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2009 Fiscal Year Final Research Report

Fabrication of Polymer Nano-Devices Using Bottom-up Nanotechnology

Research Project

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Project/Area Number 17105006
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Research Field Polymer/Textile materials
Research InstitutionTohoku University

Principal Investigator

MIYASHITA Tokuji  Tohoku University, 多元物質科学研究所, 教授 (40124630)

Co-Investigator(Kenkyū-buntansha) WATANABE Akira  東北大学, 多元物質科学研究所, 准教授 (40182901)
MITSUISHI Masaya  東北大学, 多元物質科学研究所, 准教授 (70333903)
MATSUI Jun  東北大学, 多元物質科学研究所, 准教授 (50361184)
KIM Yeji  東北大学, 多元物質科学研究所, 講師 (10431470)
MIKAYAMA Aakeshi  東北大学, 多元物質科学研究所, 助手 (50327318)
Project Period (FY) 2005 – 2009
Keywordsナノ材料 / 超薄膜 / 表面・界面特性 / 先端機能デバイス
Research Abstract

We have carried out basic research aiming at new type of nano-devices based on polymer nanosheet assemblies using the Langmuir-Blodgett (LB) technique. We demonstrated photochemically patterned polymer nanosheets for 3D nanoarchitecture and an efficient organic electrochemical transistor composed of polymer LB film. We also investigated preparation of free-standing polymer nanosheet assemblies with highly ordered structure and nanoscale periodicity from nanometer to micrometer. Hybrid polymer nanoassemblies for luminescence sensor application, and enhancement of nonlinear optical efficiency via surface plasmon coupling were also investigated. For these outstanding results, we were invited to contribute a Highlight article to Journal of Materials Chemistry.

  • Research Products

    (54 results)

All 2010 2009 2008 2007 2006 2005 Other

All Journal Article (20 results) (of which Peer Reviewed: 20 results) Presentation (20 results) Book (8 results) Remarks (3 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] Preparation of organic-ceramic-metal multihybrid particles and their organized assembly2010

    • Author(s)
      J. Matsui, S. Parvin, E. Sato, T. Miyashita
    • Journal Title

      Polym.J. 42

      Pages: 142-147

    • Peer Reviewed
  • [Journal Article] Flow behavior in surface-modified microchannels with polymer nanosheets2009

    • Author(s)
      S. Sultana, M. Mitsuishi, J. Matsui, T. Miyashita
    • Journal Title

      Thin Solid Films 518

      Pages: 606-609

    • Peer Reviewed
  • [Journal Article] Molecular orientation of nonlinear optical polymer nanosheets on silica nanoparticle monolayer studied by optical waveguide spectroscopy2009

    • Author(s)
      M. Ishifuji, T. Suzuki, M. Mitsuishi, T. Miyashita
    • Journal Title

      Thin Solid Films 518

      Pages: 457-461

    • Peer Reviewed
  • [Journal Article] Quasi-Solid-State Optical Logic Devices Based on Redox Polymer Nanosheet Assembly2009

    • Author(s)
      J. Matsui, K. Abe, M. Mitsuishi, A. Aoki, T. Miyashita
    • Journal Title

      Langmuir 25

      Pages: 11061-11066

    • Peer Reviewed
  • [Journal Article] Bottom-up Design of Hybrid Polymer Nanoassemblies Elucidates Plasmon-Enhanced Second Harmonic Generation from Nonlinear Optical Dyes2009

    • Author(s)
      M. Ishifuji, M. Mitsuishi, T. Miyashita
    • Journal Title

      J.Am.Chem.Soc. 131

      Pages: 4418-4424

    • Peer Reviewed
  • [Journal Article] Photofunctional thin film devices composed of polymer nanosheet assemblies2009

    • Author(s)
      M. Mitsuishi, J. Matsui, T. Miyashita
    • Journal Title

      J.Mater.Chem. 19

      Pages: 325-329

    • Peer Reviewed
  • [Journal Article] The Electronic Behavior of a Photosynthetic Reaction Center Monitored by Conductive Atomic Force Microscopy2009

    • Author(s)
      T. Mikayama, K. Iida, Y. Suemori, T. Dewa, T. Miyashita, M. Nango, A. T. Gardiner, R. J. Cogdell
    • Journal Title

      J.Nanosci.Nanotechnol. 9

      Pages: 97-107

    • Peer Reviewed
  • [Journal Article] Temperature Imaging for Thermal Fluid Flow in Microchannels with Luminescent Polymer Nanosheets2009

    • Author(s)
      M. Mitsuishi, M. Mihashi, M. Aminuzzaman, S. Kikuchi, T. Miyashita
    • Journal Title

      J.Nanosci.Nanotechnol. 9

      Pages: 90-96

    • Peer Reviewed
  • [Journal Article] Free-standing ultrathin films with universal thickness from nanometer to micrometer by polymer nanosheet assembly2008

