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2008 Fiscal Year Annual Research Report

電子機能物質における自己組織化の解明と応用

Research Project

Project/Area Number 16GS0219
Research InstitutionThe Institute of Physical and Chemical Research

Principal Investigator

加藤 礼三  The Institute of Physical and Chemical Research, 加藤分子物性研究室, 主任研究員 (80169531)

Co-Investigator(Kenkyū-buntansha) 古崎 昭  独立行政法人理化学研究所, 古崎物性理論研究室, 主任研究員 (10238678)
辛 埴  独立行政法人理化学研究所, 励起秩序研究チーム, チームリーダー (00162785)
高木 英典  独立行政法人理化学研究所, 高木磁性研究室, 主任研究員 (40187935)
Keywords電子機能物質 / 自己組織化 / 強相関電子系 / 分子性導体 / 遷移金属酸化物 / ディラックフェルミオン / 有機トランジスタ / フラストレーション
Research Abstract

・分子性導体の薄膜単新結晶をSiO_2/Si基板に張り付けて、電界効果トフンジスタ作成し、有機トランジスタとしては世界最高のデバイス移動度94cm^2/Vsを達成した(加藤)。
・ディラックフェルミオン系特有のゼロモードと呼ばれるLandau準位による負の層間磁気抵抗等の観察によって、α-(ET)_2I_3に続いて、バルクのディラックフェルミオン系を新たに3つ発見した(加藤)。一方、ディラックフェルミオンの量子ホール効果に対する不純物効果を研究し、量子ホールプラト-転移の臨界現象を数値的に調べた。また、ディラックフェルミオン表面状態をもつ、3次元トポロジカル絶縁体の分類理論を作った。フラストレート量子スピン模型について、マグノン束縛状態の凝縮によるスピン多極子秩序やカイラル秩序の形成を理論的に明らかにした(古崎)。
・極めて強いスピン軌道相互作用に付随するエキゾチックな物性や3d電子と比べて比較的大きな遍歴性に注目して、5d Ir酸化物の物質開発を進めた。特に、Ir^<4+>がハニカム格子を形成する新物質Na_2IrO_3が、高次の相互作用により、磁気的に極めて強いフラストレーションが働いていることを明らかにした。また、Ir酸化物の磁性やスピン軌道相互作用を調べるプローブとして、共鳴磁気X線回折の手法を確立した(高木)。
・水晶の共鳴軟X線回折を行い、構造のカイラリティの判定が行えることを明らかにした。この結果を基に、Teやベルリナイト、MnSi等の様々な結晶において構造や磁気カイラリティを持つ秩序構造を明らかにしつつある。また、酸素1s共鳴光電子分光と吸収分光によって、Co及びRh三角格子をもつ強相関熱電材料の電子状態の研究を行い、始状態に酸素ホールが存在することを明らかにした。これらの系の輸送特性がランダムポテンシャル中のホッピングで理解できる可能性を示した(辛、高木)。

  • Research Products

    (72 results)

All 2009 2008

All Journal Article (40 results) (of which Peer Reviewed: 40 results) Presentation (32 results)

  • [Journal Article] Phase sensitive observation of a spin-orbital Mott state in Sr_2IrO_42009

    • Author(s)
      B. J. Kim
    • Journal Title

      Science (in press)

    • Peer Reviewed
  • [Journal Article] NMR relaxation rate and dynamical spin structure factorsin nematic and multipolar liquids of frustrated spin chains under magnetic field2009

    • Author(s)
      M. Sato
    • Journal Title

      Physical Review B79(印刷中)

    • Peer Reviewed
  • [Journal Article] Anomalous duality of 4f electrons in filled skutterudite Ce0s40s122009

    • Author(s)
      M. Matsunami
    • Journal Title

      Physical Review Letters 102

      Pages: 036403

    • Peer Reviewed
  • [Journal Article] Effect of Molecular Packing on Field-Effect Performance of Single Crystals of Thienyl-Substituted Pyrenes2008

    • Author(s)
      M. Ashizawa
    • Journal Title

      Chem. Mater. 20(15)

