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2009 Fiscal Year Final Research Report

Control of Super-Hierarchical Helical Structures of Next-Generation Conjugated Polymers and Their Innovative Functions

Research Project

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Project/Area Number 17067002
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionKyoto University

Principal Investigator

AKAGI Kazuo  Kyoto University, 大学院・工学研究科, 教授 (20150964)

Co-Investigator(Kenkyū-buntansha) MASUDA Toshio  福井大学, 工学部・環境・生命未来工学科, 教授 (60026276)
KANETO Keiichi  九州工業大学, 大学院・生命体工学研究科, 教授 (70124766)
FUJIKI Michiya  奈良先端科学技術大学院大学, 物質創成科学研究科, 教授 (00346313)
YAMAMOTO Takakazu  東京工業大学, 資源化学研究所, 教授 (10016743)
KURODA Shin-ichi  名古屋大学, 大学院・工学研究科, 教授 (20291403)
NISHIDE Hiroyuki  早稲田大学, 理工学術院応用化学専攻, 教授 (90120930)
HOTTA Shu  京都工芸繊維大学, 大学院・工芸科学研究科, 教授 (00360743)
MIZOGUCHI Kenji  首都大学東京, 大学院・理工学研究科, 教授 (40087101)
ABE Shuji  産業技術総合研究所, ナノテクノロジー研究部門, 副研究部門長、ナノ構造物性理論グループ長 (30356373)
KISHIDA Hideo  名古屋大学, 大学院・工学研究科マテリアル理工学専攻, 准教授 (40311633)
OKADA Shuji  山形大学, 大学院・理工学研究科, 教授 (30250848)
KAWAI Tsuyoshi  奈良先端科学技術大学院大学, 物質創成科学研究科, 教授 (40221197)
RIKUKAWA Mashiro  上智大学, 理工学部・化学科, 教授 (10245798)
KOBAYASHI Norihisa  千葉大学, 大学院・融合科学研究科, 教授 (50195799)
OTSUKA Hideyuki  九州大学, 先導物質化学研究所, 准教授 (00293051)
FUJII AKIHIKO  大阪大学, 大学院・工学研究科電気電子情報工学専攻, 准教授 (80304020)
Project Period (FY) 2005 – 2009
Keywords共役ポリマー / 階層制御 / 機能制御 / ヘリカルポリアセチレン / キラル液晶場 / らせん構造 / キラル発光 / キラルドーパント
Research Abstract

The present research area has aimed to explore profound potentialities of conjugated polymers and to extract innovative electronic, magnetic and optical functions that should give rise to the next-generation materials. The project has focused on (i) synthesis of novel and fruitful conjugated polymers by means of sophisticated designs for molecules and chemical reactions, and (ii) super-hierarchical control covering primary to higher order structures, and morphological control of self-organized assemblies and complexes, and (iii) precise evaluation of physical properties and investigation of intrinsic functions by virtue of well defined multi-layered structures. Through rigorous achievement of the project, we have fostered and cultivated the scientific field of conjugated polymers.

  • Research Products

    (62 results)

All 2009 2008 2007 2006 Other

All Journal Article (54 results) Presentation (3 results) Book (2 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Helical Polyacetylene - Asymmetric Polymerization in a Chiral Liquid Crystal Field2009

    • Author(s)
      K. Akagi
    • Journal Title

      Chemical Reviews 109

      Pages: 5354-5401

  • [Journal Article] Macroscopically Aligned Helical Conjugated Polymers in Orientation-Controllable Chiral Nematic Liquid Crystal Field2009

    • Author(s)
      T. Mori, T. Sato, M. Kyotani, *K. Akagi
    • Journal Title

      Macromolecules 42

      Pages: 1817-1823

  • [Journal Article] Advances in Liquid Crystalline Conjugated Polymers2009

    • Author(s)
      K. Akagi
    • Journal Title

      J. Polym. Sci. Part A: Polym. Chem. 47

      Pages: 2463-2485

  • [Journal Article] An Ultrafast Chargeable Polymer Electrode Based on the Combination of Radical Polymer and Aqueous Electrolyte2009

