• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2005 Fiscal Year Final Research Report Summary

Synthesis of tetrapyrrolic N-confused porphyrinoids and exploration their function

Research Project

Project/Area Number 16350024
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionKYUSHU UNIVERSITY

Principal Investigator

FURUTA Hiroyuki  Kyushu University, Faculty of Engineering, Professor, 工学研究院, 教授 (40244157)

Co-Investigator(Kenkyū-buntansha) TOGANOH Motoki  Kyushu University, Faculty of Engineering, Research Associate, 工学研究院, 助手 (80372754)
Project Period (FY) 2004 – 2005
KeywordsN-confused porphyrin / N-fused porphryin / pentaphyrin / anion recognition / renium complex / zinc complex / カドミニウム錯体 / レニウム錯体
Research Abstract

To explore the chemistry of "N-confused porphyrinoids" that has been started from the finding of N-confused porphyrin, metal coordination of NCP and synthesis of N-confused expanded porphyrins were mainly studied.
When Re, a typical metal that can afford a tripodal complex, was subjected for the metal coordination to an NCP ligand, unusual N-fused porphyrin Re complex, whose confused pyrrole ring is inverted and fused to an adjacent pyrrole ring in the porphyrin core, was obtained. This complex we further oxidized to afford a Re trioxo-complex, which catalyzed an oxygen transfer reaction efficiently.
In the synthesis of the confused expanded porphyrins, several new confused octaphyrins and their complexes were obtained. From the x-ray analysis of the octaphyrin complexes, the release of the strain energy by the introduction of confused pyrrole rings was suggested. Furthermore, several new features including near infrared emission and multi-redox were revealed with the doubly confused hexaphyrin complexes.
On the other hand, a different type of confused porphyrin such as pyrazole porphyrin was newly synthesized. The synthetic methodology is thought applicable to other multi-confused porphyrins.

  • Research Products

    (25 results)

All 2006 2005

All Journal Article (24 results) Book (1 results)

  • [Journal Article] Ultrafast Responses of Doubly N-Confused Hexaphyrin Derivatives2006

    • Author(s)
      Ryu, J.H.
    • Journal Title

      Molecular Crystals and Liquid Crystals 445

      Pages: 249/[539]-257[547]

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] A Dozen Years of N-Confusion : From Synthesis to Supramolecular Chemistry2006

    • Author(s)
      Maeda, H.
    • Journal Title

      Pure and Applied Chemistry 78・1

      Pages: 29-44

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] A Entry to Doubly N-Confused [26]Hexaphyrins(1.1.1.1.1.1)from Normal [26]Hexaphyrins(1.1.1.1.1.1)via(Unprecedented Doubly Pyrrolic Rearrangement2006

    • Author(s)
      Suzuki, M.
    • Journal Title

      Chemistry-A European Journal 12・6

      Pages: 1754-1759

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Bis-Iridium(I) Complex of Inverted N-Confused Porphyrin2006

    • Author(s)
      Toganoh, M.
    • Journal Title

      Inorganic Chemistry 45

      Pages: 382-3854

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] 2-Picolinoylpyrrole : A New Entry to Metal Complexing Agent2006

    • Author(s)
      Ono, Y.
    • Journal Title

      Chemistry Letters 35(印刷中)

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Ultrafast Responses of Doubly N-Confused Hexaphyrin Derivatives.2006

    • Author(s)
      Ryu, J.-H., Nagamura, T., Nagai, Y., Matsumoto, R., Furuta, H., Nakamura, K.
    • Journal Title

      Mol.Cryst.Liq.Cryst. 445

      Pages: 249/[539]-257[547]

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] A Dozen Years of N-Confusion : From Synthesis to Supramolecular Chemistry2006

    • Author(s)
      Maeda, H., Furuta, H.
    • Journal Title

      Pure.Appl.Chem. 78

      Pages: 29-44

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] A Entry to Doubly N-Confused [26]Hexaphyrins(1.1.1.1.1.1) from Normal [26]Hexaphyrins(1.1.1.1.1.1) via Unprecedented Doubly Pyrrolic Rearrangement2006

    • Author(s)
      Suzuki, M., Yoon, M.-C., Kim, D.Y., Kwon, J.H., Furuta, H., Kim, D., Osuka, A.
    • Journal Title

      Chem.Eur.J. 12

      Pages: 1754-1759

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Bis-Iridium(I) Complex of Inverted N-Confused Porphyrin2006

