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2008 Fiscal Year Final Research Report

Science and Technology of Concentrated Polymer Brushes

Research Project

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Project/Area Number 17002007
Research Category

Grant-in-Aid for Specially Promoted Research

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Chemistry
Research InstitutionKyoto University

Principal Investigator

FUKUDA Takeshi  Kyoto University, 化学研究所, 研究員 (00111972)

Co-Investigator(Kenkyū-buntansha) TSUJII Yoshinobu  京都大学, 化学研究所, 教授 (00217308)
OHNO Kohji  京都大学, 化学研究所, 助教 (00335217)
GOTO Atsushi  京都大学, 化学研究所, 助教 (20335219)
SATO Takaya  鶴岡工業高等専門学校, 物質工学科, 教授 (30399258)
Co-Investigator(Renkei-kenkyūsha) TAKADA Akihiko  九州大学, 先導物質化学研究所, 助教 (20254427)
Project Period (FY) 2005 – 2008
Keywords表面開始LRP / 超高密度ブラシ / 極低摩擦 / サイズ排除 / 新規コロイド結晶
Research Abstract

リビングラジカル重合(LRP)を固体表面に応用して超高密度のグラフト鎖集団「濃厚ポリマーブラシ」を創製するという我々の先駆的研究を合成、物性、応用の3側面から発展させ、関連する新しい研究領域を拓く基盤を築いた。より具体的には、濃厚ポリマーブラシのもつ独自で新規な、時には驚くべき諸性質を掘り起こして体系化するとともに、これに基づく新しい分子デバイス等の概念や、より精緻/汎用的な濃厚ブラシ合成法を開拓した。

  • Research Products

    (62 results)

All 2009 2008 2007 2006 2005 Other

All Journal Article (36 results) (of which Peer Reviewed: 36 results) Presentation (14 results) Book (4 results) Remarks (6 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Reversible Chain Transfer Catalyzed Polymerization (RTCP) with Alcohol Catalysts2009

    • Author(s)
      A. Goto, N. Hirai, T. Wakada, K. Nagasawa, Y. Tsujii, T. Fukuda
    • Journal Title

      ACS Symp. Ser. (in press)

    • Peer Reviewed
  • [Journal Article] Synthesis of Monodisperse Zinc-Sulfide Particles Grafted with Concentrated Polystyrene Brush by Surface-Initiated Nitroxide-Mediated Polymerization2009

    • Author(s)
      V. Ladmiral, T. Morinaga, K. Ohno, T. Fukuda, Y. Tsujii
    • Journal Title

      Eur. Polym. J. (in press)

    • Peer Reviewed
  • [Journal Article] Structural Analysis of "Semisoft" Colloidal Crystals by Confocal Laser Scanning Microscopy2008

    • Author(s)
      T. Morinaga, K. Ohno, Y. Tsujii, T. Fukuda
    • Journal Title

      Macromolecules 41

      Pages: 3620-3626

    • Peer Reviewed
  • [Journal Article] Dispersion of Polymer-Grafted Magnetic Nanoparticles in Homopolymers and Block Copolymers2008

    • Author(s)
      C. Xu, K. Ohno, V. Ladmiral, RJ. Compost
    • Journal Title

      Polymer 49

      Pages: 3568-3577

    • Peer Reviewed
  • [Journal Article] Optimization of Organotellium Transfer Agents for Highly Controlled Living Radical Polymerization2008

    • Author(s)
      E. Kayahara, S. Yamago, Y. Kwak, A. Goto, T. Fukuda
    • Journal Title

      Macromolecules 41

      Pages: 527-529

    • Peer Reviewed
  • [Journal Article] Phase-Separated Structures of Mixed LB Films of Silane-Coupling Agents with Polymerization Initiating Groups and Amphiphilic Carboxylic Acids2008

    • Author(s)
      T. Ishikawa, M. Ejaz, Y. Tsujii, H. Shibata, M. Matsumoto
    • Journal Title

      Colloid. Surf. A-Physicochem. Eng. Asp. 321

      Pages: 76-81

    • Peer Reviewed
  • [Journal Article] High-Pressure Atom Transfer Radical Polymerization of Methyl Methacrylate for Well-Defined Ultrahigh Molecular-Weight Polymers2008

    • Author(s)
      T. Arita, Y. Tsujii, T. Fukuda
    • Journal Title

      Polymer 49

      Pages: 2426-2429

    • Peer Reviewed
  • [Journal Article] Reversible Chain Transfer Catalyzed Polymerization (RTCP) : A New Class of Living Radical Polymerization2008

