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2008 Fiscal Year Final Research Report

Creation of High-Performance Thin Holograms based on Polymer Liquid Crystals with Giant Change in Refractive Index

Research Project

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Project/Area Number 16105004
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Research Field Functional materials/Devices
Research InstitutionTokyo Institute of Technology

Principal Investigator

IKEDA Tomiki  Tokyo Institute of Technology, 資源化学研究所, 教授 (40143656)

Co-Investigator(Kenkyū-buntansha) SHISHIDO Atsushi  東京工業大学, 資源化学研究所, 准教授 (40334536)
KINOSHITA Motoi  東京工業大学, 資源化学研究所, 助教 (40361761)
MAMIYA Jun-ichi  東京工業大学, 資源化学研究所, 助教 (80401511)
SHIONO Takeshi  広島大学, 大学院工学研究科, 教授 (10170846)
KURIHARA Seiji  熊本大学, 大学院・自然科学研究科, 教授 (50225265)
KAWATSUKI Nobuhiro  兵庫県立大学, 大学院・工学研究科, 教授 (60271201)
Project Period (FY) 2004 – 2008
Keywordsホログラム / 高分子 / 液晶 / アゾベンゼン / 屈折率
Research Abstract

高複屈折液晶高分子の大きな屈折率変化を利用することにより, 記録書き換え可能・高速応答・高回折効率・高光感度を実現する新規高性能ホログラム材料の開発を行った.さらに, 架橋を施した架橋液晶高分子においては, 分子形状変化を巨視的な運動へ増幅できることを明らかにした.

  • Research Products

    (54 results)

All 2009 2008 2007 2006 2005 2004 Other

All Journal Article (31 results) (of which Peer Reviewed: 31 results) Presentation (6 results) Book (14 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Photomobile Polymer Materials-Various Three-Dimensional Movements2009

    • Author(s)
      M. Yamada, M. Kondo, R. Miyasato, Y. Naka, J.Mamiya, M. Kinoshita, A. Shishido, Y. Yu, C. J Barrett and T. Ikeda
    • Journal Title

      J. Mater. Chem 19

      Pages: 60-62

    • Peer Reviewed
  • [Journal Article] Photocontrolled Translational Motion of aMicroscale Solid Object onAzobenzene-Doped Liquid-Crystalline Films2009

    • Author(s)
      A. Kausar, H. Nagano, T. Ogata, T. Nonaka and S. Kurihara
    • Journal Title

      Angew. Chem. Int. Ed 48

      Pages: 2144-2147

    • Peer Reviewed
  • [Journal Article] Photomobile Polymer Materials - Towards Light-Driven Plastic Motors2008

    • Author(s)
      M. Yamada, M. Kondo, J. Mamiya, Y. Yu, M. Kinoshita, C. J. Barrett and T. Ikeda
    • Journal Title

      Angew. Chem. Int. Ed 47

      Pages: 4986-4988

    • Peer Reviewed
  • [Journal Article] Is Chemical Crosslinking Necessary for the Photoinduced Bending of Polymer Films2008

    • Author(s)
      J. Mamiya, A. Yoshitake, M. Kondo, Y. Yu and T. Ikeda
    • Journal Title

      J. Mater. Chem 18

      Pages: 63-65

    • Peer Reviewed
  • [Journal Article] Subwavelength Modulation of Surface Reliefand Refractive Index in Pre-IrradiatedLiquid-Crystalline Polymer Films2008

    • Author(s)
      H. Yu, A. Shishido and T. Ikeda
    • Journal Title

      Appl. Phys. Lett 92

      Pages: 103117/1-103117/3

    • Peer Reviewed
  • [Journal Article] Well-Defined Liquid-Crystalline DiblockCopolymers with an Azobenzene Moiety : Synthesis, Photoinduced Alignment and theirHolographic Properties2008

