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2009 Fiscal Year Final Research Report

Basic Processes in Hydrogen Atom-Surface Reactions: Spin Effect, Reaction Dynamics, and Origin of Interstellar Hydrogen Molecules

Research Project

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Project/Area Number 17002011
Research Category

Grant-in-Aid for Specially Promoted Research

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Engineering
Research InstitutionKyushu Institute of Technology

Principal Investigator

NAMIKI Akira  Kyushu Institute of Technology, 工学研究院, 教授 (40126941)

Project Period (FY) 2005 – 2009
Keywords水素原子 / シリコン表面 / 吸着脱離 / スピン偏極原子 / 反応ダイナミックス / 水氷表面
Research Abstract

The reaction of hydrogen atoms on Si, Ru, and water ice surfaces has been studied to elucidate kinetics and dynamics of thermal desorption as well as hydrogen abstraction of hydrogen adatoms. A historically long standing problem raised in hydrogen desorption from Si(100) surfaces is solved. In contrast to Si or Ru surfaces, a hydrogen molecular desorption due to abstraction is not confirmed on water ice surfaces even at around 10 K, suggesting that residence time of hydrogen atoms is very short on the water ice surfaces. A spin-polarized-hydrogen-surface reaction system is constructed to investigate spin dependence on hydrogen sticking onto Si(111) surfaces.

  • Research Products

    (22 results)

All 2010 2009 2008 2007 2006

All Journal Article (15 results) (of which Peer Reviewed: 15 results) Presentation (5 results) Book (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Si(100)表面での水素解離の活性障壁と脱離エネルギー:バリアパズルはどこまでわかったか2010

    • Author(s)
      並木章
    • Journal Title

      真空 53,(4)

      Pages: 1-11

    • Peer Reviewed
  • [Journal Article] 水素ラジカルが誘起するSi表面反応2010

    • Author(s)
      並木章
    • Journal Title

      表面科学 31

      Pages: 124-130

    • Peer Reviewed
  • [Journal Article] D abstraction by H at a D-saturated Ru (001) surface2009

    • Author(s)
      T. Yamauchi, Y. Nakashima, T. Misumi, K. Mine, A. Namiki
    • Journal Title

      Surf. Sci. 603

      Pages: 2333-2339

    • Peer Reviewed
  • [Journal Article] Crystalization of D2O thin films on Ru(001) surfaces2009

    • Author(s)
      T. Yamauchi, K. Mine, Y. Nakashima, A. Izumi, A. Namiki
    • Journal Title

      Appl. Surf. Sci. 256

      Pages: 1124-1127

    • Peer Reviewed
  • [Journal Article] Time-of-flight distributions of HD molecules abstracted at a Si(100) surface2009

    • Author(s)
      S. Sato, Y. Narita, A.R. Khan, A. Namiki
    • Journal Title

      Surf. Sci. 603

      Pages: 2607-2611

    • Peer Reviewed
  • [Journal Article] Substantially low desorption barriers in recombinative desorption of deuterium from the Si(100) surface2009

    • Author(s)
      Y. Narita, Y. Kihara, S. Inanaga, A. Namiki
    • Journal Title

      Surf. Sci. 603

      Pages: 1168-1174

    • Peer Reviewed
  • [Journal Article] Angular distribution of H-induced HD and D2 desorptions from the Si(100) surfaces. -Response2008

    • Author(s)
      S. Inanaga, T. Kiyonaga, F. Rahman, F. Khanom, A. Namiki
    • Journal Title

      J. Lee, J. Chem. Phys. 128

      Pages: 0171021-1

    • Peer Reviewed
  • [Journal Article] Oxidation and reduction of thin Ru films by gas plasma2008

    • Author(s)
      Y. Iwasaki, A. Izumi, H. Tsurumaki, A. Namiki, H. Oizumi, I. Nishiyama
    • Journal Title

      Appl. Surf. Sci. 253

      Pages: 8699-8704

    • Peer Reviewed
  • [Journal Article] Scattering of 300 K effusive beams from the H/Si(100) surface2008

    • Author(s)
      S. Ueno, Y. Narita, A.R. Khan, Y. Kihara, A. Namiki
    • Journal Title

      Surf. Sci. 602

      Pages: 1979-1986

    • Peer Reviewed
  • [Journal Article] Adsorption and abstraction of atomic hydrogen on the Si(110) surfaces2008