    • Author(s)
      A. Goto, Y. Tsujii, T. Fukdua
    • Journal Title

      Polymer 49

      Pages: 5177-5185

    • Peer Reviewed
  • [Journal Article] Living Radical Polymerization with Nitrogen Catalyst ; Reversible Chain Transfer Catalyzed Polymerization (RTCP) with N-Iodosuccinimide2008

    • Author(s)
      A. Goto, H. Zushi, N. Hirai, T. Wakada, T. Fukuda
    • Journal Title

      Macromolecules 41

      Pages: 6261-6263

    • Peer Reviewed
  • [Journal Article] Reversible Chain Transfer Catalyzed Polymerizations of Styrene and Methyl Methacrylate with Phosphorus Catalysts2008

    • Author(s)
      A. Goto, N. Hirai, Y. Tsujii, T. Fukuda
    • Journal Title

      Macromol. Symp. 261

      Pages: 18-22

    • Peer Reviewed
  • [Journal Article] Two-Dimensional Ordered Arrays of Monodisperse Silica Particles Grafted with Concentrated Polymer Brushes2007

    • Author(s)
      T. Morinaga, K. Ohno, Y. Tsujii, T. Fukuda
    • Journal Title

      Eur. Polym. J. 43

      Pages: 243-248

    • Peer Reviewed
  • [Journal Article] Internal Phase Separation Drived Dewetting in Polymer Blend and Nanocomposite Films2007

    • Author(s)
      H. Chung, K. Ohno, T. Fukuda, R. J. Composto
    • Journal Title

      Macromolecules 40

      Pages: 384-388

    • Peer Reviewed
  • [Journal Article] Monodisperse Silica Particles Grafted with Concentrated Oxetane-Carrying Polymer Brushes : Their Synthesis by Surface-Initiated Atom Transfer Radical Polymerization and Use for Fabrication of Hollow Spheres2007

    • Author(s)
      T. Morinaga, M. Ohkura, K. Ohno, Y. Tsujii, T. Fukuda
    • Journal Title

      Macromolecules 40

      Pages: 1159-1164

    • Peer Reviewed
  • [Journal Article] Kinetic Study on Role of Ditelluride for Organotellurium-Mediated Living Radical Polymerization (TERP)2007

    • Author(s)
      Y. Kwak, M. Tezuka, A. Goto, T. Fukuda, S. Yamago
    • Journal Title

      Macromolecules 40

      Pages: 1881-1885

    • Peer Reviewed
  • [Journal Article] Highly Controlled Living Radical Polymerization through Dual Activations of Organobismuthines2007

    • Author(s)
      S.Yamago, E. Kayahara, M. Kotani, B. Ray, Y. Kwak, A. Goto, T. Fukuda
    • Journal Title

      Angew. Chem., Int. Ed. 46

      Pages: 1304-1306

    • Peer Reviewed
  • [Journal Article] Surface Interaction of Well-Defined, Concentrated Poly(2-hydroxyethyl methacrylate) Brushes with Proteins2007

    • Author(s)
      C. Yoshikawa, A. Goto, Y. Tsujii, N. Ishizuka, K. Nakanishi, T. Fukuda
    • Journal Title

      J. Polym. Sci.,Part A: Polym. Chem. 45

      Pages: 4795-4803

    • Peer Reviewed
  • [Journal Article] Size-Exclusion Effect and Protein Repellency of Concentrated Polymer Brushes Prepared by Surface-Initiated Living Radical Polymerization2007

    • Author(s)
      C. Yoshikawa, A. Goto, N. Ishizuka, K. Nakanishi, A. Kishida, Y. Tsujii, T. Fukuda
    • Journal Title

      J Macromol. Symp. 248

      Pages: 189-198

    • Peer Reviewed
  • [Journal Article] Germanium- and Tin-Catalyzed Living Radical Polymerizations of Styrene and Methacrylates2007

    • Author(s)
      A. Goto, H. Zushi, N. Hirai, T. Wakada, Y. Kwak, T. Fukuda
    • Journal Title

      Macromol. Symp. 248

      Pages: 126-131

    • Peer Reviewed
  • [Journal Article] Photolysis of an Alkoxyamine Using Intramolecular Energy Transfer from a Quinoline Antenna - Towards Photo- Induced Living Radical Polymerization2007

    • Author(s)
      A. Goto, J. C. Scaiano, L. Maretti
    • Journal Title

      Photochem. Photobio. Sci. 6

      Pages: 833-835

    • Peer Reviewed
  • [Journal Article] Suspensions of Silica Particles Grafted with Concentrated Polymer Brush: Effects of Graft Chain Length on Brush Layer Thickness and Colloidal Crystallization2007