    • Author(s)
      K. Koshika, N. Sano, K. Oyaizu, *H. Nishide
    • Journal Title

      Chem. Commun. 7

      Pages: 836-838

  • [Journal Article] Emerging N-Type Redox-Active Radical Polymer for a Totally Organic Polymer-Based Rechargeable Battery2009

    • Author(s)
      T. Suga, H. Ohshiro, S. Sugita, K. Oyaizu, *H. Nishide
    • Journal Title

      Adv. Mater. 21

      Pages: 1627-1630

  • [Journal Article] Synthesis and Photochemical Reactions of Photochromic Terarylene having Leaving Methoxy Group2009

    • Author(s)
      H. Nakagawa, S. Kawai, T. Nakashima, *T. Kawai
    • Journal Title

      Org. Lett. 11

      Pages: 1475-1478

  • [Journal Article] Photo-, Solvent-, and Ion-Controlled Multichromism of Imidazolium-Substituted Diarylethenes2009

    • Author(s)
      T. Nakashima, K. Miyamura, T. Sakai, *T. Kawai
    • Journal Title

      Chem. Eur. J. 15

      Pages: 1977-1984

  • [Journal Article] Photochromic Amorphous Molecular Materials Based on Dibenzothienylthiazole Structure2009

    • Author(s)
      S. Kawai, T. Nakashima, Y. Kutsunugi, H. Nakagawa, H. Nakano, *T. Kawai
    • Journal Title

      J. Mater. Chem. 19

      Pages: 3606-3611

  • [Journal Article] Complexation Behavior of Supramolecular Organic Fluorophore by Solid-State Co-grinding Crystallization Using 2-Anthracenecarboxylic Acid and (R)-1-(2-Naphthyl)ethylamine and Its Optical Property2009

    • Author(s)
      Y. Imai, K. Murata, K. Kawaguchi, T. Harada, Y. Nakano, T. Sato, *M. Fujiki, R. Kuroda, Y. Matsubara
    • Journal Title

      Eur. J. Org. Chem. 9

      Pages: 1335-1339

  • [Journal Article] Theory of Antibunching of Photon Emission I2009

    • Author(s)
      K. Seki, M. Tachiya
    • Journal Title

      J. Chem. Phys. 130

      Pages: 024706

  • [Journal Article] Helical Carbon and Graphitic Films Prepared from Iodine-Doped Helical Polyacetylene Film using Morphology-Retaining Carbonization2008

    • Author(s)
      M. Kyotani, S. Matsushita, T. Nagai, Y. Matsui, M. Shimomura, A. Kaito, *K. Akagi
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 10880-10881

  • [Journal Article] Helicity-Controlled Liquid Crystal Reaction Field Using Nonbridged and Bridged Binaphthyl Derivatives Available for Synthesis of Helical Conjugated Polymers2008

    • Author(s)
      T. Mori, M. Kyotani, *K. Akagi
    • Journal Title

      Macromolecules 41

      Pages: 607-613

  • [Journal Article] Dynamic Switching of Linearly Polarized Emission in Liquid Crystallinity-Embedded Photoresponsive Conjugated Polymers2008

    • Author(s)
      H. Hayasaka, K. Tamura, *K. Akagi
    • Journal Title

      Macromolecules 41

      Pages: 2341-2346

  • [Journal Article] Electro-Optical Behavior of Ferroelectric Liquid Crystalline Polyphenylene Derivatives2008

    • Author(s)
      K. Suda, *K. Akagi
    • Journal Title

      J. Polym. Sci. Part A: Polym. Chem. 46

      Pages: 3591-3610

  • [Journal Article] Synthesis and Properties of Helical Poly(phenylacetylene) Derivatives. Effect of Chirality Combination on the Helicity2008

    • Author(s)
      R. Liu, F. Sanda, *T. Masuda
    • Journal Title

      J. Polym. Sci., Part A: Polym. Chem. 46

      Pages: 4183-4192

  • [Journal Article] DNA-lipid Complexes Carrying Carbazole and Triphenylamine Moieties: Synthesis, and Chiroptical and Photoelectronic Properties2008

