Creation of Organic-Inorganic Semiconductor Hybrid by Using Super-Hierarchical Structure

2008 Fiscal Year Final Research Report

• Project/Area Number: 17067016
• Research Category: Grant-in-Aid for Scientific Research on Priority Areas
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Sophia University
• Principal Investigator: RIKUKAWA Masahiro Sophia University, 理工学部, 教授 (10245798)
• Project Period (FY): 2005 – 2008
• Keywords: 高分子構造 / 高分子合成 / 半導体物性 / 複合材料 / 量子閉じ込め

Research Abstract

無機半導体と有機共役系分子が有する優れた特性をあわせ持つ次世代材料を創成するために、フラーレン、ポリチオフェンをもとに自己組織性を有する共役系分子を合成した。これと、金属ハライドとのハイブリッド化を試み、目的とする分子レベルでハイブリッド化された複合材料の合成に成功した。さらに、それらの特性と超階層性について調査した。

Research Products

• [Journal Article] Hydration Behavior of Perfluorinated and Hydrocarbon-Type Proton Exchange Membranes : Relationship between Morphology and Proton Conduction (2008)
  • Author(s): N. Takimoto, L. Wu, A. Ohira, Y. Takeoka, M. Rikukawa
  • Journal Title: Polymer 50 Pages: 534-540
  • Peer Reviewed
• [Journal Article] Surface Morphology and Proton Conduction Imaging of Nafion Membrane (2008)
  • Author(s): N. Takimoto, A. Ohira, Y. Takeoka, M. Rikukawa
  • Journal Title: Chem. Lett 37 Pages: 164-165
  • Peer Reviewed
• [Journal Article] Ring-opening Bulk Polymerization of L-Lactide in Porous Hydroxyapatite (2007)
  • Author(s): N. Sugiyama, R. Kunibu, M. Yoshizawa-Fujita, Y. Takeoka, M. Aizawa, M. Rikukawa
  • Journal Title: Chem. Lett 36 Pages: 1476-1477
  • Peer Reviewed
• [Journal Article] Systematic Studies on Chain Lengths, Halide Species, and Well Thicknesses for Lead Halide Layered Perovskit Thin Films (2006)
  • Author(s): Y. Takeoka, K. Asai, M. Rikukawa, K. Sanui
  • Journal Title: Bull. Chem. Soc. Jpn 79 Pages: 1607-1613
  • Peer Reviewed
• [Journal Article] Intercalated Formation of Two-Dimensional and Multi-layered Perovskites in Organic Thin Films (2005)
  • Author(s): Y. Takeoka, M. Fukasawa, T. Matsui, K. Kikuchi, M. Rikukawa, K. Sanui
  • Journal Title: Chem. Commun Pages: 378-379
  • Peer Reviewed
• [Presentation] 高分子電解質の高次構造制御とPEFC特性の関係 (2008)
  • Author(s): 陸川政弘
  • Organizer: 高分子学会燃料電池材料研究会講座(招待講演)
  • Place of Presentation: 化学会館
  • Year and Date: 2008-10-02
• [Presentation] 炭化水素系高分子電解質膜の構造と機能の関係 (2008)
  • Author(s): 陸川政弘
  • Organizer: 日本化学会第88春季年会(招待講演)
  • Place of Presentation: 立教大学
  • Year and Date: 2008-03-27
• [Presentation] Super-hierarchical Structures and Their Properties Fabricated by Fullerene Derivatives (2007)
  • Author(s): M. Rikukawa
  • Organizer: The 2nd International Workshop on Super-Hierarchical Structures
  • Place of Presentation: Osaka University
  • Year and Date: 2007-09-30
• [Presentation] 燃料電池用高分子電解質膜:デザインと機能 (2007)
  • Author(s): 陸川政弘
  • Organizer: 第56回高分子学会年次大会(招待)
  • Place of Presentation: 国立京都国際会館
  • Year and Date: 2007-05-31
• [Presentation] 炭化水素系高分子電解質のデザイン (2006)
  • Author(s): 陸川政弘
  • Organizer: 第15回ポリマー材料フォーラム(招待講演)
  • Place of Presentation: 千里ライフサイエンスセンター
  • Year and Date: 2006-11-16
• [Book] 次世代共役ポリマーの超階層制御と革新機能 (2009)
  • Author(s): 竹岡裕子、陸川政弘
  • Total Pages: 39-44
  • Publisher: CMC出版
• [Book] 機能物質の集積膜と応用展開 (2006)
  • Author(s): 陸川政弘
  • Total Pages: 257-268
  • Publisher: CMC出版
• [Remarks]
  • URL: http://www.ch.sophia.ac.jp/polymer/