    • Author(s)
      K. Ohno, T. Morinaga, S. Takeno, Y. Tsujii, T. Fukuda
    • Journal Title

      Macromolecules 40

      Pages: 9143-9150

    • Peer Reviewed
  • [Journal Article] Living Radical Polymerizations with Germanium, Tin, and Phosphorus Catalysts-Reversible Chain Transfer Catalyzed Polymerization (RTCP)2007

    • Author(s)
      A. Goto, H. Zushi, N. Hirai, T. Wakada, Y. Tsujii, T. Fukuda
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 13347-13354

    • Peer Reviewed
  • [Journal Article] A Systematic Study on Activation Processes in Organotellurium-Mediated Living Radical Polymerizations (TERPs) of Styrene, Methyl Methacrylate, Methyl Acrylate, and Vinyl Acetate2006

    • Author(s)
      Y. Kwak, A. Goto, T. Fukuda, Y. Kobayashi, and S. Yamago
    • Journal Title

      Macromolecules 39

      Pages: 4671-4679

    • Peer Reviewed
  • [Journal Article] Re-evaluation of Persistent Radical Effect in NMP2006

    • Author(s)
      W. Tang, T. Fukuda, K. Matyjaszewski
    • Journal Title

      Macromolecules 39

      Pages: 4332-4337

    • Peer Reviewed
  • [Journal Article] Suspensions of Silica Particles Grafted with Concentrated Polymer Brush. A New Family of Colloidal Crystals2006

    • Author(s)
      K. Ohno, T. Morinaga, S. Takeno, Y. Tsujii, T. Fukuda
    • Journal Title

      Macromolecules 39

      Pages: 1245-1249

    • Peer Reviewed
  • [Journal Article] Germanium- and Tin-Catalyzed Living Radical Polymerizations of Styrene2006

    • Author(s)
      A. Goto, H. Zushi, Y. Kwak, T. Fukuda
    • Journal Title

      ACS Symp. Ser. 944

      Pages: 595-603

    • Peer Reviewed
  • [Journal Article] Protein Repellency of Well-Defined, Concentrated Poly(2-hydroxyethl methacrylate) Brushes by Size-Exclusion Effect2006

    • Author(s)
      C. Yoshikawa, A. Goto, Y. Tsujii, T. Fukuda, T. Kimura, K. Yamamoto, A. Kishida
    • Journal Title

      Macromolecules 39

      Pages: 2284-2290

    • Peer Reviewed
  • [Journal Article] Mechanism and Kinetics of Dithiobenzoate-Mediated RAFT Polymerization, 1 : The Current Situation2006

    • Author(s)
      C. Barner-Kowollik, T. Fukuda, A. Goto (and 12 coauthors)
    • Journal Title

      J. Polym. Sci., Part A: Polym. Chem. 44

      Pages: 5809-5831

    • Peer Reviewed
  • [Journal Article] Structure and Properties of High-Density Polymer Brushes Prepared by Surface-Initiated Living Radical Polymerization2006

    • Author(s)
      Y. Tsujii, K. Ohno, S. Yamamoto, A. Goto, T. Fukuda
    • Journal Title

      Adv. Polym. Sci. 197

      Pages: 1-45

    • Peer Reviewed
  • [Journal Article] Ionic Liquids Containing The Tetrafluoroborate Anion Have The Best Performance and Stability for Electric Double Layer Capacitor Applications2006

    • Author(s)
      K. Yuyama, G, Masuda, H. Yoshida, T. Sato
    • Journal Title

      J. Power Sources 162

      Pages: 1401-1408

    • Peer Reviewed
  • [Journal Article] Kinetic Study on Reversible Addition-Fragmentation Chain Transfer (RAFT) Process for Block and Random Copolymerizations of Styrene and Methyl Methacrylate2005

    • Author(s)
      K. Kubo, A. Goto, K. Sato, Y. Kwak, T. Fukuda
    • Journal Title

      Polymer 46

      Pages: 9762-9768

    • Peer Reviewed
  • [Journal Article] Mechanism and Kinetics of Organostibine-Mediated Living Radical Polymerization of Styrene2005

    • Author(s)
      Y. Kwak, A. Goto, T. Fukuda, S. Yamago
    • Journal Title

      Zeit. Physik. Chem. 219

      Pages: 283-293

    • Peer Reviewed
  • [Journal Article] Synthesis of Monodisperse Silica Particles Coated with Well-Defined, High-Density Polymer Brushes by Surface-Initiated Atom Transfer Radical Polymerization2005