    • Author(s)
      J. Qu, R. Morita, H. Ashitaka, N. Ogata, *T. Masuda
    • Journal Title

      Polymer 49

      Pages: 3663-3670

  • [Journal Article] Synthesis and Properties of DNA Complexes Containing 2, 2, 6, 6-Tetramethyl-1-piperidinoxy (TEMPO) Moieties as Organic Radical Battery Materials2008

    • Author(s)
      J. Qu, R. Morita, M. Satoh, J. Wada, F. Terakura, K. Mizoguchi, N. Ogata, *T. Masuda
    • Journal Title

      Chem. Eur. J. 14

      Pages: 3250-3259

  • [Journal Article] Dynamic Structure of Regioregular Poly(alkylthiophene)s2008

    • Author(s)
      K. Yazawa, Y. Inoue, *T. Yamamoto, N. Asakawa
    • Journal Title

      J. Phys. Chem. B 112

      Pages: 11580-11585

  • [Journal Article] Synthesis and Characterization of Radical-Bearing Polyethers as an Electrode-Active Material for Organic Secondary Batteries2008

    • Author(s)
      K. Oyaizu, T. Suga, K. Yoshimura, *H. Nishide
    • Journal Title

      Macromolecules 41

      Pages: 6646-6652

  • [Journal Article] Nernstian Adsorbate-like Bulk Layer of Organic Radical Polymers for High-Density Charge Strage Purposes2008

    • Author(s)
      K. Oyaizu, Y. Ando, H. Konishi, *H. Nishide
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 14459-14461

  • [Journal Article] Lipase-catalyzed Polymerization of L-Lactide in Ionic Liquids2008

    • Author(s)
      M. Yoshizawa-Fujita, C. Saito, Y. Takeoka, *M. Rikukawa
    • Journal Title

      Polym. Adv. Technol. 19

      Pages: 1396-1400

  • [Journal Article] Nanoscale Observation of Polymer Electrolyte Membranes-Surface Morphology and Proton Conduction of Nafion Membranes-2008

    • Author(s)
      N. Takimoto, A. Ohira, Y. Takeoka, *M. Rikukawa
    • Journal Title

      Chem. Lett. 37

      Pages: 164-165

  • [Journal Article] Synthesis and Solid-State Polymerization of Triyne and Enediyne Derivatives with Similarπ-Conjugated Structures2008

    • Author(s)
      K. Mizukoshi, S. Okada, T. Kimura, S. Shimada, H. Matsuda
    • Journal Title

      Bull. Chem. Soc. Jpn. 81

      Pages: 1028-1033

  • [Journal Article] Chemical Doping into Nanocrystals of Poly(diacetylene)2008

    • Author(s)
      K. Baba, H. Kasai, Y. Shinohara, *S. Okada, H. Oikawa, H. Matsuda, H. Nakanishi
    • Journal Title

      Jpn. J. Appl. Phys. 47

      Pages: 3769-3771

  • [Journal Article] Control of Dispersion State of Silsesquioxane Nanofillers for Stabilization of Polystyrene Thin Films2008

    • Author(s)
      N. Hosaka, N. Torikai, M. Hino, *H. Otsuka, A. Takahara
    • Journal Title

      Langmuir 24

      Pages: 5766-5772

  • [Journal Article] Evidence of Photoluminescence Quenching in Poly(3-Hexylthiophene-2, 5-Diyl) due to Injected Charge Carriers2008

    • Author(s)
      V. Singh, A.K. Thakur, S.S. Pandey, W. Takashima, *K. Kaneto
    • Journal Title

      Synth. Met. 158

      Pages: 283-286

  • [Journal Article] A Comparative Study of Al and LiF:Al Interfaces with Poly (3-Hexylthiophene) Using Bias Dependent Photoluminescence Technique2008

