2017 Fiscal Year Final Research Report
Synthesis and functions of chiral helix origo-pyrrin
| Project/Area Number |
16K13951
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Project Period (FY) |
2016-04-01 – 2018-03-31
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| Keywords | ソレノイドコイル / オリゴピリン / 電気伝導 / らせん不斉 / π共役系分子 / らせん分子 / 非平面π共役系分子 / 導電性分子 |
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| Outline of Final Research Achievements |
In designing a electronic circuit with molecular device, it is necessary to combine active elements and passive elements. However, when considering a conventional molecular electronics material, it is necessary to develop a solenoid type electronics material, which is a molecule that functions as a "coil", has not yet been developed. This is probably due to the difficulty of three reasons; 1) designing and synthesizing three-dimensionally conjugated "helical" molecules, 2) the necessity to synthesize and isolate as an optically active substance, 3) the anisotropy control of electric conduction. Therefore, in this study, we focused on the development of π-conjugated helical asymmetric oligopyrine for molecular solenoid coil as a molecular electronics material.
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| Free Research Field |
有機化学
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