    • Author(s)
      H. Yu, Y. Naka, A. Shishido and T. Ikeda
    • Journal Title

      Macromolecules 41

      Pages: 7959-7966

    • Peer Reviewed
  • [Journal Article] Thermally Enhanced PhotoinducedReorientation in Photo-Cross-Linkable LiquidCrystallinePolymers Comprised of Cinnamate and TolaneMesogenic Groups2008

    • Author(s)
      N. Kawatsuki, A. Yamashita, Y. Fujii, C. Kitamura and A. Yoneda
    • Journal Title

      Macromolecules 41

      Pages: 9722-9726

    • Peer Reviewed
  • [Journal Article] Photoinduced Cooperative Reorientation inPhotoreactive Hydrogen-Bonded CopolymerFilms and LC Alignment Using the ResultantFilms2008

    • Author(s)
      N. Kawatsuki, T, Kawanishi and E. Uchida
    • Journal Title

      N. Kawatsuki, T, Kawanishi and E. Uchida Macromolecules 41

      Pages: 4642-4650

    • Peer Reviewed
  • [Journal Article] Photoinduced Cooperative Reorientation inPhotoreactive Hydrogen-Bonded CopolymerFilms and LC Alignment Using the ResultantFilmsRandom Copolymerization of Norbornene withHigher 1-Alkene withansa-Fluorenylamidodimethyltitanium Catalyst2008

    • Author(s)
      T. Shiono, M. Sugimoto, T. Hasan, Z. Cai and T. Ikeda
    • Journal Title

      Macromolecules 41

      Pages: 8292-8294

    • Peer Reviewed
  • [Journal Article] Macro- and Micro- Soft Actuators Based on Liquid-Crystalline Elastomers2008

    • Author(s)
      Y. Yu and T. Ikeda
    • Journal Title

      Angew. Chem. Int. Ed 45

      Pages: 5416-5418

    • Peer Reviewed
  • [Journal Article] Photomechanical Effects of FerroelectricLiquid-Crystalline Elastomers ContainingAzobenzene Chromophores2007

    • Author(s)
      Y. Yu, T. Maeda, J. Mamiya and T. Ikeda
    • Journal Title

      Angew. Chem. Int. Ed 46

      Pages: 881-883

    • Peer Reviewed
  • [Journal Article] Photomechanics of Liquid-Crystalline Elastomers and Other Polymers (Review article)2007

    • Author(s)
      T. Ikeda, J. Mamiya and Y. Yu
    • Journal Title

      Angew. Chem. Int. Ed 46

      Pages: 506-528

    • Peer Reviewed
  • [Journal Article] Formation of Bragg Gratings with LargeAngular Multiplicity by Means of PhotoinducedReorientation of Azobenzene Copolymers2007

    • Author(s)
      A. Saishoji, D. Sato, A. Shishido and T. Ikeda
    • Journal Title

      Langmuir 23

      Pages: 320-326

    • Peer Reviewed
  • [Journal Article] Bragg-type Polarization Gratings Formed inThick Polymer Films Containing Azobenzene andTolane Moieties2007

    • Author(s)
      M. Ishiguro, D. Sato, A. Shishido and T. Ikeda
    • Journal Title

      Langmuir 23

      Pages: 332-338

    • Peer Reviewed
  • [Journal Article] Direct Fabrication of Microlens Arrays with Polarization Selectivity2007

    • Author(s)
      M. Yaegashi, M. Kinoshita, A. Shishido and T. Ikeda
    • Journal Title

      Adv. Mater 19

      Pages: 801-804

    • Peer Reviewed
  • [Journal Article] Stable Macroscopic Nanocylinder Arrays in anAmphiphilic Diblock Liquid-CrystallineCopolymer with Successive Hydrogen Bonds2007

    • Author(s)
      H. Yu, A. Shishido, J. Li, K. Kamata, T. Iyoda and T. Ikeda
    • Journal Title

      J. Mater. Chem 17

      Pages: 3485-3488

    • Peer Reviewed
  • [Journal Article] Photoinduced Nanoscale Cooperative Motion in a Novel Well-Defined Triblock Copolymer2007

