• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2018 Fiscal Year Final Research Report

Development of New Fluorination Reactions Aiming for Conversion of Raw Materials in Fluorination

Research Project

  • PDF
Project/Area Number 16K05703
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Organic chemistry
Research InstitutionSaga University

Principal Investigator

KITAMURA Tsugio  佐賀大学, 理工学部, 教授 (00153122)

Co-Investigator(Kenkyū-buntansha) 小山田 重蔵  佐賀大学, 理工学部, 助教 (60525393)
Project Period (FY) 2016-04-01 – 2019-03-31
Keywordsフッ素化反応 / 超原子価ヨウ素 / 有機フッ素化合物 / 触媒反応
Outline of Final Research Achievements

In general, fluorination reactions need fluorine gas as a fluorine source. A safe and convenient fluorination reaction without fluorine gas is desirable. We have developed the safe and convenient fluorine reactions mediated by hypervalent iodine, where safer HF reagents are used as the fluorine source instead of dangerous fluorine gas. Furthermore, catalytic fluorination reactions using iodobenzenes have been developed. We are challenging the raw material conversion of fluorination reactions replacing conventional fluorination reactions using fluorine gas.

Free Research Field

有機化学

Academic Significance and Societal Importance of the Research Achievements

本研究で開発される技術は、従来のフッ素ガスを用いる方法では為し得なかった、安全かつ選択的フッ素化反応が進行させることができる優れた製造方法である。安全性と製造工程の簡便性、さらに重要なコスト面において、従来法をしのぐフッ素化技術である。これまでのフッ素化技術を一変させるフッ素化反応として産業界へ大きく貢献できる意義ある研究である。

URL: 

Published: 2020-03-30  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi