2009 Fiscal Year Final Research Report
Solvation and cluster structure of ionic liquids
| Project/Area Number |
17073006
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
SHIBUYA Kazuhiko Tokyo Institute of Technology, 大学院・理工学研究科化学専攻, 教授 (30126320)
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| Co-Investigator(Kenkyū-buntansha) |
KAWAI Akio 東京工業大学, 大学院・理工学研究科, 准教授 (50262259)
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| Project Period (FY) |
2005 – 2009
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| Keywords | クラスター・溶媒和 / 磁気共鳴 / 化学反応 / ダイナミクス |
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| Research Abstract |
We have carried out research on diffusion of molecular oxygen in ILs and the relaxation of triplet states, rotational diffusion in ILs and their analysis by a fractional Stokes-Einstein-Debye Law, cryogenic neon matrix-isolation FTIR spectroscopy of evaporated ILs, and geometrical structure of cation-anion 1:1 pair in the gas phase, the electronic spectra of vaporized ILs based on imidazolium and pyridinium cations, and photochromism of 3-butyl-1-methyl-2- phenylazoimidazolium in room temperature.
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Research Products
(34 results)