    • Author(s)
      H. Yu, S. Asaoka, A. Shishido, T. Iyoda and T. Ikeda
    • Journal Title

      Small 3

      Pages: 768-771

    • Peer Reviewed
  • [Journal Article] Photo-Mechanical Effects in Azobenzene-Containing Soft Materials2007

    • Author(s)
      C. J. Barrett, J. Mamiya, K. G. Yager and T. Ikeda
    • Journal Title

      Soft Matter 3

      Pages: 1249-1261

    • Peer Reviewed
  • [Journal Article] Novel Wormlike NanostructureSelf-Assembled in a Well-DefinedLiquid-Crystalline Diblock Copolymer withAzobenzene Moieties2007

    • Author(s)
      H. Yu, A. Shishido, T. Iyoda and T. Ikeda
    • Journal Title

      Macromol. Rapid Commun 28

      Pages: 927-931

    • Peer Reviewed
  • [Journal Article] Azobenzene Liquid-Crystalline Polymer forOptical Switching of Grating WaveguideCouplers with a Flat Surface2007

    • Author(s)
      C.-U. Bang, A. Shishido and T. Ikeda
    • Journal Title

      Macromol. Rapid Commun 28

      Pages: 1040-1044

    • Peer Reviewed
  • [Journal Article] Azotolane Liquid-Crystalline Polymers : HugeChange in Birefringence by PhotoinducedAlignment Change2006

    • Author(s)
      K. Okano, O. Tsutsumi, A. Shishido and T. Ikeda
    • Journal Title

      J. Am. Chem. Soc 128

      Pages: 15368-15369

    • Peer Reviewed
  • [Journal Article] Photoinduced Alignment of Nanocylinders by Supramolecular Cooperative Motions2006

    • Author(s)
      H. Yu, T. Iyoda and T. Ikeda
    • Journal Title

      J. Am. Chem. Soc 128

      Pages: 11010-11011

    • Peer Reviewed
  • [Journal Article] How Does the Initial Alignment ofMesogens Affect the Photoinduced BendingBehavior of the Azobenzene Liquid-CrystallineElastomers2006

    • Author(s)
      M. Kondo, Y. Yu and T. Ikeda
    • Journal Title

      Angew. Chem. Int. Ed 45

      Pages: 1378-1382

    • Peer Reviewed
  • [Journal Article] Photochemical Phase Transition Behaviorof Highly Birefringent Azo-TolaneLiquid-Crystalline Polymer Films : Effects of thePosition of the Tolane Group and theDonor-Acceptor Substituent in the Mesogen2006

    • Author(s)
      K. Okano, A. Shishido and T. Ikeda
    • Journal Title

      Macromolecules 39

      Pages: 145-152

    • Peer Reviewed
  • [Journal Article] An Azotolane Liquid-Crystalline PolymerExhibiting Extremely Large Birefringence andIts Photoresponsive Behavior2006

    • Author(s)
      K. Okano, A. Shishido and T. Ikeda
    • Journal Title

      Adv. Mater 18

      Pages: 523-527

    • Peer Reviewed
  • [Journal Article] Macroscopic Parallel Nanocylinder Array Fabrication Using a Simple Rubbing Technique2006

    • Author(s)
      H. Yu, J. Li, T. Ikeda and T. Iyoda
    • Journal Title

      Adv. Mater 18

      Pages: 2213-2215

    • Peer Reviewed
  • [Journal Article] Enhancement of Surface-Relief GratingsRecorded on Amphiphilic Liquid-CrystallineDiblock Copolymer by Nano-Scaled PhaseSeparation2005

    • Author(s)
      H. F. Yu, K. Okano, A. Shishido, T. Ikeda, K.Kamata, M. Komura and T. Iyoda
    • Journal Title

