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2007 Fiscal Year Annual Research Report

希土類系物質のパノスコピック形態制御と高次機能設計

Research Project

Project/Area Number 16080103
Research InstitutionOsaka University

Principal Investigator

町田 憲一  Osaka University, 先端科学イノベーションセンター, 教授 (00157223)

Co-Investigator(Kenkyū-buntansha) 佐藤 次雄  東北大学, 多元物質科学研究所, 教授 (90091694)
福永 博俊  長崎大学, 工学部, 教授 (10136533)
小松 高行  長岡技術科学大学, 工学部, 教授 (60143822)
Keywords階層的形態制御 / 希土類系物質 / ソフト溶液化学法 / 電磁物性 / 光学物性 / f 電子物性 / 高次機能 / 機能材料
Research Abstract

本特定領域研究が開始されてから4年が経過したものの、公募研究課題を新規に加えたため、スタートアップ研究打ち合わせ会は十分な研究の準備を行うために6月に開催した。また、研究班ごとに研究打合せ会を実施し、年度の研究成果のまとめを領域全体で行った。具体的な活動の実施内容は以下の通りである。
1)第1回研究打合会(スタートアップ会議)(平成19年6月22〜23日、札幌・KKRホテル札幌)
新規に採択した25件の公募研究課題を併せて、平成19年度の研究計画を議論した。
2)第2回研究打合会(若手研究発表会)(平成19年10月11〜12日、福岡・休暇村志賀島)
90名以上の参加者を得て、若手スタッフおよび大学院生を中心に研究発表を行った。
3)研究成果報告会および第5回公開シンポジウム(平成20年1月30日〜2月2日、東京・東京ガーデンパレス)
4名の評価委員の臨席のもとで、公開シンポジウムならびに非公開の研究成果発表会を行った。
一方、各研究計画班の平成19年度の主な研究計画は昨年度と同様に以下の通りであった。
1)ソフト溶液化学反応を利用したナノ領域での高度な組成、構造の規定によるパノスコピック形態制御を希土類系物質に主として適用し、これにより誘起される高度な高次物性の発現に関する研究を立案し実施した。
2)希土類-鉄属遷移金属系を中心に、パノスコピック形態制御された希土類系物質の系統的な作製と物質相の観察、および高次物性の発現とその発現機構の解明に関する研究を引き続き立案し実施した。
3)希土類イオンを含有したガラス、単結晶、微粒子等を中心に、パノスコピック形態制御された希土類系物質を作製すると共に、レーザ照射等によるガラスの結晶化や希土類イオンの励起を通して、高次光物性の発現とその機能評価に関する研究を立案し実施した。
4)A01、A02およびA03の各研究班で得られた研究成果をもとに、高性能永久磁石、高輝度蛍光体、高性能酸化物イオン導電体としての可能性を明らかにすると共に、これらの高性能アクチュエータ、電波吸収材料、ディスプレイや光源、燃料電池などの実用に向けてのシステム化に関する研究を立案し実施した.

  • Research Products

    (49 results)

All 2008 2007 Other

All Journal Article (45 results) (of which Peer Reviewed: 45 results) Presentation (1 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Crystal Line Patterning and Enhanced Ion Conductivity of Li(GE,Ti)_2(PO_4)_3 Glasses by Yb Fiber Laser Irradiation2008

    • Author(s)
      M.-L., Pang・R., Suzuki・M., Saito・K., Machida・H., Hanzawa・Y., Nojiri・S., Tanase
    • Journal Title

      J. Electrochem. Soc. 155(In press)

    • Peer Reviewed
  • [Journal Article] Extraction of Rare Earth Elements from Nd-Fe-B Magnet Scraps by NH_4Cl2008

    • Author(s)
      M., Itoh・K., Miura・K., Machida
    • Journal Title

      Chem. Lett., 37

      Pages: 372-373

    • Peer Reviewed
  • [Journal Article] Suractant-assisted Preparation and Magnetic Properties of Iron-based Nanowires2008

    • Author(s)
      K., Miura・M., Itoh・K., Machida,
    • Journal Title

      Jpn. J. Appl. Phys. (In press)

