Kolkata, India
    • Year and Date
      20071211-16
  • [Presentation] Wigner Crystallization in a Molecular Conductor, (DI-DCNQI) 2Ag2007

    • Author(s)
      H. Sawa, T. Kakiuchi, Y. Wakabayashi, K. Kanoda
    • Organizer
      AsCA
    • Place of Presentation
      Taiwan
    • Year and Date
      20071104-07
  • [Presentation] 共鳴X線散乱法による電子自由度秩序の観測-分子性導体への応用の可能性-2007

    • Author(s)
      Y. Murakami
    • Organizer
      分子性導体の機能・構造相関の研究と放射光利用
    • Place of Presentation
      SPring-8
    • Year and Date
      20070602-04
  • [Presentation] Matieral Dependence of High-Tc Superconductivity2007

    • Author(s)
      前川禎通
    • Organizer
      Hong Kong Forum of Physics 2007-Frontiers in Condenced Matter
    • Place of Presentation
      Hong Kong, China
    • Year and Date
      2007-12-14
  • [Presentation] 室温強磁性を示すSr3YCo4010.5の共鳴X線散乱によるCo軌道状態の研究2006

    • Author(s)
      村上 洋一
    • Organizer
      第21回放射光学会
    • Place of Presentation
      立命館大学・びわこ草津キャンパス
    • Year and Date
      2006-01-13
  • [Book] X線磁気分光と散乱:X線磁気散乱による磁性研究2007

    • Author(s)
      村上 洋一
    • Total Pages
      77-87
    • Publisher
      アイピーシー
  • [Remarks]

    • URL

      http://calaf.phys.tohoku.ac.jp/murakami/top.html

  • [Remarks]

    • URL

      http://www.maekawa-lab.imr.tohoku.ac.jp/

URL: 

Published: 2010-02-04   Modified: 2016-04-21  

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