      Pages: 4883-4890

    • Peer Reviewed
  • [Journal Article] Electric Properties of Mixed Compound [(CH_3)_4N][Ni_xPd_<1-x>(dmit)_2]_22008

    • Author(s)
      A. Fukaya
    • Journal Title

      Journal of the Physical Society of Japan 77(9)

      Pages: 094710/1-094710/5

    • Peer Reviewed
  • [Journal Article] Transport Properties of an Organic Mott Insulator β'-(BEDT-TTF)_2ICI_22008

    • Author(s)
      N. Tajima
    • Journal Title

      Europhysics Letters 83

      Pages: 27008/1-27008/5

    • Peer Reviewed
  • [Journal Article] Strain-induced superconductor/insulator transition and field effect in a thin single crystal of molecular conductor2008

    • Author(s)
      Y. Kawasugi
    • Journal Title

      Applied Physics Letters 92

      Pages: 243508/1-243508/3

    • Peer Reviewed
  • [Journal Article] Electrical Properties and Electronic States of Molecular Conductors Based on Unsymmetrical Organometallic-Dithiolene Gold (III) Complexes2008

    • Author(s)
      K. Kubo
    • Journal Title

      Inorganic Chemistry 47(12)

      Pages: 5495-5502

    • Peer Reviewed
  • [Journal Article] Conduction properties of micro-crystals of 2, 5-dimethyl-N, N'-dicyanoquinonediimine metal (metal=Ag, Cu) complexes on SiO_2/Si substrates2008

    • Author(s)
      H. M. Yamamoto
    • Journal Title

      Solid State Science 10(12)

      Pages: 1757-1761

    • Peer Reviewed
  • [Journal Article] Inhomogeneous site charges at the boundary between the insulating, superconducting, and metallic phases of β"-type bis-ethylenedithio-tetrathiafulvalene molecular chargetransfer salts2008

    • Author(s)
      T. Yamamoto
    • Journal Title

      Physical Review B77

      Pages: 205120/1-205120/5

    • Peer Reviewed
  • [Journal Article] Quantum spin liquid in the spin-1/2 triangular antiferromagnet EtMe_3Sb[Pd(dmit)_2]_22008

    • Author(s)
      T. Itou
    • Journal Title

      Physical Review B77

      Pages: 104413/1-104413/5

    • Peer Reviewed
  • [Journal Article] Suppression of electronic susceptibility in metal-Mott-insulator alternating material (Me-3, 5-DIP)[Ni (dmit)_2]_2 observed using ^<13>C NMR2008

    • Author(s)
      S. Fujiyama
    • Journal Title

      Physical Review B77

      Pages: 060403/1-06043/4

    • Peer Reviewed
  • [Journal Article] Infrared and Raman Study of the Charge-Ordered State in the Vicinity of the Superconducting State in the Organic Conductor β-(meso-DMBEDT-TTF)_2PF_62008

    • Author(s)
      M. Tanaka
    • Journal Title

      Journal of the Physical Society of Japan 77(2)

      Pages: 024714/1-024714/8

    • Peer Reviewed
  • [Journal Article] Supramolecular Insulating Networks sheathing Conducting Nanowires Based on Organic Radical Cations2008

    • Author(s)
      H. M. Yamamoto
    • Journal Title

      ACS Nano 2(1)

      Pages: 143-155

    • Peer Reviewed
  • [Journal Article] Frustrated minority spins in GeNi_2O_42008

    • Author(s)
      M. Matsuda
    • Journal Title

      Europhysics Letters 82

      Pages: 37006

    • Peer Reviewed
  • [Journal Article] X-ray absorption and x-ray magnetic dichroism study on Ca_3CoRhO_6 and Ca_3FeRhO_62008

    • Author(s)
      T. Burnus
    • Journal Title

      Physical Review B77

      Pages: 205111

    • Peer Reviewed
  • [Journal Article] Band Jahn-Teller Instability and Formation of Valence Bond Solid in a Mixed-Valent Spinel Oxide LiRh_2O_42008

    • Author(s)
      Y. Okamoto
    • Journal Title

      Physical Review Letters 101

      Pages: 086404

    • Peer Reviewed
  • [Journal Article] Quantum Hall effect of massless Dirac fermions in avanishins magnetic field2008

