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2007 Fiscal Year Annual Research Report

次世代共役ポリマーの超階層制御と革新機能

Research Project

Project/Area Number 17067002
Research InstitutionKyoto University

Principal Investigator

赤木 和夫  Kyoto University, 大学院・工学研究科, 教授 (20150964)

Co-Investigator(Kenkyū-buntansha) 増田 俊夫  京都大学大学院, 工学研究科, 教授 (60026276)
金藤 敬一  九州工業大学, 大学院・生命体工学研究科, 教授 (70124766)
藤木 道也  奈良先端科学技術大学院大学, 物質創成科学研究科, 教授 (00346313)
河合 壯  奈良先端科学技術大学院大学, 物質創成科学研究科, 教授 (40221197)
Keywords共役高分子 / 超階層構造 / 若手育成 / らせん構造 / 非線形現象
Research Abstract

本総括班では次世代π共役ポリマーの超階層制御と革新機能に関する研究の推進を総括し、特に関連学域の深化と新たな融合研究の創出を目指してシンポジウム開催などに取り組んできた。研究成果の公開と関連研究者との討論を目的とする公開シンポジウムについては平成19年7月5日、6日に第5回公開シンポジウム、平成20年1月28日、29日に第6回公開シンポジウムを開催した。それぞれの参加者人数は157名と132名で、きわめて盛況であった。また2編のニュースレターを刊行し、全国の関連研究者約300名に配布した。一方、ホームページにより本領域の趣旨、班員の研究計画と業績、さらに行事開催予定などの情報を公開してきた。総括班としての計画立案と総括のために2回の総括班会議を開催した。各班の共同研究を進めることを目標に、それぞれ2回の班会議を開催した。国際化の推進のために第2回超階層制御国際ワークショップを平成19年9月30日に開催した。当領域での特徴的な取り組みとして(1)領域内の共同研究の推進、(2)若手研究者の育成の2点について重点的な取り組みを推進してきた。たとえば班会議においては他班からの同伴出席者を求める同伴制度を採用しまた、合同班会議を開催するなど、班内および班間での共同研究の可能性を追求した。その結果、共同研究に関する共著論文をはじめ多数の連名の学会発表などの成果が出つつある。一方、若手研究者の育成の目的のため前年度結成した"超階層制御若手の会"を引き続き運営・拡大し第4回および第5回超階層制御若手フォーラムを開催し(平成19年7月7日、平成20年1月27日)、招待講演者や学生を含めてそれぞれ17名および33名の参加を得て、若手研究者の交流とディスカッションを深めた。今後の融合共同研究や共同研究提案などが期待できる。

  • Research Products

    (67 results)

All 2008 2007 Other

All Journal Article (50 results) (of which Peer Reviewed: 50 results) Presentation (4 results) Book (5 results) Remarks (1 results) Patent(Industrial Property Rights) (7 results)

  • [Journal Article] Dynamic Switching of Linearly Polarized Emission in Liquid Crystallinity-Embedded Photoresponsive Conjugated Polymers2008

    • Author(s)
      H. Hayasaka
    • Journal Title

      Macromolecules 41

      Pages: 2341-2346

    • Peer Reviewed
  • [Journal Article] Tubular-Shaped Nanocarbons Prepared from Polyaniline Synthesized by a Self-Assembly-Process and Their Electrical Conductivity2008

    • Author(s)
      M. Kyotani
    • Journal Title

      J. Nanosci. Nanotechnol. 8

      Pages: 1999-2004

    • Peer Reviewed
  • [Journal Article] Helicity-Controlled Liquid Crystal Reaction Field Using Nonbridged and Bridged Binaphthyl Derivatives Available for Synthesis of Helical Conjugated Polymers2008

    • Author(s)
      T. Mori
    • Journal Title

      Macromolecules 41

      Pages: 607-613

    • Peer Reviewed
  • [Journal Article] Interfacial Conversion of Poly (para-phenylenevinylene) at a Cholesteric Liquid Crystal Surface2008

    • Author(s)
      H. Goto
    • Journal Title

      J. Appl. Polym. Sci. 107

      Pages: 438-443

    • Peer Reviewed
  • [Journal Article] Ferroelectric Liquid Crystalline Polyphenylene Derivatives with Quick Polarization Inversion and Memory Function2008

    • Author(s)
      K. Suda
    • Journal Title

      J. Polym. Sci. Part A: Polym. Chem. (In press)

    • Peer Reviewed
  • [Journal Article] Self-assembly of tris (phenylisoxazolyl) benzene and its asymmetric induction of supramolecular chirality2008

    • Author(s)
      T. Haino
    • Journal Title

      Chem. Commun.

