Development of Molecular Transformation Through the Synergy of Aluminum and Conjugated Systems

2017 Fiscal Year Final Research Report

• Project/Area Number: 16K13953
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Multi-year Fund
• Research Field: Organic chemistry
• Research Institution: Ibaraki University
• Principal Investigator: Agou Tomohiro 茨城大学, 工学部, 准教授 (90466798)
• Project Period (FY): 2016-04-01 – 2018-03-31
• Keywords: アルミニウム / アルモール / 共役電子系 / 触媒反応 / 分子活性化 / ホスファアルメン

Outline of Final Research Achievements

We have investigated the synthesis and reactivity of alumole (aluminacyclopentadiene)-transition metal complexes as potential catalysts for small molecule activation reactions. Reactivity of stable alumoles with various small molecules were also investigated, while inorganic small molecules, such as dihydrogen and carbon monoxide, did not react with the almoles under ambient conditions. We have investigated the synthesis of phosphaalumenes, Al=P conjugated systems.

Free Research Field

有機典型元素化学