    • Author(s)
      V. Singh, A.K. Thakur, S.S. Pandey, W. Takashima, *K. Kaneto
    • Journal Title

      Org. Electr. 9

      Pages: 790-796

  • [Journal Article] Photomodulation of Ionic Interaction and Reactivity: Reversible Photoconversion between Imidazolium and Imidazolinium2008

    • Author(s)
      T. Nakashima, M. Goto, S. Kawai, *T. Kawai
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 14570-14575

  • [Journal Article] ESR Observations of Optically Generated Solitons in the Quasi-One-Dimensional Iodo-Bridged Diplatinum Complex Pt2(n-pentylCS2)4I2008

    • Author(s)
      H. Tanaka, H. Nishiyama, *S. Kuroda, T. Yamashita, M. Mitsumi, K. Toriumi
    • Journal Title

      Phys. Rev. B 78

      Pages: 033104(1-4)

  • [Journal Article] Charge-Density-Wave to Mott-Hubbard Phase Transition in Quasi-One-Dimensional Bromo-Bridged Pd Compounds2008

    • Author(s)
      S. Takaishi, M. Takamura, T. Kajiwara, H. Miyasaka, M. Yamashita, M. Iwata, H. Matsuzaki, H. Okamoto, H. Tanaka, *S. Kuroda, H. Nishikawa, H. Oshio, K. Kato, M. Takata
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 12080-12084

  • [Journal Article] Roles of Spin Fluctuation and Frustration in the Superconductivity of β-(BDA-TTP)2X (X=SbF6, AsF6) under Uniaxial Compression2008

    • Author(s)
      H. Ito, T. Ishihara, H. Tanaka, *S. Kuroda, T. Suzuki, S. Onari, Y. Tanaka, J. Yamada, K. Kikuchi
    • Journal Title

      Phys. Rev. B 78

      Pages: 172506(1-4)

  • [Journal Article] Continuous Control of Third-order Optical Nonlinearity in Charge-Transfer-Type2008

    • Author(s)
      H. Kishida, K. Hirota, H. Okamoto, H. Kokubo, T. Yamamoto
    • Journal Title

      Appl. Phys. Lett. 92

      Pages: 033309

  • [Journal Article] Stiffness- and Conformation-Dependent Polymer Wrapping onto Single-Walled Carbon Nanotubes2008

    • Author(s)
      M. Naito, K. Nobusawa, H. Onouchi, M. Nakamura, K. Yasui, A. Ikeda, *M. Fujiki
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 11697-16703

  • [Journal Article] Polysilanes on surfaces2008

    • Author(s)
      M. Naito, *M. Fujiki
    • Journal Title

      Soft Matter 4

      Pages: 211-223

  • [Journal Article] Organic Light-Emitting Field-Effect Transistors Operated by Alternating-Current Gate Voltages2008

    • Author(s)
      T. Yamao, Y. Shimizu, K. Terasaki, *S. Hotta
    • Journal Title

      Adv. Mater. 20

      Pages: 4109-4112

  • [Journal Article] Polarized Emissions from Single Crystals of Thiophene/Phenylene Co-oligomers Measured by Microspectroscopy2008

    • Author(s)
      T. Yamao, Y. Taniguchi, K. Yamamoto, T. Miki, T. Ohira, *S. Hotta
    • Journal Title

      Jpn. J. Appl. Phys. 47

      Pages: 4719-4723

  • [Journal Article] Laser Oscillation in a Highly Anisotropic Organic Crystal with a Refractive Index of 4. 02008

    • Author(s)
      T. Yamao, K. Yamamoto, Y. Taniguchi, T. Miki, *S. Hotta
    • Journal Title

      J. Appl. Phys. 103

      Pages: 093115

  • [Journal Article] Optical Properties and Micro-Capillary Laser of Blue Emissiveπ-Conjugated Polymers Based on 9, 10-Dihydrophenanthrene Unit2008

    • Author(s)
      K. Masuyama, *A. Fujii, T. Nakao, T. Asao, H. Fukumoto, T. Yamamoto, J. Sakai, R. Hidayat, M. Ozaki
    • Journal Title