      Pages: 468-470

    • Peer Reviewed
  • [Journal Article] Synthesis and Helical Structure of Poly (N-butynylamide) s Having Various Side Chains, Where the Helix Is Highly Affected by the Methyl Branch and the Lactone Moiety2008

    • Author(s)
      Y. Suzuki
    • Journal Title

      Macromolecules 41

      Pages: 1086-1093

    • Peer Reviewed
  • [Journal Article] Thermochromism of Polydiacetylene in the Solid State and in Solution by the Self-Organization of Polymer Chains Containing No Polar Group2008

    • Author(s)
      S. Dei
    • Journal Title

      Macromolecules 40(In press)

    • Peer Reviewed
  • [Journal Article] DNA/導電性高分子高次組織体の構造とEL特性2008

    • Author(s)
      小林範久
    • Journal Title

      未来材料 8

      Pages: 14-21

    • Peer Reviewed
  • [Journal Article] Continuous control of third-order optical nonlinearity in charge-transfer-type2008

    • Author(s)
      H. Kishida
    • Journal Title

      Appl. Phys. Lett. 92

      Pages: 033309-1/4

    • Peer Reviewed
  • [Journal Article] A New Approach to the Spectral Study of Unstable Radicals and Ions in Solution by the Use of an Inert Gas Glovbox System: Observation and Analysis of the Infrared Spectra of the Radical Anion and Dianion of p_Terphenyl2008

    • Author(s)
      A. Sakamoto
    • Journal Title

      J. Phys. Chem. A 112-2

      Pages: 1180-1187

    • Peer Reviewed
  • [Journal Article] Polysilanes on surfaces2008

    • Author(s)
      M. Naito
    • Journal Title

      Soft Matter 4

      Pages: 211-223

    • Peer Reviewed
  • [Journal Article] Optical selection rule for the lower Davydov excitons in co-oligomer single crystals2008

    • Author(s)
      K. Bando
    • Journal Title

      Phys. Rev. B 77

      Pages: 045205-211

    • Peer Reviewed
  • [Journal Article] Preparation of microporous and microdot structures from photo crosslinkable resin by self-organization2008

    • Author(s)
      M. Shimomura
    • Journal Title

      Coll. Surf. A 313-314

      Pages: 343-346

    • Peer Reviewed
  • [Journal Article] Development of Novel Carbon Nanotubes/Photopolymer Nanocomposites with High Conductivity and Application to Nanoimprint Photolithography2008

    • Author(s)
      T. Fujigaya
    • Journal Title

      Adv. Mater. 20(In press)

    • Peer Reviewed
  • [Journal Article] Hyperstructured Polyacetylene2007

    • Author(s)
      K. Akagi
    • Journal Title

      Polym. Intern. 56

      Pages: 1192-1199

    • Peer Reviewed
  • [Journal Article] Highly Twisted Helical Polyacetylene with Morphology Free From Bundle of Fibrils Synthesized in Chiral Liquid Crystal Reaction Field2007

    • Author(s)
      M. Goh
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 8519-8527

    • Peer Reviewed
  • [Journal Article] The Hierarchical Microstructure of Helical Polyacetylene Nanofibers2007

    • Author(s)
      Z. X. Jin
    • Journal Title

      Curr. Appl. Phys. 7

      Pages: 367-369

    • Peer Reviewed
  • [Journal Article] Helical Polyacetylenes Synthesized in Helical Sense and Pitch Controllable Chiral Nematic Liquid Crystal with Unprecedented Temperature Dependence2007

    • Author(s)
      M. Goh
    • Journal Title

      Macromolecules 40

      Pages: 4762-4771

    • Peer Reviewed
  • [Journal Article] Synthesis of Pyrrole-Based Methine Bridge Type Liquid Crystalline Conjugated Polymer2007

    • Author(s)
      M. Kyotani
    • Journal Title

      Synth. Metals 157

      Pages: 546-550

    • Peer Reviewed
  • [Journal Article] External Stimulus-Responsive Supramolecular Structures Formed by a Stilbene Cyclodextrin Dimer2007

    • Author(s)
      P. Kuad
    • Journal Title

      J. Am. Chem. Soc. 129(42)

      Pages: 12630-12631

    • Peer Reviewed
  • [Journal Article] Chemically-Responsive Sol-Gel Transition of Supramolecular Single-Walled Carbon Nanotubes (SWNTs) Hydrogel Made by Hybrids of SWNTs and Cyclodextrins2007

