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2006 Fiscal Year Annual Research Report

次世代共役ポリマーの超階層制御と革新機能

Research Project

Project/Area Number 17067002
Research InstitutionKyoto University

Principal Investigator

赤木 和夫  京都大学, 工学研究科, 教授 (20150964)

Co-Investigator(Kenkyū-buntansha) 増田 俊夫  京都大学, 工学研究科, 教授 (60026276)
金藤 敬一  九州工業大学, 大学院生命体工学研究科, 教授 (70124766)
藤木 道也  奈良先端科学技術大学院大学, 物質創成科学研究科, 教授 (00346313)
河合 壯  奈良先端科学技術大学院大学, 物質創成科学研究科, 教授 (40221197)
Keywords共役高分子 / 超階層構造 / 若手育成 / らせん構造 / 非線形現象
Research Abstract

本総括班では本領域の進捗と研究の推進を総括し、特に関連学域の深化と新たな融合研究の創出を目指してシンポジウム開催などに取り組んできた。公開シンポジウムについては平成18年6月19日、20日に第3回公開シンポジウム、平成19年1月15日、16日に第4回公開シンポジウムを開催した。それぞれの参加者人数は158名と166名で、きわめて盛況であった。また第4回公開シンポジウムでは一般公募を含め合計86件のポスター発表を行った。また2編のニュースレターを刊行し、全国の関連研究者約300名に配布した。一方、ホームページにより本領域の趣旨、班員の研究計画と業績、さらに行事開催予定などの情報を公開してきた。総括班としての計画立案と総括のために2回の総括班会議を開催した。また、各班ごとの共同研究を進めることを目標に、それぞれ2回の班会議を開催した。さらに、国際化の推進のために第1回超階層制御国際ワークショップを平成19年3月18日に開催した。当領域での特徴的な取り組みとして(1)領域内の共同研究の推進、(2)若手研究者の育成のの2点を掲げ、重点的な取り組みを推進してきた。共同研究の推進策の一例として、班会議においては他班からの同伴出席者を求める同伴制度を採用し、班内および班間での共同研究の可能性を追求した。その結果、共同研究に関する共著論文をはじめ多数の連名の学会発表などの成果が出つつある。一方、若手研究者の育成の目的のため前年度結成した"超階層制御若手の会"を引き続き運営・拡大し第2回および第3回超階層制御若手フォーラムを開催し(平成18年6月20日、21日、平成19年1月14日、15日)、招待講演者や学生を含めてそれぞれ35名および40名の参加を得て、若手研究者の交流とディスカッションを深めた。今後の融合共同研究や共同研究提案などが期待できる。

  • Research Products

    (46 results)

All 2007 2006

All Journal Article (41 results) Book (5 results)

  • [Journal Article] Synthesis and Properties of Liquid-Crystalline-Conjugated Polymers2007

    • Author(s)
      K.Akagi
    • Journal Title

      BULL. CHEM. SOC. JPN. 80・4

      Pages: 649-661

  • [Journal Article] Chiral 1-methylpropargyl alcohol : A simple and powerful helical source for substituted polyacetylenes2007

    • Author(s)
      Y.Suzuki, M.Shiotsuki, F.Sanda, T.Masuda
    • Journal Title

      MACROMOLEC. 40・6

      Pages: 1864-1867

  • [Journal Article] Synthesis and characteristics of poly(macromonomers) and graft copolymers composed of poly(phenylacetylene) main chain and poly(ethylene oxide) side chains2007

    • Author(s)
      W.Zhang, M.Shiotsuki, T.Masuda
    • Journal Title

      MACROMOLEC. 40・5

      Pages: 1421-1428

  • [Journal Article] Synthesis of polymer brushes composed of poly(phenylacetylene) main chain and either polystyrene or poly(methyl methacrylate) side chains2007

    • Author(s)
      W.Zhang, M.Shiotsuki, T.Masuda, J.Kumaki, E.Yashima
    • Journal Title

      MACROMOLEC. 40・2

      Pages: 178-185

  • [Journal Article] Minimization of contact resistance between metals and polymer by surface doping2007

    • Author(s)
      A.K.Mukherjee, A.K.Thakur, W.Takahima, K.Kaneto
    • Journal Title

      J.PHYS.D.APPL.PHYS. 40・6

      Pages: 1789-1793

  • [Journal Article] Ambipolar Field Effect Transistors Based on Poly(3-hexylthiophene) / Fullerene Derivative Bi-layer Films2007

    • Author(s)
      K.Kaneto, M.Yano, M.Shibao, T.Morita, W.Takashima
    • Journal Title

      JPN.J.APP.PHYS. 46・4

      Pages: 1736-1738

  • [Journal Article] Ambipolar transport and light effect in Field effect transistors based on composite films of poly(3-hexlythiophene) and fullerene derivatives2007

    • Author(s)
      M.Shibao, T.Morita, W.Takashima, K.Kaneto
    • Journal Title

      JPN.J.APP.PHYS. 46・6

      Pages: L123-L125

  • [Journal Article] Conducting polymer soft actuators based on polypyrrole films - energy conversion efficiency-2007

    • Author(s)
      K.Kaneto, H.Fujisue, M.Kunifusa, W.Takashima
    • Journal Title

      SMART MATER.STRUCT. 16・2

      Pages: S250-S255

  • [Journal Article] Switching in Orientation of Macromolecular Helical Rod Silicon on the solid SurfacesMacromolecules2007

    • Author(s)
      M.Naito, N.Saeki, M.Fujiki, A.Ohira
    • Journal Title

      MACROMOLEC. 40・2

      Pages: 648-652

  • [Journal Article] Highly Organized Phthalocyanine Assembly onto Gold Surface : through Spontaneous Polymerization2007

    • Author(s)
      M.Ishikawa, M.Naito, M.Fujiki
    • Journal Title

      CHEM.LETT. 36

      Pages: 304-305

  • [Journal Article] Vertically Aligned Polypyrrole Drawing a Fingerprint Array Prepared by Electrochemical Polymerization in Chiral Nematic Electrolyte2006

    • Author(s)
      H.Goto, K.Akagi
    • Journal Title

      J.POLYM.SCI.PART A : POLYM. CHEM. 44・2

      Pages: 1042-1047

  • [Journal Article] Optically Active Electrochromism of Poly(3,4-ethylenedioxythiphene) Synthesized by Electrochemical Polymerization in Lyotropic Liquid Crystal of Hydroxypropyl Cellulose/Water - Active Control of Optical Activity by Electrochemical Method2006

    • Author(s)
      H.Goto, K.Akagi
    • Journal Title

      CHEM.MATER. 18・2

      Pages: 255-262

  • [Journal Article] Microscopic Orientational Order of Polymer Chains in Helical Polyacetylene Thin Films Studied by Confocal Laser Raman Microscopy2006

    • Author(s)
      M.Ofuji, Y.Takano, Y.Houkawa, Y.Takanishi, K.Ishikawa, H.Takezoe, T.Mori, M.Goh, S.Guo, K.Akagi
    • Journal Title

      JPN.J.APPL.PHYS. 45・3A

      Pages: 1710-1713

  • [Journal Article] Syntheses of Highly Twisted Helical Polyacetylene under Nano-order Chiral Nematic Liquid Crystal Reaction Field2006

    • Author(s)
      M.J.Goh, M.Kyotani, K.Akagi
    • Journal Title

      CURRENT APPL.PHYS. 6・5

      Pages: 948-951

  • [Journal Article] Vertically Aligned Helical Polyacetylene Synthesized in Chiral Nematic Liquid Crystal under Magnetic Field2006

    • Author(s)
      T.Matsushita, M.J.Goh, M.Kyotani, K.Akagi
    • Journal Title

      CURRENT APPL.PHYS. 6・5

      Pages: 952-955

  • [Journal Article] Synthesis and Properties of PEDOT Derivatives Containing Liquid Crystalline Groups2006

    • Author(s)
      Y.S.Jeong, H.Goto, J.R.Reynolds, K.Akagi
    • Journal Title

      CURRENT APPL.PHYS. 6・5

      Pages: 956-959

  • [Journal Article] Chiral BEDOT-based Copolymers Prepared by Chemical and Electrochemical Polymerization2006

    • Author(s)
      Y.S.Jeong, H.Goto, S.Iimura, T.Asano, K.Akagi
    • Journal Title

      CURRENT APPL. PHYS. 6・5

      Pages: 960-963

  • [Journal Article] Structural Properties of Pyrolytic Carbon from Structure-controlled Polyacetylene Thin Films2006

    • Author(s)
      M.Kyotani, S.Matsushita, T.Nagai, Y.Matsui, K.Akagi
    • Journal Title

      CURRENT APPL. PHYS. 6・5

      Pages: 956-959

  • [Journal Article] Effect of diene ligands in the rhodium-catalyzed polymerization of phenylacetylene2006

