2017 Fiscal Year Final Research Report
Sigma/Pi Coordination of Heteroarenes to a Transition Metal Center
Project/Area Number |
16K17884
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Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Multi-year Fund |
Research Field |
Inorganic chemistry
|
Research Institution | Tokyo Institute of Technology |
Principal Investigator |
Yamamoto Koji 東京工業大学, 物質理工学院, 助教 (70647198)
|
Project Period (FY) |
2016-04-01 – 2018-03-31
|
Keywords | ヘテロアレーン / パラジウム / 錯体 / sigma-pi連続性 |
Outline of Final Research Achievements |
The coordination behavior of heteroarenes to a palladium center has attracted much attention since their coordination has been thought to be involved in Pd-catalyzed transformations of heteroarenes. While the eta1-sigma-coordinating heteroarenes complexes have been proposed in the Pd-catalyzed processes, the coordination behavior of heteroarenes has been still elusive. We demonstrated that there is a sigma-pi continuum for eta1-indole-Pd complexes through successful isolation, systematic structure analysis and theoretical calculation analysis of a series of non-anchored indole-Pd(II) complexes.
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Free Research Field |
錯体化学
|