    • Author(s)
      T. Ogoshi
    • Journal Title

      J. Am. Chem. Soc. 129(16)

      Pages: 4878-4879

    • Peer Reviewed
  • [Journal Article] Ring-opening bulk polymerization of L-lactide in porous hydroxyapatite2007

    • Author(s)
      N. Sugiyama
    • Journal Title

      Chem. Lett. 36

      Pages: 1476-1477

    • Peer Reviewed
  • [Journal Article] Synthesis of Helical Poly (N-propargylamides) Carrying Azobenzene Moieties in Side Chains. Reversible Arrangement-Disarrangement of Helical Side Chain Arrays upon Photoirradiation Keeping Helical Main Chain Intact2007

    • Author(s)
      T. Fujii
    • Journal Title

      Macromolecules 40

      Pages: 7079-7088

    • Peer Reviewed
  • [Journal Article] Conversion of a Disilenide into a Silene: Silyl-Anion-Substituted Silene by Sila-Peterson-Type Reaction from an sp^2-Type Silyl Anion2007

    • Author(s)
      S. Inoue
    • Journal Title

      Angew. Chem, Int. Ed. 46

      Pages: 3346-3348

    • Peer Reviewed
  • [Journal Article] Stable Cyclic Silenes from Reaction of Disilenides with Carboxylic Acid Chlorides2007

    • Author(s)
      I. Bejan
    • Journal Title

      Angew. Chem, Int. Ed. 46

      Pages: 3349-3352

    • Peer Reviewed
  • [Journal Article] Chemical and Electrochemical Oxidation of Thiophene-Pyridine and Thiophene-Pyrimidine Co-Oligomers in Solutions2007

    • Author(s)
      A. Kumagai
    • Journal Title

      J. Phys. Chem., B 111

      Pages: 8020-8026

    • Peer Reviewed
  • [Journal Article] Dewetting Inhibition and Interfacial Structures of Silsesquioxane-terminated Polystyrene Thin Films2007

    • Author(s)
      K. Miyamoto
    • Journal Title

      Polym. J. 39

      Pages: 1247-1252

    • Peer Reviewed
  • [Journal Article] Template- and Vacuum-Ultraviolet- Assisted Fabrication of a Ag-Manoparticle Array on Flexible and Rigid Substrates2007

    • Author(s)
      J. Li
    • Journal Title

      Adv. Mater. 19

      Pages: 1267-1271

    • Peer Reviewed
  • [Journal Article] Additive-Free Synthesis of Poly (phenylene oxide): Aerobic Oxidative Polymerization in a Base-condensed Dendrimer Capsule2007

    • Author(s)
      K. Yamamoto
    • Journal Title

      J. Am. Chem. Soc 129

      Pages: 9256-9257

    • Peer Reviewed
  • [Journal Article] Gel-Electrolyte Based Flexible Electrochromic Devices Showing Subtractive Primary Colors2007

    • Author(s)
      N. Kobayashi
    • Journal Title

      Electrochim. Acta 53

      Pages: 1643-1647

    • Peer Reviewed
  • [Journal Article] Spin Transition at the Mesophase Transition Temperature in a Cobalt (II) Compound with Branched Alkyl Chains2007

    • Author(s)
      S. Hayami
    • Journal Title

      Inorg. Chem. 46

      Pages: 7692-7694

    • Peer Reviewed
  • [Journal Article] Surface Struture Effect on Optical Properties of Organic Nanocrystals2007

    • Author(s)
      E. Kwon
    • Journal Title

      Chem. Phys. Lett. 441

      Pages: 106-108

    • Peer Reviewed
  • [Journal Article] Work behaviors of soft actuators based on cation driven polypyrrole2007

    • Author(s)
      H. Fujisue
    • Journal Title

      Bioinsp. Biomim. 2

      Pages: 1-5

    • Peer Reviewed
  • [Journal Article] Charge injection mechanism across Au-poly(3-hexylthiophene-2, 5-diyl)interface2007

    • Author(s)
      K. Thakur
    • Journal Title

      J. Appl. Phys. 101

      Pages: 104508-1-5

    • Peer Reviewed
  • [Journal Article] Ambipolar Field Effect Transistors Based on Poly(3-hexylthiophene)/Fullerene Derivative Bilayer Films2007