    • Author(s)
      I.Saeed, M.Shiotsuki, T.Masuda
    • Journal Title

      MACROMOLEC. 39・26

      Pages: 8977-8981

  • [Journal Article] Novel optically active polyacetylenes : Synthesis and helical conformation of L-lysine-dendronized poly (phenylacetylene)2006

    • Author(s)
      HC.Zhao, F.Sanda, T.Masuda
    • Journal Title

      MACROMOLEC.CHEMI.PHYS. 207・21

      Pages: 1921-1926

  • [Journal Article] Nanoporous, honeycomb-structured network fibers spun from semiflexible, ultrahigh molecular weight, disubstituted aromatic polyacetylenes : Superhierarchical structure and unique optical anisotropy2006

    • Author(s)
      G.Kwak, S.Fukao, M.Fujiki, T.Sakaguchi, T.Masuda
    • Journal Title

      CHEM.MATER. 18・23

      Pages: 5537-5542

  • [Journal Article] Synthesis and properties of polyacetylenes carrying N-phenylcarbazole and triphenylamine moieties2006

    • Author(s)
      JQ.Qu, R.Kawasaki, M.Shiotsuki, F.Sanda, T.Masuda
    • Journal Title

      POLYMER 47・19

      Pages: 6551-6559

  • [Journal Article] Synthesis, characterization, and gas permeation properties of silylated derivatives of ethyl cellulose2006

    • Author(s)
      FZ.Khan, T.Sakaguchi, M.Shiotsuki, Y.Nishio, T.Masude
    • Journal Title

      MACROMOLEC. 39・18

      Pages: 6025-6030

  • [Journal Article] Synthesis of substituted polyacetylenes grafted with polystyrene chains by the macromonomer method and their characterization2006

    • Author(s)
      W.Zhang, M.Shiotsuki, T.Masuda
    • Journal Title

      MACROMOLEC.CHEMI. HYS. 207・11

      Pages: 933-940

  • [Journal Article] Polymerization of o-diethynylbenzene and its derivatives controlled by transition metal catalyst systems2006

    • Author(s)
      W.Zhang, M.Shiotsuki, T.Masuda
    • Journal Title

      POLYMER 47・9

      Pages: 2956-2961

  • [Journal Article] Temperature-dependent, static, and dynamic fluorescence properties of disubstituted acetylene polymer films2006

    • Author(s)
      G.Kwak, S.Fukao, M Fujiki, T.Sakaguchi, T.Masuda
    • Journal Title

      CHEM.MATER. 18・8

      Pages: 2081-2085

  • [Journal Article] Stimuli-responsive conjugated polymers. Synthesis and chiroptical properties of polyacetylene carrying L-glutamic acid and azobenzene in the side chain2006

    • Author(s)
      HC.Zhao, F.Sanda, T.Masuda
    • Journal Title

      POLYMER 47・8

      Pages: 2596-2602

  • [Journal Article] Synthesis and properties of pyrene-functionalized polyacetylene. A stable helical polymer emitting fluorescence2006

    • Author(s)
      HC.Zhao, F.Sanda, T.Masuda
    • Journal Title

      POLYMER 47・5

      Pages: 1584-1589

  • [Journal Article] Conjugated poly (phenylacetylene) films cross-linked with electropolymerized polycarbazole precursors2006

    • Author(s)
      T.Fulghum, SMA.Karim, A.Baba, P.Taranekar, T.Nakai, T.Masuda, RC.Advincula
    • Journal Title

      MACROMOLEC. 39・4

      Pages: 1467-1473

  • [Journal Article] Synthesis and properties of membranes of poly(diphenylacetylenes) having fluorines and hydroxyl groups2006

    • Author(s)
      Y.Shida, T.Sakaguchi, M.Shiotsuki, F.Sanda, BD.Freeman, T.Masuda
    • Journal Title

      MACROMOLEC. 39・2

      Pages: 569-574

  • [Journal Article] Mono- and multicolor FL image patterning based on highly luminous diphenylacetylene polymer derivative by facile photobleaching2006

    • Author(s)
      G.Kwak, M.Fujiki, T.Sakaguchi, T.Masuda
    • Journal Title

      MACROMOLEC. 39・1

      Pages: 319-323

  • [Journal Article] Synthesis and properties of optically active amino acid based polyacetylenes bearing eugenol and fluorene moieties2006

    • Author(s)
      EA.Rahim, F.Sanda, T.Masuda
    • Journal Title

      J.POLYM.SCI.A-POLYM.CHEM. 44・2

      Pages: 810-819

  • [Journal Article] Poly-(3-Hexylthiophene) self assembled momolayer based choresterol biosensor using plasmon resonance technique2006

