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2005 Fiscal Year Final Research Report Summary

Structure and Dynamics of Ions and Free Radicals : Investigations by Submillimeter-wave Spectroscopy

Research Project

Project/Area Number 16350004
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionIbaraki University

Principal Investigator

AMANO Takayoshi  Ibaraki University, College of Science, Professor, 理学部, 教授 (60037249)

Co-Investigator(Kenkyū-buntansha) KASAI Yasuko  NICT, SMILES, Principal Researcher, 主任研究員 (60281630)
Project Period (FY) 2004 – 2005
KeywordsSubmillimeter-wave / Interstellar molecule / Deuterated species / Atmosnheric chemistry / Ions / Free radicals
Research Abstract

This project was planned to pursue a further development of our on-going project on high-resolution spectroscopic investigation of molecular ions and free radicals which had been our main research objectives in the past several years. A major workhorse to promote our investigation is a submillimeter-wave spectrometer system. One such machine had been constructed on the basis of the past several years of research activities. The spectrometer covers the frequency range of 270-860 GHz with three back-ward wave oscillators. During the period of this research project, another similar submillimeter system has been completed. It utilizes a millimeter-wave frequency synthesizer as a local oscillator opposed to a millimeter-wave Gunn oscillator used in the old system. In addition, Fourier transform visible spectroscopy of the Swan system of C_2 and a visible system of C_3 has been carried out as a part of the collaboration with Professor Bernath at University of Waterloo by using a Bruker Fourier transform spectrometer.
Major achievements obtained during this project term are mainly in the following areas.
(1) Spectroscopy of molecular ions. (2) Extended investigation of the Swan band system of C_2. (3) Precise pressure broadening measurements of molecules relevant to the Earth's atmospheric chemistry.

  • Research Products

    (9 results)

All 2006 2005

All Journal Article (9 results)

  • [Journal Article] Submillimeter-wave spectroscopy of HCNH^+ and CH_3CNH^+2006

    • Author(s)
      T.Amano, T.Hirao, K.Hashimoto
    • Journal Title

      Journal of Molecular Structure (accepted)

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Submillimeter-wave lines of H_2D^+ and D_2H^+ as probes into chemistry in cold dark clouds2006

    • Author(s)
      T.Amano
    • Journal Title

      Philosophical Transaction of Royal Society of London A (accepted)

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Submillimeter-wave spectroscopy of HCNH^+ and CH_3CNH^+2006

    • Author(s)
      T.Amano, K.Hashimoto, T.Hirao
    • Journal Title

      Journal of Molecular Structure (in press)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Pressure broadening measurement of submillimeter-wave lines of O_32005

    • Author(s)
      M.M.Yamada, T.Amano
    • Journal Title

      Journal of Quantitative Spectroscopy & Radiative Transfer 95

      Pages: 221-230

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Fourier Transform Emission Spectra of the (000)-(000) Band of the lambda4051.6 Band of C_32005

    • Author(s)
      A.Tanabashi, T.Hirao, T.Amano, P.F.Bernath
    • Journal Title

      Astrophysical Journal 624

      Pages: 1116-1120

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Accurate Rest Frequencies of Submillimeter-wave Lines of H_2D^+ and D_2H^+2005

    • Author(s)
      T.Amano, T.Hirao
    • Journal Title

      Journal of molecular Spectroscopy 233

      Pages: 7-14

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Submillimeter-wave spectroscopy of HN_2^+ and DN_2^+ in the excited vibrational states.2005

    • Author(s)
      T.Amano, T.Hirao, J.Takano
    • Journal Title

      Journal of molecular Spectroscopy 234

      Pages: 170-175

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Accurate Rest Frequencies of Submillimeter-wave Lines of H_2D^+ and D_2H^+2005

    • Author(s)
      T.Amano, T.Hirao
    • Journal Title

      Journal of Molecular Spectroscopy 233

      Pages: 7-14

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Submillimeter-wave spectroscopy of HN_2^+ and DN_2^+ in the excited vibrational states2005

    • Author(s)
      T.Amano, T.Hirao, J.Takano
    • Journal Title

      Journal of Molecular Spectroscopy 234

      Pages: 170-175

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2007-12-13  

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