2018 Fiscal Year Annual Research Report
ＭＯＦを出発原料として用いたキャパシタ用多孔質電極の合成
| Project/Area Number |
16F16722
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| Research Institution | National Institute for Materials Science |
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Principal Investigator |
山内 悠輔 国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, MANA主任研究者 (10455272)
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| Co-Investigator(Kenkyū-buntansha) |
KANETI YUSUF VALENTINO 国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 外国人特別研究員
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| Project Period (FY) |
2016-10-07 – 2019-03-31
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| Keywords | Metal-organic frameworks / Carbon |
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| Outline of Annual Research Achievements |
This year's aim is to develop a general method for producing mesoporous oxide nanosheets using MOFs as sacrificial templates. We demonstrated the general preparation of mesoporous 2D metal-doped Co3O4 nanosheets using MOFs as templates/precursors, including Cu-BTC, Co-BTC, MOF-808 (Zr-BTC) and Fe-BTC. The resulting 2D metal-doped Co3O4 nanosheets exhibited relatively large specific surface areas of up to 120 m2 g-1 with narrow pore size distribution in the mesoporous range. More importantly, the pore size distribution could be controlled by adjusting the calcination temperature of the precursor nanosheets. When employed as electrocatalysts for OER, the Fe-doped Co3O4 nanosheets derived from Fe-BTC exhibited high performance.
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| Research Progress Status |
平成30年度が最終年度であるため、記入しない。
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| Strategy for Future Research Activity |
平成30年度が最終年度であるため、記入しない。
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