      Adv. Mater 17

      Pages: 2184-2188

    • Peer Reviewed
  • [Journal Article] Effect of Ester Moieties in Dye Structures onPhotoinduced Reorientation of Dye-Doped LiquidCrystals2005

    • Author(s)
      M. Yaegashi, A. Shishido, T. Shiono and T. Ikeda
    • Journal Title

      Chem. Mater 17

      Pages: 4304-4309

    • Peer Reviewed
  • [Journal Article] Highly Birefringent Liquid-CrystallinePolymers for Photonic Applications : Synthesis ofLiquid-Crystalline Polymers with Side-ChainAzo-Tolane Mesogens and Their HolographicProperties2005

    • Author(s)
      K. Okano, A. Shishido, O. Tsutsumi, T. Shiono and T. Ikeda
    • Journal Title

      J. Mater. Chem 15

      Pages: 3395-3401

    • Peer Reviewed
  • [Journal Article] Novel Amphiphilic Diblock and TriblockLiquid-Crystalline Copolymers withWell-Defined Structures Prepared by AtomTransfer Radical Polymerization2005

    • Author(s)
      H. Yu, A. Shishido, T. Ikeda and T. Iyoda
    • Journal Title

      Macromol. Rapid Commun 26

      Pages: 1594-1598

    • Peer Reviewed
  • [Journal Article] Effect of Cross-Linking Density onPhotoinduced Bending Behavior of OrientedLiquid-Crystalline Network Films ContainingAzobenzene2004

    • Author(s)
      Y. Yu, M. Nakano, A. Shishido, T. Shiono and T.Ikeda
    • Journal Title

      Chem. Mater 16

      Pages: 1637-1643

    • Peer Reviewed
  • [Presentation] 光運動高分子材料の設計と機能2008

    • Author(s)
      池田富樹
    • Organizer
      第57回高分子年次大会招待講演
    • Place of Presentation
      パシフィコ横浜アネックスホール
    • Year and Date
      2008-05-28
  • [Presentation] 液晶応用の新展開2008

    • Author(s)
      池田富樹
    • Organizer
      2008年(平成20年)春季第55回応用物理学関係連合講演会
    • Place of Presentation
      日本大学舟橋キャンパス
    • Year and Date
      2008-03-29
  • [Presentation] Photomobile Polymer Materials -Towards Light-Driven Plastic Motors-2007

    • Author(s)
      Tomiki Ikeda, Munenori Yamada, Mizuho Kondo,Jun-ichi Mamiya, Motoi Kinoshita, Yanlei Yu
    • Organizer
      Plenary talk at 12th International Topical Meeting on Optics of Liquid Crystals
    • Place of Presentation
      NH Hotel Puebla, Puebla, Mexico
    • Year and Date
      20071001-05
  • [Presentation] Photoresponsive Behavior of Photochromic Liquid-Crystalline Polymers2006

    • Author(s)
      Tomiki Ikeda
    • Organizer
      Plenary talk at 21st International Liquid Crystal Conference
    • Place of Presentation
      Colorado, USA
    • Year and Date
      20060702-07
  • [Presentation] Direction-Controllable Photodeformationn of Liquid-Crystalline Network Films2005

    • Author(s)
      Tomiki Ikeda, Taketo Maeda, Mizuho Kondo, Jun-ichi Mamiya, Motoi Kinoshita, Yanlei Yu
    • Organizer
      Plenary talk at the 11th International TopicalMeeting on Optics of Liquid Crystals (OLC 2005), Marriott Suites Clearwater Beach on Sand Key
    • Place of Presentation
      Florida, USA
    • Year and Date
      20051002-07
  • [Presentation] Direction-Controllable Bending of Liquid-Crystalline Elastomer Films2005

    • Author(s)
      Tomiki Ikeda
    • Organizer
      Invited talk at Gordon Research Conference onElastomers, Networks and GelsConference Chair : Gregory B. MacKenna (TexasTech) ; Vice Chair : H. Henning Winter (UMASS).Colby-Sawyer College
    • Place of Presentation
      New London, NewHampshire
    • Year and Date
      20050717-22
  • [Book] 光アクチュエータ材料としての架橋液晶高分子2008

    • Author(s)
      山田宗紀, 池田富樹
    • Total Pages
      91-93
    • Publisher
      プラスチックス
  • [Book] フォトクロミック液晶高分子を利用した書き換え型ブラッグホログラム2008

    • Author(s)
      宍戸厚, 池田富樹
    • Total Pages
      279-291
    • Publisher
      市村國宏監修「光機能性高分子材料の新たな潮流-最新技術とその展望-」, シーエムシー出版
  • [Book] 光応答性液晶2007

    • Author(s)
      池田富樹
    • Total Pages
      207-214
  • [Book] 機能材料2007

    • Author(s)
      山田宗紀, 池田富樹
    • Total Pages
      13-18
  • [Book] O plus E2007

    • Author(s)
      近藤瑞穂, 池田富樹
    • Total Pages
      11-17
  • [Book] ナノ自己組織化フォトクロミック液晶高分子の高性能ブラッグホログラム2007

    • Author(s)
      宍戸厚, 池田富樹
    • Total Pages
      251-255
    • Publisher
      国武豊喜監修「自己組織化マテリアル」, フロンティア出版, 第5 章 第4 節
  • [Book] 液晶を操る光化学2006

    • Author(s)
      川本益揮, 池田富樹
    • Total Pages
      120-144
    • Publisher
      光化学協会編「光化学の驚異」第5章
  • [Book] 光-力変換機能を有する架橋液晶高分子2006

    • Author(s)
      間宮純一
    • Total Pages
      604
  • [Book] ナノインテリジェント(液晶)材料2005

    • Author(s)
      池田富樹
    • Total Pages
      357-377
    • Publisher
      日本化学会編第5版実験化学講座28「ナノテクノロジーの化学」3 デバイス・応用「新機能ナノ材料」
  • [Book] 高分子液晶2005

    • Author(s)
      木下基, 池田富樹
    • Total Pages
      609-615
    • Publisher
      国武豊喜監修「ナノマテリアルハンドブック」, NTS, 第8章第3節
  • [Book] ナノインテリジェント(液晶)材料2005

    • Author(s)
      池田富樹
    • Total Pages
      357-377
    • Publisher
      日本化学会編第5 版実験化学講座28「ナノテクノロジーの化学」3 デバイス・応用「新機能ナノ材料」
  • [Book] 高分子アゾベンゼン液晶のフォトニクス-ホログラムと光アクチュエータへの応用2004

    • Author(s)
      宍戸厚, 池田富樹
    • Total Pages
      513-519
    • Publisher
      吉野勝美監修「ナノ・IT時代の分子機能材料と素子開発」, NTS, 第1編第6章第2節
  • [Book] 協同現象を利用した高分子光機能材料2004

    • Author(s)
      池田富樹
    • Total Pages
      276-282
    • Publisher
      高分子
  • [Book] 高分子アゾベンゼン液晶フィルムのブラッグ型高回折効率ホログラム2004

    • Author(s)
      宍戸厚, 池田富樹
    • Total Pages
      5-9
    • Publisher
      機能材料
  • [Remarks]

    • URL

      http://www.res.titech.ac.jp/polymer

  • [Patent(Industrial Property Rights)] 光駆動型アクチュエータ, 及び動力伝達システム2007

    • Inventor(s)
      池田富樹, 山田宗紀
    • Industrial Property Number
      特許出願2007-58593
    • Filing Date
      2007-03-08
  • [Patent(Industrial Property Rights)] 光誘起回転方法, 光駆動型回転子, 動力伝達システム, 及び動力伝達装置2006

    • Inventor(s)
      池田富樹, 近藤瑞穂, 山田宗紀
    • Industrial Property Number
      特許出願2006-311412
    • Filing Date
      2006-11-17

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Published: 2010-06-10   Modified: 2016-04-21  

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