    • Author(s)
      K. Nomura
    • Journal Title

      Physical Review Letters 100

      Pages: 246806

    • Peer Reviewed
  • [Journal Article] Boundary multifractality at the integer quantum Hall plateau transition: implications for the critical theory2008

    • Author(s)
      H. Obuse
    • Journal Title

      Physical Review Letters 101

      Pages: 116802

    • Peer Reviewed
  • [Journal Article] Spectral functions of strongly interacting isospin-1/2bosons in one dimension2008

    • Author(s)
      K. A. Matveev
    • Journal Title

      Physical Review Letters 101

      Pages: 170403

    • Peer Reviewed
  • [Journal Article] Vector chiral and multipolar orders in the spin-1/2 frustrated ferromagnetic chain in magnetic field2008

    • Author(s)
      T. Hikihara
    • Journal Title

      Physical Review B78

      Pages: 144404

    • Peer Reviewed
  • [Journal Article] Classification of topological insulators and superconductors in three spatial dimensions2008

    • Author(s)
      A. P. Schnyder
    • Journal Title

      Physical Review B78

      Pages: 195125

    • Peer Reviewed
  • [Journal Article] Right handed or left handed? Forbidden x-ray diffraction reveals chirality2008

    • Author(s)
      Y. Tanaka
    • Journal Title

      Physical Review Letters 100

      Pages: 145502

    • Peer Reviewed
  • [Journal Article] Electronic structure of semiconducting CeFe4P12: strong hybridization and relevance of single-impurity anderson model2008

    • Author(s)
      M. Matsunami
    • Journal Title

      Physical Review B77

      Pages: 165126

    • Peer Reviewed
  • [Journal Article] Temperature-dependent localization excitations of doped carriers in superconducting diamond2008

    • Author(s)
      K. Ishizaka
    • Journal Title

      Physical Review Letters 100

      Pages: 166402

    • Peer Reviewed
  • [Journal Article] Revisiting the valence-band and core-level photoemission spectra of NiO2008

    • Author(s)
      M. Taguchi
    • Journal Title

      Physical Review Letters 100

      Pages: 206401

    • Peer Reviewed
  • [Journal Article] Soft x-ray emission spectroscopy of Co nanoislands on anitrogen-adsorbed Cu (001) surface2008

    • Author(s)
      Y. Takagi
    • Journal Title

      Surface Science 602

      Pages: L65-L68

    • Peer Reviewed
  • [Journal Article] Temperature dependence of the exchange stiffness in FePd (001) thin films: deviation from the empirical law A(T)∝M2s at intermediate temperature2008

    • Author(s)
      M. Mulazzi
    • Journal Title

      Physical Review B77

      Pages: 224425

    • Peer Reviewed
  • [Journal Article] 熱電コバルト酸化物のキャリア・エントロピーの光電子分光による直接観測2008

    • Author(s)
      石田行章
    • Journal Title

      固体物理 43

      Pages: 343-349

    • Peer Reviewed
  • [Journal Article] Comparison of recoil effects in graphite as observed by photoemission, electron scattering, and neutron scattering2008

    • Author(s)
      M. Vos
    • Journal Title

      Physical Review B78

      Pages: 024301

    • Peer Reviewed
  • [Journal Article] σ-bonding contribution of a strong π-acceptor molecule: surfce chemical bond of S02 on Ni (100)2008

    • Author(s)
      T. Tokushima
    • Journal Title

      Physical Review B78

      Pages: 085405

    • Peer Reviewed
  • [Journal Article] Photoemission evidence for a Mott-Hubbard metal-insulator transition in VO_22008

    • Author(s)
      R. Eguchi
    • Journal Title

      Physical Review B78

      Pages: 075115

    • Peer Reviewed
  • [Journal Article] Recoil effect of photoelectrons in the fermi edge of simple metals2008

    • Author(s)
      Y. Takata
    • Journal Title

      Physical Review Letters 100

      Pages: 137601

    • Peer Reviewed
  • [Journal Article] Pressure-induced valence anomaly in TmTe probed by resonantinelastic x-ray scattering2008

    • Author(s)
      I. Jarrige
    • Journal Title

      Physical Review Letters 101

      Pages: 127401

    • Peer Reviewed
  • [Journal Article] Unusual pseudogap features observed in iron oxypnictide superconductors2008

    • Author(s)
      T. Ishida
    • Journal Title

      Journal of the Physical Society of Japan 77 Suppl. C

      Pages: 61-64

    • Peer Reviewed
  • [Journal Article] Low power density multihole cathode very-high-frequency plasma for mixed phase Si:H thin films2008

    • Author(s)
      C. Jariwala
    • Journal Title

      Applied Physics Letters 93

      Pages: 191502

    • Peer Reviewed
  • [Journal Article] Combining photoemission and optical spectroscopies for reliable valence determination in YbS and Yb metal2008

    • Author(s)
      M. Matsunami
    • Journal Title

      Physical Review B78

      Pages: 195118

    • Peer Reviewed
  • [Journal Article] 液体や溶液の価電子状態を元素選択的に観る:SPring-8軟X線ビームラインBL17SUにおける軟X線発光実験2008

    • Author(s)
      徳島高
    • Journal Title

      日本物理学会誌(BUTSURI)

      Pages: 852-857

    • Peer Reviewed
  • [Journal Article] ミオグロビンのFe3d電子状態2008

    • Author(s)
      原田慈久
    • Journal Title

      固体物理 43

      Pages: 711-720

    • Peer Reviewed
  • [Journal Article] Mapping of chemical bonding states of Ag/Si (111) with synchrotron radiation photo emission electron microscopy2008

    • Author(s)
      M. Hashimoto
    • Journal Title

      Surface and Interface Analysis 40

      Pages: 1772-1776

    • Peer Reviewed
  • [Presentation] Spin Liquid State of in the S=1/2 Hyper-Kagome Antiferromagnet Na_4Ir_3O_82009

    • Author(s)
      H. Takagi
    • Organizer
      APS March Meeting
    • Place of Presentation
      Pittsuburgh, USA
    • Year and Date
      2009-03-18
  • [Presentation] Wave function of spin-orbit complex in 5d Mott insulato Sr_2IrO_4 probed by resonant magnetic X-ray diffraction2008

    • Author(s)
      H. Takagi
    • Organizer
      9th Korea-Japan-Taiwan Symposium on Correlated Electron Systems
    • Place of Presentation
      Tamsui, Taiwan
    • Year and Date
      20081120-20081122
  • [Presentation] Time-resolved photoemission study onBi2212 and graphite2008

    • Author(s)
      S. Shin
    • Organizer
      9th Korea-Japan-Taiwan Symposium on Strongly Correlated Electron Systems
    • Place of Presentation
      Tamsui, Taiwan
    • Year and Date
      20081120-20081122
  • [Presentation] Chirality observed by resonant diffraction with circularly polarized x-rays2008

    • Author(s)
      Y. Tanaka
    • Organizer
      9th Korea-Japan-Taiwan Symposium on Strongly Correlated Electron Systems
    • Place of Presentation
      Tamsui, Taiwan
    • Year and Date
      20081120-20081122
  • [Presentation] Probing the photo induced phase transition in (C_2H_5)_2(CH_3)_2Sb[Pd(dmit)_2]_2 I2008

    • Author(s)
      R. Kato
    • Organizer
      The 3rd International Conference on Photo-Induced Phase Transitions and Cooperative Phenomena (PIPT2008)
    • Place of Presentation
      大阪
    • Year and Date
      20081111-20081115
  • [Presentation] Probing the photo induced phase transition in (C_2H_5)_2(CH_3)_2Sb[Pd(dmit)_2]_2 II2008

    • Author(s)
      R. Kato
    • Organizer
      The 3rd International Conference on Photo-Induced Phase Transitions and Cooperative Phenomena (PIPT2008)
    • Place of Presentation
      大阪
    • Year and Date
      20081111-20081115
  • [Presentation] Time-resolved photoemission study on two dimentional materials2008

