2017 Fiscal Year Final Research Report
Development of atom-economical synthesis of novel semiconducting materials with electron-deficient moiety
| Project/Area Number |
16K17908
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Polymer chemistry
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| Research Institution | Yamagata University |
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Principal Investigator |
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| Project Period (FY) |
2016-04-01 – 2018-03-31
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| Keywords | 直接アリール化反応 / ドナー・アクセプター型分子 / チエノイソインディゴ / 有機薄膜太陽電池 |
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| Outline of Final Research Achievements |
The atom-economical synthesis of donor-acceptor semiconducting materials with an electron-deficient thienoisoindigo (TIG) moiety has been investigated. The desired materials were successfully synthesized under the direct arylation condition by utilizing a monomer design based on a catalytic cycle of direct arylation. Furthermore, an organic photovoltaics study using an obtained polymer was also achieved. To the best of my knowledge, this is the first OPV study using a TIG-based polymer synthesized by the direct arylation.
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| Free Research Field |
高分子合成、機能性高分子
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