    • Author(s)
      Toganoh, M., Konagawa, J., Furuta, H.
    • Journal Title

      Inorg.Chem. 45

      Pages: 3852-3854

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] 2-Picolinoylpyrrole : A New Entry to Metal Complexing Agent2006

    • Author(s)
      Ono, Y., Furuta, H.
    • Journal Title

      Chem.Lett. 35(in press)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] N-Confused Porphine2005

    • Author(s)
      Morimoto, T.
    • Journal Title

      European Journal of Organic Chemistry 18

      Pages: 3887-3890

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Confusion Approach in the Porphyrinoid Chemistry2005

    • Author(s)
      Srinivasan, A.
    • Journal Title

      Accounts of Chemical Research 38・1

      Pages: 10-20

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Recent Development of A Porphyrin Mutant-N-Confused Porphyrin2005

    • Author(s)
      Ishizuka, T.
    • Journal Title

      Journal of Organosynthetic Chemistry (Yuki Gosei Kagaku Kyokaishi) 63・3

      Pages: 211-221

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] N-Fused Pentaphyrins and Their Rhodium Complexes : Oxidation-Indced Rhodium Rearrangement2005

    • Author(s)
      Mori, S.
    • Journal Title

      Chemistry-A European Journal 11・8

      Pages: 2417-2425

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Rhenium Complexes of N-methyl N-Confused Porphyrin and Its Normal Isomer.2005

    • Author(s)
      Toganoh, M.
    • Journal Title

      Chemistry Letters 34・7

      Pages: 1034-1035

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Re(VII)Complex of N-Fused Tetraphenylporphyrin2005

    • Author(s)
      Toganoh, M.
    • Journal Title

      Chemical Communications 36

      Pages: 4589-4591

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Spectroelectrochemical Behaviour of Doubly N-Confused DioxoHexaphyrins2005

    • Author(s)
      Mayer, I.
    • Journal Title

      Journal of Porphyrin and Phthalocyanins. 9

      Pages: 813-820

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] N-Confused Porphine2005

    • Author(s)
      Morimoto, T., Taniguchi, S., Osuka, A., Furuta, H.
    • Journal Title

      Eur.J.Org.Chem.

      Pages: 3887-3890

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Confusion Approach in the Porphyrinoid Chemistry2005

    • Author(s)
      Srinivasan, A., Furuta, H.
    • Journal Title

      Acc.Chem.Res. 38

      Pages: 10-20

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] N-Fused Pentaphyrins and Their Rhodium Complexes : Oxidation-Induced Rhodium Rearrangement2005

    • Author(s)
      Mori, S., Shin, J.-Y., Shimizu, S., Ishikawa, F., Furuta, H., Osuka, A.
    • Journal Title

      Chem.Eur.J. 11

      Pages: 2417-2425

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Recent Development of A Porphyrin Mutant-N-Confused Porphyrin2005

    • Author(s)
      Ishizuka, T., Furuta, H.
    • Journal Title

      J.Organosynth.Chem. 63

      Pages: 211-221

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Rhenium Complexes of N-methyl N-Confused Porphyrin and Its Normal Isomer2005

    • Author(s)
      Toganoh, M., Furuta, H.
    • Journal Title

      Chem.Lett. 34

      Pages: 1034-1035

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Re(VII) Complex of N-Fused Tetraphenylporphyrin2005

    • Author(s)
      Toganoh, M., Ikeda, S., Furuta, H.
    • Journal Title

      Chem.Commun.

      Pages: 4589-4591

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Spectroelectrochemical Behavior of Doubly N-Confused DioxoHexaphyrins2005

    • Author(s)
      Mayer, I., Nakamura, K., Srinivasan, A., Furuta, H., Araki, K.
    • Journal Title

      J. Porphyrin Phthalocyanin. 9

      Pages: 813-820

    • Description
      「研究成果報告書概要(欧文)」より
  • [Book] 「ポルフィリンおよびフラーレンを基体とする超分子連結分子の合成」(分担)「ナノマテリアルハンドブック」(国武豊喜監修)2005

    • Author(s)
      戸叶基樹, 他
    • Total Pages
      566-570(807)
    • Publisher
      エヌ・ティ・エス
    • Description
      「研究成果報告書概要(和文)」より

URL: 

Published: 2007-12-13  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi