2017 Fiscal Year Final Research Report
Synthesis and applicataion of polycarbonyl compounds
| Project/Area Number |
16H06592
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| Research Category |
Grant-in-Aid for Research Activity Start-up
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| Allocation Type | Single-year Grants |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Hokkaido University |
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Principal Investigator |
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| Project Period (FY) |
2016-08-26 – 2018-03-31
|
| Keywords | ポリカルボニル化合物 / 1,3-ジカルボニル / 1,4-ジカルボニル |
|---|
| Outline of Final Research Achievements |
An efficient synthesis of oligomers of aliphatic polycalbonyl compounds was achieved. The oligomers were also successfully converted into flexible ligands and organic chromophores.
An oxidative coupling reaction of enol silyl ether of 3,3-dimethylpentane-2,4-dione gave densely carbonylated oligomers of acetyl acetone derivative bearing 1,3- and 1,4-diketone unit. These oligomers converted into isopyrazole ligand upon treatment with hydrazine and organic chromophores by means of acid treatment.
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| Free Research Field |
有機化学
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