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2007 Fiscal Year Final Research Report Summary

Preparation and evaluation of lithium secondary batteries by using thin film technology

Research Project

Project/Area Number 16560272
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionShizuoka University

Principal Investigator

ISAI Masaaki  Shizuoka University, Faculty of Engineering, Professor (80022317)

Project Period (FY) 2004 – 2007
KeywordsLiMN_2O_4 / Li secondary batteries / Manganese oxide films / Magnetron Sputtering / Reactive Evaporation / Rapid Thermal Annealing
Research Abstract

The preparation procedure of manganese oxide films have been investigated from 2005 through 2006. Before starting this research, it was found that manganese oxide (Mn_3O_4) films for lithium secondary batteries have been prepared using a reactive evaporation method. The metallic Mn in the crucible suffers oxidation since it is evaporated in the oxygen atmosphere. So the deposition rate is deteriorated with increasing deposition run.
This research shows a technique which keeps off the Mn evaporant from oxygen atmosphere during the reactive evaporation process. Three types of separators have been developed through our studies: a Mo separator, a stainless steel cell (SUS cell), and a quartz ampoule. They have been installed in the bottom of the Mn crucible. The Mn_3O_4 films could be prepared with high reproducibility with these devices.
During the evaluation of Mn_3O_4 films, it was found that manganese oxide films which involve Li have to be prepared. Preparation of LiMn_2O_4 thin films using a sputtering method was started on 2006. It was found that LiMn_2O_4 thin films could be prepared even at the substrate temperature of room temperature (R.T.) by this method. This material is superior to other materials in the cost performance as well as non-toxic. The crystal properties could be improved after a rapid thermal annealing (RTA) process. The preparation procedure has been sophisticated through this study. The study is now under way.

  • Research Products

    (29 results)

All 2008 2007 2006 2005 2004 Other

All Journal Article (28 results) (of which Peer Reviewed: 4 results) Presentation (1 results)

  • [Journal Article] Effect of doughnut-type disc on preparation of LiMn_2O_4 films prepared by RF magnetron sputtering2008

    • Author(s)
      T. Hosokawa, K. Nakamura, S. Hosoe, S. Sakai, M. Isai
    • Journal Title

      pring Meeting, 2005 The Japan Society of Applied Physics and Related Societies 2, 28p-M-13

      Pages: 646

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] スパッタリング法によるLiMn_2O_4薄膜の生成2007

    • Author(s)
      以西雅章、中村功一、長南祐史
    • Journal Title

      信学技法 ED2007

      Pages: 93-96

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Preparation of LiMn_2O_4 films by sputtering method2007

    • Author(s)
      M. Isai, K. Nakamura, and T. Hosokawa
    • Journal Title

      Inter-Academia 2007 iA & Inter-Academia for young researchers workshop iAY Vol.1

      Pages: 17

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Preparation of manganese oxide films for Li secondary batteries2007

    • Author(s)
      M. Isai, Y. Chonan, and Y. Tojo
    • Journal Title

      Trans. Mater. Res. Jpn 32

      Pages: 1203-1206

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Preparation of LiMn_2O_4 films by sputtering method2007

    • Author(s)
      M. Isai, K. Nakamura, and T. Hosokawa
    • Journal Title

      The 17th Symposium of the Materials Research Society of Japan Program and Abstracts

      Pages: 331

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Preparation of manganese oxide films for Li secondary batteries2007

    • Author(s)
      M. Isai Y. Chonan, Y. Tojo
    • Journal Title

      Trans. Mater. Res. Soc. Jpn Vol.32

      Pages: 1203-1206

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation of LiMn_2O_4 films by sputtering method2007

    • Author(s)
      M. Isai, K. Nakamura, T. Hosokawa
    • Journal Title

      Inter-Academia 2007iA &, Inter-Academia for young researchers workshop iAY Program & Abstracts(Hamamatsu, Romania)

      Pages: 17

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation of LiMn_2O_4 films using sputtering process2007

    • Author(s)
      M. Isai, K. Nakamura, Y. Chonan, T. Hosokawa
    • Journal Title

      Technical Report of IEICE ED 2007-26

      Pages: 93-96

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation of lithium manganese oxide films for lithium secondary batteries by using RF magnetron sputtering method2007

    • Author(s)
      M. Isai, Y. Chonan, Y. Tojo, K. Nakamura, T. Hosokawa, Y. Kurachi, T. Horino
    • Journal Title

      The 54th Spring Meeting, 2005 The Japan Society of Applied Physics and Related Societies 2, 30a-SQ-3

      Pages: 712

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation of LiMn2O4 films by sputtering method2007

    • Author(s)
      M. Isai, K. Nakamura, T. Hosokawa
    • Journal Title

      The 18th Symposium of the Materials Research Society of Japan(Nihon University) Q-P-28-M

      Pages: 331

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Research on reactively evaporated Mn oxide films2006

    • Author(s)
      M. Isai
    • Journal Title

      Trans. Mater. Res. Soc. Jpn Vol.31

      Pages: 1025-1028

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation of manganese oxide films for Li secondary batteries2006