    • Peer Reviewed
  • [Journal Article] Extraction and recovery characteristics of Fe element from Nd-Fe-B sintered magnet powder scrap by carbonylation2008

    • Author(s)
      K., Miura・M., Itoh・K., Machida,
    • Journal Title

      J. Alloys Compd. (In press)

    • Peer Reviewed
  • [Journal Article] Synthesis of Nitridosilicate CaSr_<1-x>Eu_xSi_5N_8 (x=0-1) Phosphor by Calcium Cyanamide Reduction for White Light-Emitting Diode Applications2008

    • Author(s)
      X.-Q., Piao・K., Machida・T., Horikawa・H., Hanzawa
    • Journal Title

      J. Electrochem. Soc. 155

      Pages: J17-22

    • Peer Reviewed
  • [Journal Article] Formation of NaNbO_3-based conductive crystal lines on glass surface by Yb fiber laser irradiation2008

    • Author(s)
      M.-L., Pang・R., Suzuki・M., Saito・K., Machida・H., Hanzawa・Y., Nojiri・S., Tanase
    • Journal Title

      J. Appl. Phys. 103

      Pages: 013112-1-4

    • Peer Reviewed
  • [Journal Article] Formation and crystal line patterning of Li_<1.3>Al_<0.3>Ti_<1.7>(PO_4)_3 ion conductive glass by Niatom heat processing method2008

    • Author(s)
      M.-L., Pang・R., Suzuki・M., Saito・K., Machida・H., Hanzawa・Y., Nojiri・S., Tanase
    • Journal Title

      Appl. Phys. Lett. 92

      Pages: 041112-1-3

    • Peer Reviewed
  • [Journal Article] Recycle of Rare Earth Sintered Magnet Powder Scraps as Electromagnetic Wave Absorbers in Gigahertz Range2008

    • Author(s)
      M., Itoh・K., Nishiyama・F., Shogano・T., Murota・K., Yamamoto・M., Sasada・K., Machida
    • Journal Title

      J. Alloys Compd. 451

      Pages: 507-509

    • Peer Reviewed
  • [Journal Article] Synthesis of K_0.8Li_<0.27>Ti_<1.73>O_4 and Ce_0.8Ca_<0.2>O_<1.8>/K_<0.8>Li_<0.27>Ti_<1.73>O_4 Nanocomposite for UV Shielding Performance Enhancement of Calcia Doped Ceria2008

    • Author(s)
      A.M., El-Toni・S., Yin・T., Sato
    • Journal Title

      J. Mater. Sci. 42(In press)

    • Peer Reviewed
  • [Journal Article] Panoscopic Assembling and UV-shielding Properties of Calcia-doped Ceria with Micaceous Lepidcrocite Type Potassium Lithium Titanate via Soft Chemical Processes2008

    • Author(s)
      T., Sato・A.M., El-Toni・S., Yin・T., Kumei
    • Journal Title

      Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry 42(In press)

    • Peer Reviewed
  • [Journal Article] 紫外光吸収剤,添加剤の選定活用と規制2008

    • Author(s)
      佐藤次雄, 殷シュウ
    • Journal Title

      技術科学協会 (印刷中)

    • Peer Reviewed
  • [Journal Article] 板状チタン酸/セリアナノ粒子バシスコピック形態制御複合体の紫外線遮蔽特性2008

    • Author(s)
      佐藤千草, モハメド アーメド エルトニ, 殷シュウ, 佐藤次雄
    • Journal Title

      粉体および粉末冶金 (印刷中)

    • Peer Reviewed
  • [Journal Article] 磁性材料2008

    • Author(s)
      福永博俊, 中野正基
    • Journal Title

      電気評論 92

      Pages: 66-70

    • Peer Reviewed
  • [Journal Article] Laser-induced line patterning of nonlinear optical crystals in glass2008

    • Author(s)
      T., Komatsu・T., Honma
    • Journal Title

      IEEE LEOS (In press)

    • Peer Reviewed
  • [Journal Article] Transparent nonlinear optical crystallized glass fibers with highly oriented Ba_2TiGe_2O_8 crystals2008