    • Author(s)
      K. Ohno, T. Morinaga, K. Koh, Y. Tsujii, T. Fukuda
    • Journal Title

      Macromolecules 38

      Pages: 2137-2142

    • Peer Reviewed
  • [Journal Article] Fabrication of High-Density Polymer Brush on Polymer Substrate by Surface-Initiated Living Radical Polymerization2005

    • Author(s)
      C. Yoshikawa, A. Goto, Y. Tsujii, T. Fukuda, K. Yamamoto, A. Kishida
    • Journal Title

      Macromolecules 38

      Pages: 4604-4610

    • Peer Reviewed
  • [Journal Article] Precision Synthesis of A Fluorinated Polyhedral Oligomeric Silsesquioxane-Terminated Polymer and Surface Characterization of Its Blend Film with Poly(methyl methacrylate)2005

    • Author(s)
      K. Koh, S. Sugiyama, T. Morinaga, K. Ohno, Y. Tsujii, T. Fukuda, M. Yamahiro, K. Watanabe, T. Miyashita
    • Journal Title

      Macromolecules 38

      Pages: 1264-1270

    • Peer Reviewed
  • [Journal Article] Fabrication and Electrochemical Properties of High-density Graft Films with Ferrocene Moieties on ITO substrates2005

    • Author(s)
      T. Sakakiyama, H. Ohkita, M. Ohta, S. Ito, Y. Tsujii, T. Fukuda
    • Journal Title

      Chem. Lett. 34

      Pages: 1366-1367

    • Peer Reviewed
  • [Journal Article] Photofunctional Ultrthin Films Prepared by High-Density Graft Polymerization2005

    • Author(s)
      S. Ito, J. Kuno, K. Yamashita, M. Ohoka, H. Ohkita, Y. Tsujii, T. Fukuda
    • Journal Title

      Trans. Mater. Res. Soc. Jpn. 30

      Pages: 687-690

    • Peer Reviewed
  • [Presentation] Synthesis, Structure/Properties, and Functions of Concentrated Polymer Brushes2008

    • Author(s)
      Y. Tsujii(Invited)
    • Organizer
      The IUMRS International Conference in Asia 2008 (IUMRS-ICA 2008)
    • Place of Presentation
      Nagoya
    • Year and Date
      2008-12-10
  • [Presentation] Novel Properties of Concentrated Polymer Brushes2008

    • Author(s)
      Y. Tsujii (Invited)
    • Organizer
      International Conference on Advanced Functional Polymers and Self-Organized Materials 2008 (IC-PSM08)
    • Place of Presentation
      Korea.
    • Year and Date
      2008-09-22
  • [Presentation] Living/Controlled Radical Polymerization and Concentrated Polymer Brushes2008

    • Author(s)
      T. Fukuda (Invited)
    • Organizer
      10th Annual UNESCO/IUPAC Conference on Macromolecules & Materials
    • Place of Presentation
      South Africa
    • Year and Date
      2008-09-08
  • [Presentation] Science and Technology of Concentrated Polymer Brushes2008

    • Author(s)
      T. Fukuda (Invited)
    • Organizer
      236th American Chemical Society Fall National Meeting
    • Place of Presentation
      Philadelphia, USA.
    • Year and Date
      2008-08-18
  • [Presentation] Science and Technology of Concentrated Polymer Brushes2008

    • Author(s)
      T. Fukuda (Invited)
    • Organizer
      IUPAC International Congress on Macromolecular Science - Macro 2008
    • Place of Presentation
      Taipei
    • Year and Date
      2008-06-30
  • [Presentation] Super Lubrication of Concentrated Polymer Brushes in Solvents2008

    • Author(s)
      Y. Tsujii (Invited)
    • Organizer
      トライボロジー国際フォーラム
    • Place of Presentation
      産業技術総合研究所臨海副都心センター
    • Year and Date
      2008-05-15
  • [Presentation] Nanoparticles Densely Grafted with Polymer Chains2007

    • Author(s)
      T. Fukuda (Invited)
    • Organizer
      BASF International Conference on Nanomaterials 2007
    • Place of Presentation
      Singapore
    • Year and Date
      2007-10-21
  • [Presentation] Germanium-, Tin-, and Phosphorus- Catalyzed Living Radical Polymerizations of Styrene and Methacrylates2007

    • Author(s)
      A. Goto (Invited)
    • Organizer
      Hangzhou International Polymer Forum
    • Place of Presentation
      China
    • Year and Date
      2007-05-14
  • [Presentation] Surface-Initiated Living Radical Polymerization and Concentrated Polymer Brushes2006

