2009 Fiscal Year Final Research Report
Synthesis and synthetic utilities of functionalized reaction system in ionic liquids
| Project/Area Number |
17073007
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
KITAZUME Tomoya Tokyo Institute of Technology, 大学院・生命理工学研究科, 教授 (30092547)
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| Co-Investigator(Kenkyū-buntansha) |
YAMAZAKI Takashi 東京農工大学, 大学院・共生科学技術研究院, 准教授 (40191267)
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| Co-Investigator(Renkei-kenkyūsha) |
IWAI Noritaka 東京工業大学, 大学院・生命理工学研究科, 助教 (80376938)
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| Project Period (FY) |
2005 – 2009
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| Keywords | イオン液体 / 酵素反応 / フルオリナーゼ / 光学活性体 / 機能性反応場 |
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| Research Abstract |
We have established new ionic liquid reaction systems for the organic reactions. 1) We have reported the utilities of ionic liquid-supported NHPI complexes as recoverable and recyclable systemfor the oxidation and nitration. 2) Ionic liquids have recognized as a solvent for Geotrichum candidum-catalyzed optical resolution and/or deracemization of rcemic secondary alcohols, giving optically active alcohols.
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