    • Author(s)
      M. Isai
    • Journal Title

      Trans. Mater. Res. Soc. Jpn Vol.31

      Pages: 1037-1040

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation of manganese oxide films for Li secondary batteries2006

    • Author(s)
      M. Isai, Y. Chonan, Y.Tojo
    • Journal Title

      The 5th International Conference on Global research and Education Inter-Academia(Iasi, Romania) Vol.I

      Pages: 185-191

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation of manganese oxide films for Li secondary batteries2006

    • Author(s)
      M. Isai, Y. Chonan, Y. Tojo
    • Journal Title

      Technical Report of IEICE ED 2006-21

      Pages: 7-10

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation of Li-involved Mn oxide filmsLi2006

    • Author(s)
      M. Isai, Y. Nagashio, T. Tatei, H. Fujiyasu
    • Journal Title

      The 53th Spring Meeting, 2005 The Japan Society of Applied Physics and Related Societies 2, 24a-R-6

      Pages: 696

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation of manganese oxide films for Li secondary batteries2006

    • Author(s)
      M. Isai, Y. Chonan, Y. Tojo
    • Journal Title

      The 17th Symposium of the Materials Research Society of Japan(Nihon University) Q-P02

      Pages: 288

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Stabilization of deposition rate of Mn oxide films by using SUS cell2005

    • Author(s)
      M. Isai, Y. Nagashio, T. Tatei, H. Fujiyasu
    • Journal Title

      Trans. Mater.Res.Soc. Jpn Vol.30

      Pages: 1031-1035

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation of manganese oxide films for Li secondary batteries2005

    • Author(s)
      M. Isai, T. Tatei, H. Fujiyasu
    • Journal Title

      Technical Report of IEICE ED 2005-23

      Pages: 39-43

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Prevention of oxidation of Mn evaporated by using a SUS cell2005

    • Author(s)
      M. Isai, Y. Nagashio, T. Tatei, H. Fujiyasu
    • Journal Title

      The 52th Spring Meeting, 2005 The Japan Society of Applied Physics and Related Societies 2, 31a-C-7

      Pages: 740

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Prerparation of manganese oxide films for Li secondary batteries2005

    • Author(s)
      M. Isai
    • Journal Title

      The 66th Fall Meeting, 2005 The Japan Society of Applied Physics and Related Societies 2, 10p-D-5

      Pages: 541

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation of manganese oxide films for Li secondary batteries2005

    • Author(s)
      M. Isai, Yuji, Chonan
    • Journal Title

      The 16th Symposium of the Materials Research Society of Japan(Nihon University) Q1-P02

      Pages: 268

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] (Invited) Trajectory on research on reactively evaporated Mn oxide films2005

    • Author(s)
      M. Isai
    • Journal Title

      The 16th Symposium of the Materials Research Society of Japan(Nihon University) Q1-IO4

      Pages: 276

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] A trial of preventing the oxidation of Mn evaporant during the reactive evaporation2004

    • Author(s)
      M. Isai, K. Kamikihara, H. Shimizu, Y. Nagashio, H. Fujiyasu
    • Journal Title

      4th International conference on Solid State Chemistry(Prague, Czech Republic)

      Pages: 92

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation of Mn_3O_4 films for Li secondary batteries by using quartz ampoule2004

    • Author(s)
      M. Isai, K. Kamikihara, H. Shimizu, Y. Nagashio, H. Fujiyasu
    • Journal Title

      4th International conference on Inorganic Materials(Universuty of Antwerp, Belgium)

      Pages: 241

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation of Mn_3O_4 filmd for secondary batteries by using quartz ampoule2004

    • Author(s)
      M. Isai, K. Kamikihara, H. Shimizu, Y. Nagashio, H. Fujiyasu
    • Journal Title

      Technical Report of IEICE ED 2004-26

      Pages: 19-23

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation of Mn oxide films and stabilization of deposition rate by using SUS cell2004

    • Author(s)
      M. Isai, Y. Nagashio, T. Tatei, H. Fujiyasu
    • Journal Title

      The Institue of Electronics, Tokai Branch Meeting

      Pages: P-015

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Stabillization of deposition rate of Mn oxide films by using SUS cell2004

    • Author(s)
      M. Isai, Y. Nagashio, T. Tatei, H. Fujiyasu
    • Journal Title

      The 15th Symposium of the Materials Research Society of Japan(Nihon University) Q2-P42

      Pages: 252

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation of LiMn_2O_4 films by sputtering method

    • Author(s)
      M. Isai, K. Nakamura, T. Hosokawa
    • Journal Title

      (submitted)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] RFマグネトロンスパッタリング法によるLiMn_2O_4薄膜生成へのドーナツ円板の効果2008

    • Author(s)
      細川貴之、中村功一、細江俊介 酒井里、以西雅章
    • Organizer
      第55回応用物理学関係連合講演会
    • Place of Presentation
      日本大学理工学部船橋
    • Year and Date
      2008-03-28
    • Description
      「研究成果報告書概要(和文)」より

URL: 

Published: 2010-02-04  

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