2017 Fiscal Year Final Research Report
Design of Multiple Controlled Polymers Based on Reversible Chain Transfer Cationic Polymerization
| Project/Area Number |
16H06863
|
|---|
| Research Category |
Grant-in-Aid for Research Activity Start-up
|
| Allocation Type | Single-year Grants |
|---|
| Research Field |
Polymer chemistry
|
|---|
| Research Institution | Nagoya University |
|---|
Principal Investigator |
|
|---|
| Project Period (FY) |
2016-08-26 – 2018-03-31
|
| Keywords | 高分子合成 / リビング重合 / カチオン重合 / ラジカル重合 / 立体特異性重合 / 特殊構造高分子 / RAFT重合 / 高分子構造・物性 |
|---|
| Outline of Final Research Achievements |
This study was directed to the control of multiple precise structures based on cationic polymerization via reversible chain transfer mechanism. The reversible chain transfer cationic polymerization was combined with stereospecific cationic polymerization to achieve stereospecific living cationic polymerization, in which both molecular weight and stereoregularity were controlled simultaneously. The control of molecular weight based on reversible chain transfer reaction was also efficient for asymmetric cationic polymerization of benzofuran. In addition, the synthesis of star polymer via cross-linking reactions was achieved by combination cationic and radical RAFT polymerization.
|
| Free Research Field |
化学
|