    • Author(s)
      K. kaneto
    • Journal Title

      Jpn. J. Appl. Phys. 46・4A

      Pages: 1736-1738

    • Peer Reviewed
  • [Journal Article] Unipolarization of ambipolar organic field effect transistors toward high-impedance complementary metal-oxide-semiconductor circuits2007

    • Author(s)
      W. Takashima
    • Journal Title

      Appl. Phys. Lett. 91

      Pages: 071905-1-3

    • Peer Reviewed
  • [Journal Article] One-Dimensional Bromo-Bridged NiIII complexes [Ni(S,S-bn)_2Br]Br_2(S, S-bn=2S, 3S-diaminobutane): Synthesis, Physical Properties, and Electrostatic Carrier Doping2007

    • Author(s)
      S. Takaishi
    • Journal Title

      Chem. Eur. J. 14

      Pages: 472-477

    • Peer Reviewed
  • [Journal Article] Liquid crystal imidazolium salts: towards materials for catalysis and molecular electronic devicese2007

    • Author(s)
      J. Suisse,
    • Journal Title

      Eur. J. Inorg. Chem. 24

      Pages: 3899-3905

    • Peer Reviewed
  • [Journal Article] Magnetic field effects and time-resolved EPR studies on the photogenerated biradicals in phenothiazine-C_60 linked systems: clarification of the by dependences of methylene chain length and temperature2007

    • Author(s)
      S. Moribe
    • Journal Title

      Chem. Phys. 334

      Pages: 242-252

    • Peer Reviewed
  • [Journal Article] Photochromism of Thiazole-Containing Teiang Terarylenes2007

    • Author(s)
      T. Nakashima
    • Journal Title

      Eur. J. Org. Chem. 2007

      Pages: 3212-3218

    • Peer Reviewed
  • [Journal Article] Circularly Polarized Luminescence of a Fluorescent Chiral Binaphtylene-perylenebiscarboxydiimide Dimer2007

    • Author(s)
      T. Kawai
    • Journal Title

      Chem. Phys. Chem 8

      Pages: 1465-1468

    • Peer Reviewed
  • [Journal Article] Fabrication of densely packed multi-walled carbon nanotube ultrathin films using a liquid-liquid interface2007

    • Author(s)
      J. Matsui
    • Journal Title

      J. Mater. Chem. 17

      Pages: 3806-3811

    • Peer Reviewed
  • [Journal Article] Microdisk and microring lasers of thiophene-phenylene co-oligomers in Si0_2 substrates2007

    • Author(s)
      F. Sasaki
    • Journal Title

      Adv. mater. 19

      Pages: 3653-3655

    • Peer Reviewed
  • [Journal Article] Spectrally narrowed emissions occurring near an interface between a single crystal thiophene/phenylene co-oligomer and a glass substrate2007

    • Author(s)
      T. Yamao
    • Journal Title

      Appl. Phys. Lett. 91

      Pages: 201117-120

    • Peer Reviewed
  • [Journal Article] Spin Density Distribution and Electronic States in (DMe-DCNQI) 2M (M=Li,Ag,Cu) from High-Resolution Solid-State NMR2007

    • Author(s)
      Y. Shinohara
    • Journal Title

      Phys. Rev. B 76

      Pages: 0351289(1-9)

    • Peer Reviewed
  • [Journal Article] Electrocatalytic Activities for the Reduction of Oxygen at Carbon Particles Modified with Polypyrrole Including Various Metal Ions as Electrocatalytic Sites2007

    • Author(s)
      M. Yuasa
    • Journal Title

      Electrochem. 75

      Pages: 800-806

    • Peer Reviewed
  • [Journal Article] Nanoscale Metal Coordination Macrocycles Fabricated by Using ″Dimeric″ Dipyrrins2007

    • Author(s)
      H. Maeda
    • Journal Title

      Chem. Eur. J. 13

      Pages: 7900-7907

    • Peer Reviewed
  • [Journal Article] Hydrogen bonding self-assemblies with 1-D linear. dimeric and hexagonal nanostructures of meso-pyridy1-substituted dipyrromethanes2007

    • Author(s)
      H. Maeda
    • Journal Title

      Chem. Commun.

