2017 Fiscal Year Final Research Report
Fabrication of quantum cellular automaton by using charge degrees of freedom in molecules
| Project/Area Number |
16K17489
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Nanomaterials chemistry
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| Research Institution | University of Hyogo |
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Principal Investigator |
Keishiro Tahara 兵庫県立大学, 物質理学研究科, 助教 (50622297)
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| Project Period (FY) |
2016-04-01 – 2018-03-31
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| Keywords | 分子内電荷移動 |
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| Outline of Final Research Achievements |
Mixed-valence compounds have attracted great interest from the viewpoint of molecular quantum cellular automaton (QCA). In this study, we regard molecular mixed-valence compounds involving two redox-active components as QCA half-cells and aim to obtain insight into controlling charge distributions as information. We constructed homo- and hetero-conjugates by covalently linking redox-active organic and/or organometallic components and clarified the effects of the types of redox-active components and bridging moieties on intramolecular charge transfer. We also explored a chemical method to introduce guest anions as external charges.
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| Free Research Field |
錯体化学
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