2017 Fiscal Year Final Research Report
Creation of the huge surface area by secondary connection of covalent cage molecules
| Project/Area Number |
16K14070
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Polymer/Textile materials
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| Research Institution | Tohoku University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
高石 慎也 東北大学, 理学研究科, 准教授 (10396418)
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| Project Period (FY) |
2016-04-01 – 2018-03-31
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| Keywords | 多孔性フレームワーク / 有機かご状分子 / 巨大表面積 |
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| Outline of Final Research Achievements |
We have synthesized novel organic cage molecule with using tetraphenylmethane or triptycene. We synthesized porous organic polymer by linking each cage molecule. We masured 13C NMR and confirmed the linking. However, we found that diyne has reacted. In addition, surface area determined by N2 sorption at 77 K indicated that this compound possesses poor porosity. This indicates that the porous framework has collapsed, which is probably related with reaction of diyne part. Thus, we next synthesized alkyl linked framework. We will make characterization and measurements in near future.
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| Free Research Field |
錯体化学
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