      Pages: 2726-2728

    • Peer Reviewed
  • [Journal Article] Organogels of 8-Quinolinol/Metal(II)-Chelate Derivatives That Show Electron-and Light-Emitting Properties2007

    • Author(s)
      M. Shirakawa
    • Journal Title

      Chem. Eur. J. 13

      Pages: 4155-4162

    • Peer Reviewed
  • [Presentation] 共役系高分子の次世代光材料への期待2008

    • Author(s)
      赤木和夫
    • Organizer
      第88回日本化学会春季年会
    • Place of Presentation
      東京
    • Year and Date
      2008-03-26
  • [Presentation] Work Characteristics of Conducting Polymer Actuators using Cation Driven Polypyrrole2007

    • Author(s)
      Keiichi Kaneto
    • Organizer
      MRS Spring Meeting
    • Place of Presentation
      アメリカ、サンフランシスコ
    • Year and Date
      20070409-13
  • [Presentation] Ambipolar Transport in Field Effect Transistors based on P3HT and PCBM Composite Films2007

    • Author(s)
      Keiichi Kaneto
    • Organizer
      MRS Spring Meeting
    • Place of Presentation
      アメリカ、サンフランシスコ
    • Year and Date
      20070409-13
  • [Presentation] 液晶性π共役系高分子の開発の現状2007

    • Author(s)
      赤木和夫
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2007-09-20
  • [Book] 電子共役系有機材料の創製と機能開発2008

    • Author(s)
      赤木和夫(分担執筆)
    • Total Pages
      224-244
    • Publisher
      シーエムシー出版
  • [Book] Thiophene-based Materials for Electronics2008

    • Author(s)
      K. Akagi(分担執筆)
    • Publisher
      Wiley(In press)
  • [Book] 導電性材料大全集 上巻2007

    • Author(s)
      赤木和夫(分担執筆)
    • Total Pages
      5-27
    • Publisher
      技術情報協会
  • [Book] 「自己組織化ナノマテリアル:フロントランナー85人が語るナノテクノロジーの新潮流」Chapter 4-82007

    • Author(s)
      鎌田香織, 彌田智一
    • Total Pages
      5
    • Publisher
      フロンティア出版
  • [Book] 有機エレクトロニクスにおける分子配向技術2007

    • Author(s)
      藤井彰彦 等
    • Total Pages
      368
    • Publisher
      シーエムシー出版
  • [Remarks]

    • URL

      http://www.choukaisou.com/

  • [Patent(Industrial Property Rights)] 発光デバイスの駆動方法及び駆動装置2008

    • Inventor(s)
      山雄健史, 清水康弘, 寺崎皓平, 堀田収
    • Industrial Property Rights Holder
      京都工芸繊維大学
    • Industrial Property Number
      特願2008-29318
    • Filing Date
      2008-02-08
  • [Patent(Industrial Property Rights)] らせん状液晶性共役高分子と発光材料2008

    • Inventor(s)
      赤木和夫
    • Industrial Property Rights Holder
      JST
    • Industrial Property Number
      特許第4063624号
    • Acquisition Date
      2008-01-11
  • [Patent(Industrial Property Rights)] フィルム状炭素材料を製造する方法およびフィルム状炭素材料2007

    • Inventor(s)
      赤木和夫, 京谷陸征, 松井良夫、長井拓郎
    • Industrial Property Rights Holder
      筑波大学, 独)物質・材料研究機構
    • Industrial Property Number
      特許2007-228619
    • Filing Date
      2007-09-04
  • [Patent(Industrial Property Rights)] 金属被覆型有機結晶の製造方法2007

    • Inventor(s)
      小野寺恒信, 及川英俊, 笠井 均, 中西八郎, 関口隆史
    • Industrial Property Rights Holder
      (独)科学技術振興機構, (独)物質・材料研究機構
    • Patent Publication Number
      特開2007-084851
    • Filing Date
      2007-04-05
  • [Patent(Industrial Property Rights)] 有機スイッチング素子およびその製造方法2007

    • Inventor(s)
      藤田克彦、市川央、小澤雅昭、安井圭、大士井啓祐
    • Industrial Property Rights Holder
      九州大学
    • Industrial Property Number
      特願2007-228332
    • Filing Date
      2007-09-03
  • [Patent(Industrial Property Rights)] 液晶性共役高分子組成物と円偏光二色性発光材料2007

    • Inventor(s)
      赤木和夫
    • Industrial Property Rights Holder
      JST
    • Industrial Property Number
      特許第3949552号
    • Acquisition Date
      2007-04-27
  • [Patent(Industrial Property Rights)] ジチエニルエテン誘導体および光制御型共役系高分子2007

    • Inventor(s)
      赤木和夫
    • Industrial Property Rights Holder
      JST
    • Industrial Property Number
      特許第3982990号
    • Acquisition Date
      2007-07-13

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Published: 2010-02-04   Modified: 2016-04-21  

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