      Jpn. J. Appl. Phys. 47

      Pages: 4724-4727

  • [Journal Article] Highly Twisted Helical Polyacetylene with Morphology Free From Bundle of Fibrils Synthesized in Chiral Liquid Crystal Reaction Field2007

    • Author(s)
      M. Goh, M. Kyotani, *K. Akagi
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 8519-8527

  • [Journal Article] Helical Polyacetylenes Synthesized in Helical Sense and Pitch Controllable Chiral Nematic Liquid Crystal with Unprecedented Temperature Dependence2007

    • Author(s)
      M. Goh, T. Matsushita, M. Kyotani, *K. Akagi
    • Journal Title

      Macromolecules 40

      Pages: 4762-4771

  • [Journal Article] Synthesis and Helical Structure of Poly(N-butynylamide)s Having Various Side Chains, Where the Helix Is Highly Affected by the Methyl Branch and the Lactone Moiety2007

    • Author(s)
      T. Fujii, M. Shiotsuki, Y. Inai, F. Sanda, *T. Masuda
    • Journal Title

      Macromloecules 40

      Pages: 7079-7083

  • [Journal Article] Synthesis and Helical Structure of Poly(N-butynylamide)s Having Various Side Chains, Where the Helix Is Highly Affected by the Methyl Branch and the Lactone Moiety2007

    • Author(s)
      Y. Suzuki, J. Tabei, M. Shiotsuki, Y. Inai, F. Sanda, *T. Masuda
    • Journal Title

      Macromolecules 41

      Pages: 1086-1092

  • [Journal Article] Charge Injection Mechanism across Au-poly(3-hexylthiophene-2, 5-diyl) Interface2007

    • Author(s)
      A.K. Thakur, A.K. Mukherjee, D.M.G. Preethichandra, W. Takashima, *K. Kaneto
    • Journal Title

      J. Appl. Phys. 101

      Pages: 104508

  • [Journal Article] Ambipolar Field Effect Transistors Based on Poly(3-hexylthiophene)/Fullerene Derivative Bilayer Films2007

    • Author(s)
      K. Kaneto, M. Yano, M. Shibao, T. Morita, W. Takashima
    • Journal Title

      Jpn. J. Appl. Phys. 46

      Pages: 1736

  • [Journal Article] Unipolarization of Ambipolar Organic Field Effect Transistors toward High-Impedance Complementary Metal-Oxide-Semiconductor Circuits2007

    • Author(s)
      W. Takashima, T. Murasaki, S. Nagamatsu, T. Morita, *K. Kaneto
    • Journal Title

      Appl. Phys. Lett. 91

      Pages: 071905

  • [Journal Article] Novel Photochromic Molecules Based on 4, 5-Dithienyl Thiazole with Fast Thermal Bleaching Rate2007

    • Author(s)
      S. Kawai, T. Nakashima, K. Atsumi, T. Sakai, M. Harigai, M. Imamoto, H. Kamikubo, M. Kataoka, *T. Kawai
    • Journal Title

      Chem. Mater. 19

      Pages: 3479-3483

  • [Journal Article] Photochromism of Thiazole-Containing Triangle Terarylenes2007

    • Author(s)
      T. Nakashima, K. Atsumi, S. Kawai, T. Nakagawa, Y. Hasegawa, *T. Kawai
    • Journal Title

      Eur. J. Org. Chem. 2007

      Pages: 3212-3218

  • [Journal Article] Electron-Nuclear Double Resonance Observation of Spatial Extent of Polarons in Polythiophene and Poly(3-alkylthiophene)2007

    • Author(s)
      S. Kuroda, K. Marumoto, T. Sakanaka, N. Takeuchi, Y. Shimoi, S. Abe, H. Kokubo, T. Yamamoto
    • Journal Title

      Chem. Phys. Lett. 435

      Pages: 273-277

  • [Journal Article] Ambipolar Organic Light Emitting Field Effect Transistors with Modified Asymmetric Electrodes2007

