• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2008 Fiscal Year Final Research Report

Invention of Conjugated Electronic Structures and Novel Functions

Research Project

  • PDF
Project/Area Number 16GS0209
Research Category

Grant-in-Aid for Creative Scientific Research

Allocation TypeSingle-year Grants
Research InstitutionKyoto University

Principal Investigator

HIYAMA Tamejiro  Kyoto University, 大学院・工学研究科, 教授 (90026295)

Co-Investigator(Kenkyū-buntansha) CHUJO Yoshiki  京都大学, 大学院・工学研究科, 教授 (70144128)
HAYASHI Tamio  京都大学, 大学院・理学研究科, 教授 (00093295)
SHIMIZU Masaki  京都大学, 大学院・工学研究科, 准教授 (10272709)
IKEDA Tomiki  東京工業大学, 資源化学研究所, 教授 (40143656)
KATO Takashi  東京大学, 大学院・工学系研究科, 教授 (70214377)
YOKOYAMA Masaaki  大阪大学, 先端科学イノベーションセンター, 客員教授 (90029281)
YAMAGUCHI Yoshihiro  近畿大学, 理工学部, 准教授 (30200637)
Project Period (FY) 2004 – 2008
Keywords選択的合成・反応 / 有機電子材料・素子 / 液晶材料・素子
Research Abstract

電子共役系有機分子の効率的合成のための革新的合成戦略・方法を創出し,π電子共役系を随意構築する方法論を確立した.これによって新規π共役系モジュールを構築するとともに,その一部を典型金属元素で代用してハイブリッド効果を活用する共役系,すなわちσ-π共役やp-π共役の材料を創製した.これらの新規電子共役系を液晶配向法,オリゴマー形成法あるいは精密重合法を活用して高次構造化させ,電荷輸送能,発光能,非線形光学機能あるいは導電性を示す新規材料を創製した.

  • Research Products

    (13 results)

All 2009 2008 2007 2006 2005

All Journal Article (5 results) Presentation (5 results) Book (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Palladium-catalyzed Intramolecular Coupling of 2-[(2-Pyrrolyl)silyl]aryl Triflates through 1, 2-Silicon Migration2009

    • Author(s)
      K. Mochida, M. Shimizu, T. Hiyama
    • Journal Title

      J. Am. Chem. Soc. 131

      Pages: 8350-8351

  • [Journal Article] Stimuli-responsive Luminescent Liquid Crystals: Change of Photoluminescent Colors Triggered by a Shear-induced Phase Transition2008

    • Author(s)
      Y. Sagara, T. Kato
    • Journal Title

      Angew. Chem. Int. Ed. 47

      Pages: 5175-5178

  • [Journal Article] A Dramatic Effect of Lewis Acid Catalyst on Nickel-catalyzed Carbocyanation of Alkynes2007

    • Author(s)
      Y. Nakao, A. Yada, S. Ebata, T. Hiyama
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 2428-2429

  • [Journal Article] Rigid Molecular Architectures That Comprise a 1, 3, 5-Tri-substituted Benzene Core and Three Oligoaryleneethynylene Arms: Light-emitting Characteristics and p-Conjugation between The Arms2006

    • Author(s)
      Y. Yamaguchi, T. Ochi, S. Miyamura, T. Tanaka, S. Kobayashi, T. Wakamiya, Y. Matsubara, Z. Yoshida
    • Journal Title

      J. Am. Chem. Soc. 128

      Pages: 4504-4505

  • [Journal Article] Arylmagnesiation of Alkynes Catalyzed Cooperatively by Iron and Copper Complexes2005

    • Author(s)
      E. Shirakawa, T. Yamagami, T. Kimura, S. Yamaguchi, T. Hayashi
    • Journal Title

      J. Am. Chem. Soc. 127

      Pages: 17164-17165

  • [Presentation] Invention of Transition Metal-Catalyzed Carbon-Carbon Bond Forming Reactions for Organic Synthesis2009

    • Author(s)
      T. Hiyama
    • Organizer
      The 4th ACP Symposium for Cutting-edge Organic Chemistry
    • Place of Presentation
      Bangkok
    • Year and Date
      20091131
  • [Presentation] Invention of Transition Metal-Catalyzed Carbon-Carbon Bond Forming Reactions for Organic Synthesis2008

    • Author(s)
      T. Hiyama
    • Organizer
      CRC Symposium on Cross-Coupling and Organometallics
    • Place of Presentation
      Stockholm, Sweden
    • Year and Date
      2008-11-03
  • [Presentation] Invention of Transition Metal-Catalyzed Carbon-Carbon Bond Forming Reactions2008

    • Author(s)
      T. Hiyam
    • Organizer
      5th Asian-Europe Symposium
    • Place of Presentation
      Obernai, France
    • Year and Date
      2008-05-26
  • [Presentation] Carbocyanation of Unsaturated Carbon-Carbon Bonds2006

    • Author(s)
      T. Hiyama
    • Organizer
      International Symposium on Organic Chemistry
    • Place of Presentation
      Singapore
    • Year and Date
      2006-12-18
  • [Presentation] Synthetic Reactions of Electron-Conjugated Systems2006

    • Author(s)
      T. Hiyama
    • Organizer
      5th International Forum on Functional Organic Chemicals
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2006-11-19
  • [Book] 電子共役系有機構造体の創製と機能開発2008

    • Author(s)
      檜山爲次郎
    • Total Pages
      324
    • Publisher
      CMC
  • [Patent(Industrial Property Rights)] ベンゼン化合物2008

    • Inventor(s)
      清水正毅, 檜山爲次郎
    • Industrial Property Rights Holder
      国立大学法人京都大学
    • Industrial Property Number
      特許権・特願2009-46049
    • Filing Date
      2008-02-27
  • [Patent(Industrial Property Rights)] 分子末端に電子供与基を導入したポリシアノオリゴフェニレンエチニレン化合物2008

    • Inventor(s)
      山口仁宏, 若宮建昭, 吉田善一
    • Industrial Property Rights Holder
      近畿大学
    • Patent Publication Number
      特許権・特開2009-209073
    • Filing Date
      2008-09-17

URL: 

Published: 2011-06-18   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi