2009 Fiscal Year Final Research Report
Two-Photon Photoemission Microspectroscopy for Molecule-Electrode Contact System
| Project/Area Number |
17069012
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Osaka University |
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Principal Investigator |
MUNAKATA Toshiaki Osaka University, 大学院・理学研究科, 教授 (20150873)
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| Co-Investigator(Kenkyū-buntansha) |
MIYAKUBO Keisuke 大阪大学, 大学院・理学研究科, 講師 (70263340)
YAMADA Takashi 大阪大学, 大学院・理学研究科, 助教 (90432468)
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| Project Period (FY) |
2005 – 2009
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| Keywords | 光電子分光 / 顕微光電子分光 / 電子ダイナミクス / 有機薄膜 / 吸着 / フェムト秒レーザー |
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| Research Abstract |
We have investigated the occupied and unoccupied levels for nano-link molecules. The nuclear motion of molecule in the excited electronic state is detected as the change of the vibronic structure. The pump-photon energy dependence of the two-photon photoemission spectrum revealed that the photoexcitation process cannot be interpreted by a simple energy level scheme, and point to further understanding of excitation process. By comparative experiments on spectroscopy and atomic level microscopy, correlation between the structure of molecular assembly and electronic structure is clarified.
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