    • Author(s)
      K. Yamane, H. Yanagi, A. Sawamoto, *S. Hotta
    • Journal Title

      Appl. Phys. Lett. 90

      Pages: 162108-162114

  • [Journal Article] Microdisk and Microring Lasers of Thiophene-Phenylene Co-Oligomers Embedded in Si/SiO2 Substrates2007

    • Author(s)
      F. Sasaki, S. Kobayashi, S. Haraichi, S. Fujiwara, K. Bando, Y. Masumoto, *S. Hotta
    • Journal Title

      Adv. Mater. 19

      Pages: 3653-3655

  • [Journal Article] Spectrally Narrowed Emissions Occurring Near an Interface Between a Single Crystal Thiophene/Phenylene Co-Oligomer and a Glass Substrate2007

    • Author(s)
      T. Yamao, K. Yamamoto, Y. Taniguchi, *S. Hotta
    • Journal Title

      Appl. Phys. Lett. 91

      Pages: 201117

  • [Journal Article] Effect of Diene Ligands in the Rhodium-Catalyzed Polymerization of Phenylacetylene2006

    • Author(s)
      I. Saeed, M. Shiotsuki, *T. Masuda
    • Journal Title

      Macromoecules 39

      Pages: 8977-8984

  • [Journal Article] Living Polymerization of Phenylacetylene with Tetrafluorobenzobarrelene Ligand-Containing Rhodium Catalyst Systems Featuring the Synthesis of High Molecular Weight Polymer2006

    • Author(s)
      I. Saeed, M. Shiotsuki, *T. Masuda
    • Journal Title

      Macromoecules 39

      Pages: 8567-8574

  • [Journal Article] A High-Spin and Helical Organic Polymer: Poly{[4-(dianisylaminium)phenyl]acetylene}2006

    • Author(s)
      H. Murata, D. Miyajima, *H. Nishide
    • Journal Title

      Macromoecules 39

      Pages: 6331-6336

  • [Presentation] From Helical Polyacetylene to Helical Graphite: Synthesis in Helical Sense-Controllable Liquid Crystal Field and Morphology-Retaining Carbonization2008

    • Author(s)
      K. Akagi
    • Organizer
      US-Japan POLYMAT 2008 Summit
    • Year and Date
      2008-08-10
  • [Presentation] Fibril Bundle-Free Helical Polyacetylene Synthesized in Ultimately Twisted Chiral Nematic Liquid Crystal Field2008

    • Author(s)
      K. Akagi
    • Organizer
      International Conference on Synthetic Metals
    • Year and Date
      2008-06-12
  • [Presentation] Construction of Superhierarchical Structure of Helical Polyacetylene by using Liquid Crystal Field2007

    • Author(s)
      K. Akagi
    • Organizer
      30 Years of Conducting Polymers for American Chemical Society
    • Year and Date
      2007-03-26
  • [Book] 次世代共役ポリマーの超階層性らせん構造の制御と革新機能の創出2009

    • Author(s)
      赤木和夫(監修)
    • Publisher
      出版シーエムシー
  • [Book] Synthetic Metals(Special Issue, International Symposium on Control of Super-Hierarchical Helical Structures and Innovative Functions of Next-Generation Conjugated Polymers)2009

    • Author(s)
      K. Kaneto, S. Okada, N. Kobayashi, M. Rikukawa, H. Kishida (Guest Editors)
    • Total Pages
      9-10
  • [Remarks] 特定領域研究・超階層制御

    • URL

      http://www.choukaisou.com/

  • [Remarks] 2010年合成金属の科学と技術に関する国際会議(ICSM 2010)

    • URL

      http://www.icsm2010.com/

  • [Patent(Industrial Property Rights)] フォトクロミック色素2006

    • Inventor(s)
      河合壯, 中嶋琢也, 河合重和
    • Industrial Property Rights Holder
      奈良先端科学技術大学院大学
    • Industrial Property Number
      特許・特願2006-189651
    • Filing Date
      2006-07-10

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Published: 2011-06-18   Modified: 2014-04-07  

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