    • Author(s)
      T. Fukuda (Invited)
    • Organizer
      The 4th IUPAC International Symposium SML' 06
    • Place of Presentation
      Tuscany, Italy.
    • Year and Date
      2006-09-07
  • [Presentation] Synthesis and Applications of Fine Particles Grafted with Concentrated Polymer Brush2006

    • Author(s)
      K. Ohno (Invited)
    • Organizer
      Macro Group UK International Conference on Polymer Synthesis '06
    • Place of Presentation
      Coventry, UK.
    • Year and Date
      2006-08-02
  • [Presentation] Concentrated Polymer Brushes : Surprising New Surfaces Created by Living Radical Polymerization2006

    • Author(s)
      T. Fukuda (Invited)
    • Organizer
      BASF Asian Workshop 2006 on Nanostructured Surfaces
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2006-05-09
  • [Presentation] Concentrated Polymer Brushes : Striking New Surfaces Created by Living Radical Polymerization2006

    • Author(s)
      T. Fukuda (Invited)
    • Organizer
      28th Australasian Polymer Symposium (APS2006)
    • Place of Presentation
      Rotorua, New Zealand.
    • Year and Date
      2006-02-06
  • [Presentation] Surfaces with a Concentrated Polymer Brush : Their Unique and Striking Features2005

    • Author(s)
      T. Fukuda (Invited)
    • Organizer
      Pacifichem International Chemical Congress of Pacific Basin Society
    • Place of Presentation
      Hawaii, USA.
    • Year and Date
      2005-12-17
  • [Presentation] Surface-initiated Living Radical Polymerization and Concentrated Polymer Brushes : Their Unique and Striking Properties2005

    • Author(s)
      T. Fukuda (Invited)
    • Organizer
      230th ACS Fall National Meeting & Exposition
    • Place of Presentation
      Washington DC, USA.
    • Year and Date
      2005-08-29
  • [Book] 濃厚ポリマーブラシ 超分子サイエンス〜基礎から材料への展開〜(国武豊喜監修編), 3.3.8節2008

    • Author(s)
      辻井、大野、福田
    • Publisher
      エヌ・ティー・エス
  • [Book] Grafting and Polymer Brushes on Solid Surfaces, Macromolecular Engineering. Precise Synthesis, Materials Properties, Applications (K. Matyjaszewski, Y. Gnanou, L. Leibler, Eds.)2007

    • Author(s)
      T. Fukuda, Y. Tsujii, K. Ohno
    • Total Pages
      1137-1178
    • Publisher
      Wiley-VCH, Weinheim
  • [Book] 濃厚ポリマーブラシの調製と特性, 機能物質の集積膜と応用展開(関隆広編)2006

    • Author(s)
      辻井、福田
    • Total Pages
      83-93
    • Publisher
      シーエムシー出版
  • [Book] ナノコンポジットマテリアル, 無機界面からのグラフト重合(井上明久編)2005

    • Author(s)
      辻井、福田
    • Total Pages
      261-266
    • Publisher
      フロンティア出版
  • [Remarks] 新聞報道等

  • [Remarks] (1) 電子材料、2008年11月、「京都大学が高性能高分子材料の超低コスト製造方法を開発」

  • [Remarks] (2) 化学工業日報、2008年9月12日、「低コストLRP法開発」.

  • [Remarks] (3) 化学工業日報、2006年10月2日、「材料表面の新改質法」.

  • [Remarks] (4) 日経産業新聞、2006年9月21日、「結晶化の新技術」.

  • [Remarks]

    • URL

      http://www.cpm.kuicr.kyoto-u.ac.jp/05/index.html

  • [Patent(Industrial Property Rights)] イオン液体ポリマー複合微粒子を用いた高分子固体電解質2007

    • Inventor(s)
      辻井敬亘、大野工司、福田 猛、佐藤貴哉
    • Industrial Property Rights Holder
      国立大学法人京都大学、独立行政法人国立高等専門学校機関
    • Industrial Property Number
      特許出願2007-227782
    • Filing Date
      2007-09-03
  • [Patent(Industrial Property Rights)] リン化合物を触媒として用いた新規リビングラジカル重合法2007

    • Inventor(s)
      後藤淳、福田猛、辻井敬亘
    • Industrial Property Rights Holder
      国立大学法人京都大学
    • Industrial Property Number
      特許出願2007-125009
    • Filing Date
      2007-05-09

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Published: 2010-06-10   Modified: 2016-04-21  

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