    • Author(s)
      Sunil K.Arya, Pratima Rl.Solanki, S.P.Singh, K.Kaneto, Manoj K.Pandey, Monika Datta, Bansi D.Malhotra
    • Journal Title

      BIOSENSORS AND BIOELECTRONICS (印刷中)

  • [Journal Article] A combined bi-ionic polymer actuator with unidirectional extension against bipolar excitations2006

    • Author(s)
      D.M.G.Preethichandra, A.K.Thakur, W.Takashima, K.Kaneto
    • Journal Title

      SENORS AND ACTUATORS B : CEMICAL (印刷中)

  • [Journal Article] Fast and large Stretching Bis Bis(trifluoromethylsulfonyl)imide (TSFI)-doped Polypyrrole Actuators and Their Applications to Small Devices2006

    • Author(s)
      T.Zama, N.Tanaka, W.Takashima, K.Kaneto
    • Journal Title

      POLYM.J. 38・7

      Pages: 669-677

  • [Journal Article] Tubular linear actuators using conducting polymer, polypyrrole2006

    • Author(s)
      K.Yamato, K.Kaneto
    • Journal Title

      ANALY.CHIM.ACTA. 568・1-2

      Pages: 133-137

  • [Journal Article] Circular Dichroism of Optically Active Poly(dialkylsilane) Aggregates in Microcapsules2006

    • Author(s)
      K.Terao, N.Kikuchi, T.Sato, A.Teramoto, M.Fujiki, T.Dobashi
    • Journal Title

      LANGMUIR 22

      Pages: 7975-7980

  • [Journal Article] Energy Transfer from Locally Excited pai to Charge Transfer Ground States in a Silylene-pai Hetero-junction Polymer2006

    • Author(s)
      G.Kwak, A.Takagi, M.Fujiki
    • Journal Title

      MACROMOLC.RAPID COMMUN. 27

      Pages: 1561-1564

  • [Journal Article] Polyacetylene Intermediate Bearing Reactive Benzylidene Malonate : Helix Induction, Inversion, and Recovery by Tandem Michael and Amidation Reactions with Chiral Nucleophiles and Wate2006

    • Author(s)
      G.Kwak, S.Hososhima, M.Fujiki
    • Journal Title

      FOLYM.J. 38

      Pages: 976-982

  • [Journal Article] Weak Noncovalent Si/FC Interactions Stabilized Fluoroalkylated Rod-like Polysilanes As Ultrasensitive Chemosensors2006

    • Author(s)
      A.Saxena, R.Rai, S-Y.Kim, M.Fujiki, M.Naito, K.Okoshi, G.Kwak
    • Journal Title

      J.POLYM.SCL.: PART A : POLYM.CHEM. 44

      Pages: 5060-5075

  • [Journal Article] Switching in Molecular Shapes : Main Chain Length Driven Rod-Circle Transition of Isolated Helical Polysilane2006

    • Author(s)
      A.Ohira, S-Y.Kim, M.Fujiki, Y.Kawakami, M.Naito, G.Kwak, A.Saxens
    • Journal Title

      CHEM.COMMUN.

      Pages: 2659-266

  • [Book] 自己組織化ナノマテリアル フロントランナ-85人が語るナノテクノロジーの新潮流-2007

    • Author(s)
      赤木和夫, 松下哲士(分担執筆)
    • Total Pages
      302
    • Publisher
      フロンティア出版
  • [Book] Handbook of Conducting Polymers, Third Edition, Conjugated Polymers2007

    • Author(s)
      K.Akagi(分担執筆)
    • Total Pages
      1680
    • Publisher
      CRC Press
  • [Book] Thermotropic Liquid Crystals : Recent Advances2007

    • Author(s)
      K.Akagi(分担執筆)
    • Publisher
      Springer (in press)
  • [Book] "ファイバー" スーパーバイオミメティックス 〜近未来の新技術創成〜2006

    • Author(s)
      赤木和夫, 高文柱, 森泰蔵(分担執筆)
    • Total Pages
      1127
    • Publisher
      エヌ・ティー・エス
  • [Book] 液晶ポリマーの改質と最新応用技術2006

    • Author(s)
      赤木和夫, 早坂裕之(分担執筆)
    • Total Pages
      321
    • Publisher
      技術情報協会

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Published: 2008-05-08   Modified: 2016-04-21  

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