    • Author(s)
      A.R. Khan, Y. Narita, A. Namiki, A. Kato, M. Suemitsu
    • Journal Title

      Surf. Sci. 602

      Pages: 1979-1986

    • Peer Reviewed
  • [Journal Article] Optical second-harmonic generation study of incorporation of nitrogen atoms at Si(100) surfaces2007

    • Author(s)
      H. Tsurumaki, E. Kuroki, I. Ishida, Y. Tohara, A. Namiki
    • Journal Title

      Surf. Sci. 601

      Pages: 4629-4635

    • Peer Reviewed
  • [Journal Article] Transient desorption of HD and D2 molecules from the D/Si(100) surfaces exposed to a modulated H-beam2007

    • Author(s)
      A.R. Khan, A. Takeo, S. Ueno, S. Inanaga, T. Yamauchi, Y. Narita, T. Tsurumaki, A. Namiki
    • Journal Title

      Surf. Sci. 601

      Pages: 1635-1641

    • Peer Reviewed
  • [Journal Article] Desorption related adsorption of hydrogen via detailed balance on the Si(100) surfaces2006

    • Author(s)
      A. Namiki
    • Journal Title

      Prog. Surf. Sci. 81

      Pages: 337-366

    • Peer Reviewed
  • [Journal Article] Angular distributions of H-induced HD and D2 desorptions from the Si(100) surfaces2006

    • Author(s)
      S. Inanaga, T. Kiyonaga, F. Rahman, F. Khanom, A. Namiki, J. Lee
    • Journal Title

      J. Chem. Phys. 124

      Pages: 0547151-5

    • Peer Reviewed
  • [Journal Article] Desorption dynamics of deuterium molecules from the Si(100)-(3x1) dideuteride surface2006

    • Author(s)
      T. Niida, H. Tsurumaki, A. Namiki
    • Journal Title

      J. Chem. Phys. 124

      Pages: 0247151-5

    • Peer Reviewed
  • [Presentation] Si(100)表面での拡散支援機構に従う水素熱脱離における脱離サイトの検討2010

    • Author(s)
      成田克, 上杉功, 稲永征司, 並木章
    • Organizer
      第57回応用物理学関係連合講演会
    • Place of Presentation
      東海大学
    • Year and Date
      20100317-20100320
  • [Presentation] D+D2O/Ru共吸着表面からの水素引き抜き反応2009

    • Author(s)
      山内貴志、嶺和幸、並木章
    • Organizer
      第50回真空に関する連合講演会
    • Place of Presentation
      学習院創立百周年記念会館
    • Year and Date
      20091104-20091106
  • [Presentation] D吸着Si表面から引き抜かれたHD分子の飛行時間分布測定2009

    • Author(s)
      安冨伍郎, 佐藤真一郎, 吉田佑太郎, A.R. Khan, 成田克, 並木章
    • Organizer
      第56回応用物理学関係連合講演会
    • Place of Presentation
      筑波大学
    • Year and Date
      20090330-20090402
  • [Presentation] スピン偏極水素原子線の生成と磁場反転法によるスピン反転2009

    • Author(s)
      鶴巻浩, 西川峻一, 豊田尚志, 古賀祐太郎, 實松敦, 並木章
    • Organizer
      第56回応用物理学関係連合講演会
    • Place of Presentation
      筑波大学
    • Year and Date
      20090330-20090402
  • [Presentation] IRAS study on crystallization process of thin D2O ice films on Ru(0001) surface2008

    • Author(s)
      K. Mine, Y, Nakashima, T. Yamauchi, A. Namiki
    • Organizer
      4th Vacuum and Surf. Sci. Conf. of Asia and Australia
    • Place of Presentation
      Matsue
    • Year and Date
      20081028-20081031
  • [Book] "水素-シリコン表面反応", "水素, 将来のエネルギー利用を目指して"(並木章)2006

    • Author(s)
      西川正史, 深田智, 渡辺幸信, 共編
    • Total Pages
      196-223
    • Publisher
      養賢堂
  • [Patent(Industrial Property Rights)] 原子状水素定量方法及びその装置2008

    • Inventor(s)
      並木章, 和泉亮, 鶴巻浩
    • Industrial Property Rights Holder
      国立大学法人九州工業大学
    • Industrial Property Number
      日本国特許・4072627
    • Acquisition Date
      2008-02-01

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Published: 2011-06-18   Modified: 2016-04-21  

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