    • Author(s)
      S. Shin
    • Organizer
      3rd International Conference on Photo-induced Phase Transitions and Coopetarive Phenomena (Yamada Conference LXTTT-PIPT)
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      20081111-20081115
  • [Presentation] Transport Phenomena in Oeganic Zero-Gap Conductors2008

    • Author(s)
      N. Tajima
    • Organizer
      The 2nd International Symposium on Anomalous Quantum Materials (ISAQM2008) and the 7th Asia-Pacific Workshop
    • Place of Presentation
      東京
    • Year and Date
      20081107-20081110
  • [Presentation] Hard x-ray photoelectron spectroscopy at BL29 in SPring-8:Important characteristics and typical applications2008

    • Author(s)
      Y. Takata
    • Organizer
      2008 Advanced Light Source Users' Meeting
    • Place of Presentation
      Berkeley, USA
    • Year and Date
      20081013-20081015
  • [Presentation] ^<13>C NMR study of the spin-liquid state in the triangular quantum antiferromagnet EtMe_3Sb[Pd(dmit)_2]_22008

    • Author(s)
      田村雅史、加藤礼三, ほか
    • Organizer
      Highly Frustrated Magnetism 2008
    • Place of Presentation
      Braunschweig, Germany
    • Year and Date
      20080907-20080912
  • [Presentation] Multi-polar liquids and chiral order in the frustrated ferromagnetic ID chain2008

    • Author(s)
      T. Momoi
    • Organizer
      Highly Frustrated Magnetism 2008
    • Place of Presentation
      Braunschweig, Germany
    • Year and Date
      20080907-20080912
  • [Presentation] Transport properties of massless Dirac fermions system in anorganic conductor α-(BEDT-TTF)_2I_32008

    • Author(s)
      田嶋尚也
    • Organizer
      The 9th International Symposium on Foundations of Quantum Mechanics in the Light of New Technology (ISQM-TOKYO'08)
    • Place of Presentation
      Saitama
    • Year and Date
      20080825-20080828
  • [Presentation] Crystal structures and physical properties of donor type dithiolene complexes with cycloalkane rings2008

    • Author(s)
      K. Kubo, T. Fukunaga, H. M. Yamamoto, R. Kato
    • Organizer
      XXI Congress and General Assembly of the International Union of Crystallography (IUCr2008)
    • Place of Presentation
      大阪
    • Year and Date
      20080823-20080830
  • [Presentation] Exotic properties of Pd(dmit)_2 salts based on various degrees of freedom (dmit=1, 3-dithiole-2-thione-4, 5-dithiolate2008

    • Author(s)
      R. Kato
    • Organizer
      The 21st IUCr Satellite Meeting "Molecular Crystals Exhibiting Exotic Functions
    • Place of Presentation
      大阪
    • Year and Date
      20080821-20080822
  • [Presentation] Electronic structures of metallic and superconducting metal dithiolene complexes2008

    • Author(s)
      R. Kata
    • Organizer
      236th ACS National Meeting & Exposition
    • Place of Presentation
      Philadelphia
    • Year and Date
      20080817-20080821
  • [Presentation] Effects of zero-mode Landau level on transport property in anorganic massless Dirac Fermions system α-(BEDT-TTF)_2I_3 under high pressure2008

    • Author(s)
      N. Tajima, R. Kato
    • Organizer
      25th International Conference on Low Temprature Physics (LT25)
    • Place of Presentation
      Amsterdam, Netherlands
    • Year and Date
      20080807-20080813
  • [Presentation] Effect of Pressure on Conductive Anion-Radical Salt, (DMe-DCNQI)_2Cu2008

    • Author(s)
      R. Kato
    • Organizer
      μSR2008
    • Place of Presentation
      Tsukuba
    • Year and Date
      20080721-20080725
  • [Presentation] Surface multifractality and conformal invariance at 2D metal-insulator transition2008

    • Author(s)
      A. Furusaki
    • Organizer
      Network Models in Quantum Physics
    • Place of Presentation
      Bremen, Germany
    • Year and Date
      20080721-20080725
  • [Presentation] New aspects of pressure-induced superconductivity in anoin radical salts of Pd(dmit)_2 (dmit=1, 3-dithiole-2-thione-4, 5-dithiolate)2008