    • Author(s)
      Y., Hane・Y., Benino・T., Fujiwara・T., Komatsu
    • Journal Title

      J. Appl. Phys. (In press)

    • Peer Reviewed
  • [Journal Article] Patterninng of c-axis oriented Ba_2TiX_2O_8 (X=Si,Ge) crystal lines in glass by laser irradiation and their second-order optical nonlinearities2008

    • Author(s)
      T., Honman・Y., Benino・T., Komatsu
    • Journal Title

      J. Mater. Res. (In press)

    • Peer Reviewed
  • [Journal Article] YAG laser-induced structural modification in transition metal ion containing 40K_2O-40Nb_2O_5-20SiO_2 glasses2008

    • Author(s)
      B.H., Venkataraman・T., Komatsu
    • Journal Title

      Mater. Res. Bull. (In press)

    • Peer Reviewed
  • [Journal Article] Creation of ferroelectric, single-crystal architecture in Sm_<0.5>La_<0.5>BGeO_5 glass2008

    • Author(s)
      P., Gupta・H., Jain・D.B., Williams・T., Honma・Y., Benino・T., Kornatsu
    • Journal Title

      J. Am. Ceram. Soc. 91

      Pages: 110-114

    • Peer Reviewed
  • [Journal Article] Writing of crystal line patterns in glass by laser irradiation2008

    • Author(s)
      T., Honma・R., Ihara・Y., Benino・R., Sato・T., Fujiwara・T., Komatsu
    • Journal Title

      J. Non-Cryst. Solids 354

      Pages: 468-471

    • Peer Reviewed
  • [Journal Article] Patterning of nonlinear optical crystals in glass by laser-induced crystallization2008

    • Author(s)
      T., Komatsu・R., Ihara・T., Honma・Y., Benino・R., Sato・H.G., Kim・T., Fujiwara
    • Journal Title

      J. Am. Ceram. Soc. 90

      Pages: 699-705

    • Peer Reviewed
  • [Journal Article] A novel Process of Resource Recovery from Rare Earth Magnet Scrap Using Carbonylation Reaction and Recycle as Electromagnetic Wave Absorber2007

    • Author(s)
      M., Itoh・K., Miura・K., Machida
    • Journal Title

      J. Ceram. Soc. Jpn. 115

      Pages: 628-632

    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Sr_2Si_5N_8: Eu^<2+> Phosphor Using Strontium Carboxylate2007

    • Author(s)
      T., Horikawa・M., Fujitani・X.-Q., Piao・H., Hanzawa・K., Machida
    • Journal Title

      J. Ceram. Soc. Jpn. 103

      Pages: 623-627

    • Peer Reviewed
  • [Journal Article] Self-propagating high temperature synthesis of yellow-emitting Ba_2Si_5N_8: Eu^<2+> phosphors for white light-emitting diodes2007

    • Author(s)
      X.-Q., Piao・T., Horikawa・H., Hanzawa・K., Machida
    • Journal Title

      Appl. Phys. Lett. 91

      Pages: 041908-1-3

    • Peer Reviewed
  • [Journal Article] Preparation of CaAlSiN_3: Eu^<2+> Phosphors by the Self-Propagating High-Temperature Synthesis and Their Luminescent Properties2007

    • Author(s)
      X.-Q., Piao・T., Horikawa・H., Hanzawa・K., Machida・Y., Shimomura・N., Kijima
    • Journal Title

      Chem. Mater. 19

      Pages: 4592-4599

    • Peer Reviewed
  • [Journal Article] DNA Damage upon UV Illumination in the Presence of Inorganic UV-shielding Materials2007

    • Author(s)
      T., Sato・A.M., El-Toni・S., Yin・H., Hidaka
    • Journal Title

      Key Eng. Mat. 352

      Pages: 293-296

    • Peer Reviewed
  • [Journal Article] Synthesis and Silica Coating of Calcia-doped Ceria/plate-like Titanate (K_<0.8>Li_<0.27>Ti_<1.73>O_4) Nanocomposite by Seeded Polymerizat Technique2007

    • Author(s)
      A.M., El-Toni・S., Yin・T., Sato
    • Journal Title

      Mater. Chem. Phys. 103

      Pages: 345-350

    • Peer Reviewed
  • [Journal Article] Synthesis and UV-shielding Property of Plate-like Potassium Lithium Titanate Coated with Calcium-doped Ceria Nanoparticles2007

    • Author(s)
      T., Sato・A.M., El-Toni
    • Journal Title

      J. Ceram. Soc. Jpn. 115

      Pages: 571-576

    • Peer Reviewed
  • [Journal Article] Synthesis and Photochemical Properties of Micaceous Cerium Phosphates2007

    • Author(s)
      T., Sato・R., Li・C., Sato・S., Yin
    • Journal Title

      Phosphorus Res. Bull. 21

      Pages: 44-47

    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Wire-like and Near-spherical Eu_2O_3-doped Y_2O_3 Phosphors by Solvothermal Reaction2007

    • Author(s)
      S., Yin・M., Shinozaki・T., Sato
    • Journal Title

      J., Lumin. 126

      Pages: 427-433

    • Peer Reviewed
  • [Journal Article] Order/disorder phase composite Fe-Pt exchange-spring thick film magnets2007

    • Author(s)
      M., Nakano・H, Kuroda・J., Koga・T., Yanai・Y., Tanaka・H., Fukunaga
    • Journal Title

      J., Appl. Phys. 103

      Pages: 07E110-1-3

    • Peer Reviewed
  • [Journal Article] Preparation method of rare earth bonded magnets with continuously controlled anisotropy directions2007

    • Author(s)
      F., Yamashita・K., Kawamura・Y., Okada・H., Murakami・M., Ogushi・M., Nakano・H., Fukunaga
    • Journal Title

      J. Appl. Phys. 103

      Pages: 09K522-1-3

    • Peer Reviewed
  • [Journal Article] Enhancement in coercivity of PLD-made Nd-Fe-B thick film magnets by high-speed crystallization2007

    • Author(s)
      M., Nakano・H, Takeda・S., Sato・T., Yanai・F., Yamashita・H., Fukunaga
    • Journal Title

      J. Appl. Phys. 103

      Pages: 09K525-1-3

    • Peer Reviewed
  • [Journal Article] Review of Fabrication and Characterization of Nd-Fe-B Thick Films for Magnetic Micromachines2007

    • Author(s)
      M., Nakano・S., Sato・F., Yamashita・T., Honda・J., Yamasaki・K., Ishiyama・M., Itakura・J., Fidler・T., Yanai・H., Fukunaga
    • Journal Title

      IEEE Trans. Magn. 23

      Pages: 2672-2676

    • Peer Reviewed
  • [Journal Article] Composite bonded magnets with controlled anisotropies direction prepared by viscous deformation phenomenon2007

    • Author(s)
      F., Yamashita・K., Kawamura・Y., Okada・H., Murakami・M., Ogushi・M., Nakano・H., Fukunaga
    • Journal Title

      J. Magn. Magn. Mater. 316

      Pages: e101-e104

    • Peer Reviewed
  • [Journal Article] Nd-Fe-B thick films prepared under high deposition rate of 90μm/h2007

    • Author(s)
      M., Nakano・H., Takeda・F., Yamashita・H., Fukunaga
    • Journal Title

      IEEJ Trans. of Electrical and Electronic Engineering 2

      Pages: 450-452

    • Peer Reviewed
  • [Journal Article] Microstructure of Anisotropic Nd-Fe-B Film Magnets Prepared by Pulsed Laser Deposition2007

    • Author(s)
      M., Ishimaru・M., Itakura・N., Kuwano・S., Sato・M., Nakano・H., Fukunaga
    • Journal Title

      Mater. Sci. Forum 561-565

      Pages: 1131-1134

    • Peer Reviewed
  • [Journal Article] Improvement in soft magnetic properties using magnetostriction2007

    • Author(s)
      H., Fukunaga and T., Yamaguchi,
    • Journal Title

      J. Magn. Magn. Mater. 316

      Pages: e632-e635

    • Peer Reviewed
  • [Journal Article] Patterning and morphology of nonlinear optical Gd_xBi_<1-x>BO_3 crystals in Gd_2O_3-Bi_2O_3-B_2O_3 glasses by YAG laser irradiation2007

    • Author(s)
      K., Koshiba・T., Honma・Y., Benino・T., Komatsu
    • Journal Title

      Appl. Phys. A89

      Pages: 981-986

    • Peer Reviewed
  • [Journal Article] Line patterning of (Sr Ba)Nb_2O_6 crystals in borate glasses by transition atom heat processing2007

    • Author(s)
      M., Sato・T., Honma・Y., Benino・T., Komatsu
    • Journal Title

      J. Solid State Chem. 180

      Pages: 2541-2549

    • Peer Reviewed
  • [Journal Article] Formation of LiNbO_3 crystals at the surface of TeO_2-based glass by YAG laser-induced crystallization2007

    • Author(s)
      H., Sugita・T., Honma・Y., Benino・T., Komatsu
    • Journal Title

      Solid State Commun. 354

      Pages: 280-284

    • Peer Reviewed
  • [Journal Article] Patterning of ferroelectricβ'-Gd_2(MoO_4)_3 crystal lines on the glass surface by transition metal atom heat processing2007

    • Author(s)
      R., Nakajima・T., Honma・Y., Benino・T., Komatsu
    • Journal Title

      J. Ceram. Soc. Jpn. 115

      Pages: 582-587

    • Peer Reviewed
  • [Journal Article] Chemically etched sharpened tip of transparent crystallized glass fibers with nonlinear optical Ba_2TiSi_2O_8 nanocrystals2007

    • Author(s)
      I., Enomoto・Y., Benino・T., Fujiwara・T., Komatsu
    • Journal Title

      J. Ceram. Soc. Jpn. 115

      Pages: 374-378

    • Peer Reviewed
  • [Journal Article] Chemically etched sharpened tip of transparent crystallized glass fibers with nonlinear optical Ba_2TiSi_2O_8 nanocrystals2007

    • Author(s)
      K., Hirose・T., Honma・Y., Benino・T., Komatsu Benino・T., Fujiwara・T., Komatsu
    • Journal Title

      Soled State Ionics 178

      Pages: 801-807

    • Peer Reviewed
  • [Journal Article] Nanocrystalline patterning of K_3Li_2Nb_5O_15 on TeO_2 glasses by an excimer laser2007

    • Author(s)
      M.N., Ahamad・S., Mizuno・T., Komatsu・K.B.R., Varma
    • Journal Title

      J. Crystal Growth. 304

      Pages: 270-274

    • Peer Reviewed
  • [Journal Article] Laser-induced crystallization of β'-RE_2(MoO_4)_3 ferroelectrics (RE: Sm, Gd, Dy) in oxie glasses and their surface morphologies2007

    • Author(s)
      R., Nakajima・M., Abe・Y., Benino・T., Fujiwara・H.G., Kim・T., Komatsu
    • Journal Title

      J. Non-Cryst. Solids 353

      Pages: 85-93

    • Peer Reviewed
  • [Presentation] コウロピウムイオン含有ハロホウ酸塩の合成と蛍光特性2007

    • Author(s)
      町田憲一
    • Organizer
      第24回希士類討論会
    • Place of Presentation
      九州大学医学部 百年講堂
    • Year and Date
      2007-05-17
  • [Remarks]

    • URL

      http://www21.casi.osaka-u.ac.jp/panoscopic

  • [Patent(Industrial Property Rights)] 希土類磁石の製造方法2008

    • Inventor(s)
      町田憲一, 伊東正浩, 西本大夢, 李徳善
    • Industrial Property Rights Holder
      大阪大学
    • Industrial Property Number
      特許特願2008-035403
    • Filing Date
      2008-02-17
  • [Patent(Industrial Property Rights)] 成膜方法及び成膜装置2007

    • Inventor(s)
      福永博俊, 中野正基
    • Industrial Property Rights Holder
      長崎大学
    • Industrial Property Number
      特願2007-262596
    • Filing Date
      2007-10-15

URL: 

Published: 2010-02-04   Modified: 2016-04-21  

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