    • Author(s)
      加藤礼三、田嶋陽子、福永武男
    • Organizer
      ICSM 2008
    • Place of Presentation
      Recife, Brazil
    • Year and Date
      20080706-20080711
  • [Presentation] Field effect on molcular conductors2008

    • Author(s)
      山本浩史、川椙義高、田嶋尚也、福永武男、加藤礼三
    • Organizer
      ICSM 2008
    • Place of Presentation
      Recife, Brazil
    • Year and Date
      20080706-20080711
  • [Presentation] Physical properties and electronic states of cation radical salts based on unsymmetrical type metal-dithiolene complexes2008

    • Author(s)
      久保和也、加藤礼三
    • Organizer
      ICSM 2008
    • Place of Presentation
      Recife, Brazil
    • Year and Date
      20080706-20080711
  • [Presentation] Multi-polar orders in spin-1/2 frustrated magnets2008

    • Author(s)
      T. Momoi
    • Organizer
      Topological Aspects of Solid State Physics
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      20080623-20080627
  • [Presentation] Topological phases of time-reversal invariant superconductors in three dimensions2008

    • Author(s)
      A. Furusaki
    • Organizer
      Topological Aspects of Solid State Physics
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      20080623-20080627
  • [Presentation] The photo-induced phase transition in Et_2Me_2Sb[Pd(dmit)_2]_22008

    • Author(s)
      R. Kato
    • Organizer
      2008 International Conference on Excitonic Processes on Condensed Matter (EXCON'08
    • Place of Presentation
      Kyoto
    • Year and Date
      20080622-20080627
  • [Presentation] Hard x-ray photoelectron spectroscopy2008

    • Author(s)
      Y. Takata
    • Organizer
      21st International conference on x-ray and inner-shell processes (X08)
    • Place of Presentation
      Paris, France
    • Year and Date
      20080622-20080627
  • [Presentation] Time resolved photoemission spectroscopy in graphite2008

    • Author(s)
      T. Togashi
    • Organizer
      XVI Conference on Ultrafast Phenomena (UP2008)
    • Place of Presentation
      Milan, Italy
    • Year and Date
      20080606-20080613
  • [Presentation] Strong spin-orbit coupling effect in 5d Mott insulator Sr_2IrO_4 revealed by magnetic X-ray diffraction2008

    • Author(s)
      H. Takagi
    • Organizer
      Second CoMePhS Workshop in Controlling Phase Separation in Electronic Systems
    • Place of Presentation
      Nafplion, Greece
    • Year and Date
      2008-09-30
  • [Presentation] Spin Liquid State in S=1/2 Hyper-Kagome Antiferromagnet Na_4Ir_3O_82008

    • Author(s)
      H. Takagi
    • Organizer
      Highly Frustrated Magnetism 2008
    • Place of Presentation
      Braunschweig, Germany
    • Year and Date
      2008-09-09
  • [Presentation] Liquid state of spins and charges in geometrically frustrated spinel oxides2008

    • Author(s)
      H. Takagi
    • Organizer
      21th Congress and General Assembly of the International Union of Crystallography
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2008-08-30
  • [Presentation] Physics of 5d Ir oxides2008

    • Author(s)
      H. Takagi
    • Organizer
      Miniworkshop on Strongly Correlated in Materials and Atom Traps
    • Place of Presentation
      Trieste, Italy
    • Year and Date
      2008-08-07
  • [Presentation] Spin liquid ground state in Na_4lr_3O_82008

    • Author(s)
      H. Takagi
    • Organizer
      2008 Correlated Electron Systems Gordon Research Conference
    • Place of Presentation
      Biddeford, USA
    • Year and Date
      2008-06-10
  • [Presentation] Geometrically frustrated transition-metal oxides2008

    • Author(s)
      H. Takagi
    • Organizer
      CIAR-Quantum Materials Program Meeting
    • Place of Presentation
      Toronto, Canada
    • Year and Date
      2008-05-08

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Published: 2010-06-11   Modified: 2016-04-21  

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