    • Author(s)
      H. Endo, M. Mitsuishi, T. Miyashita
    • Journal Title

      J.Mater.Chem. 18

      Pages: 1302-1306

    • Peer Reviewed
  • [Journal Article] Photoinduced High-Quality Ultrathin SiO_2 Film from Hybrid Nanosheet at Room Temperature2008

    • Author(s)
      Y. Kim, F. Zhao, M. Mitsuishi, A. Watanabe, T. Miyashita
    • Journal Title

      J.Am.Chem.Soc. 130

      Pages: 11848-11849

    • Peer Reviewed
  • [Journal Article] Second harmonic generation from multilayered hybrid polymer nanoassemblies enhanced by coupled surface plasmon resonance2008

    • Author(s)
      M. Ishifuji, M. Mitsuishi, T. Miyashita
    • Journal Title

      Chem.Comm.

      Pages: 1058-1060

    • Peer Reviewed
  • [Journal Article] Preparation of Ultrathin Silsesquioxane Nanofilms via Polymer Langmuir-Blodgett Films2008

    • Author(s)
      M. Mitsuishi, F. Zhao, Y. Kim, A. Watanabe, T. Miyashita
    • Journal Title

      Chem.Mater. 20

      Pages: 4310-4316

    • Peer Reviewed
  • [Journal Article] Impedance Modulation of Polymer Nanosheet Capacitor by Light Stimuli2008

    • Author(s)
      J. Matsui, Y. Sato, T. Miyashita
    • Journal Title

      Colloids Surf., A 313

      Pages: 452-455

    • Peer Reviewed
  • [Journal Article] Fabrication of Electrochemical Transistor Based on π-conjugate Polymer Langmuir-Blodgett Film2007

    • Author(s)
      J. Matsui, Y. Sato, T. Mikayama, T. Miyashita
    • Journal Title

      Langmuir 23

      Pages: 8602-8606

    • Peer Reviewed
  • [Journal Article] Nanoscale Actuation of Thermoreversible Polymer Brushes Coupled with Localized Surface Plasmon Resonance of Gold Nanoparticles2007

    • Author(s)
      M. Mitsuishi, Y. Koishikawa, H. Tanaka, E. Sato, T. Mikayama, J. Matsui, T. Miyashita
    • Journal Title

      Langmuir 23

      Pages: 7472-7474

    • Peer Reviewed
  • [Journal Article] Hybrid Polymer Nanoassemblies : Polymer Nanosheets Organized with Metal Nanoparticle Arrays for Surface Plasmon Photonics2007

    • Author(s)
      M. Mitsuishi, M. Ishifuji, H. Endo, H. Tanaka, T. Miyashita
    • Journal Title

      Polym.J. 39

      Pages: 411-422

    • Peer Reviewed
  • [Journal Article] Electroless Copper Plating onto Polyimide Using Polymer Nanosheet as a Nano-Adhesive2007

    • Author(s)
      J. Matsui, K. Kubota, Y. Kado, T. Miyashita
    • Journal Title

      Polym.J. 39

      Pages: 41-47

    • Peer Reviewed
  • [Journal Article] Enhanced optical second harmonic generation in hybrid polymer nanoassemblies based on coupled surface plasmon resonance of a gold nanoparticle array2006

    • Author(s)
      M. Ishifuji, M. Mitsuishi, T. Miyashita
    • Journal Title

      Appl.Phys.Lett. 89

      Pages: 011903-011903

    • Peer Reviewed
  • [Journal Article] Fabrication of Free-Standing Hybrid Nanosheets Organized with Polymer Langmuir-Blodgett Films and Gold Nanoparticles2006

    • Author(s)
      H. Endo, Y. Kado, M. Mitsuishi, T. Miyashita
    • Journal Title

      Macromolecules 39

      Pages: 5559-5563

    • Peer Reviewed
  • [Journal Article] unctional Organized Molecular Assemblies Based on Polymer Nano-sheets2006

    • Author(s)
      M. Mitsuishi, J. Matsui, T. Miyashita
    • Journal Title

      Polym.J. 38

      Pages: 877-896

    • Peer Reviewed
  • [Presentation] Fabrication of Polymer Hybrid Nano Assemblies toward Film Electronics2010

    • Author(s)
      T. Miyashita, M. Mitsuishi, J. Matsui
    • Organizer
      Conference & Discussions on Molecular Electronics
    • Place of Presentation
      Korea
    • Year and Date
      2010-01-27
  • [Presentation] フィルムエレクトロニクスを目指した高分子ナノハイブリッド集積体2009

    • Author(s)
      宮下徳治
    • Organizer
      第18回ポリマー材料フォーラム
    • Place of Presentation
      東京
    • Year and Date
      2009-11-27
  • [Presentation] Organic Nano-Electronics Based on Polymer Nano-sheet Assemblies2009

    • Author(s)
      T. Miyashita, J. Matsui, M. Mitsuishi
    • Organizer
      10th Japan-Belgium Symposium on Polymer Science
    • Place of Presentation
      Tokyo
    • Year and Date
      2009-11-09
  • [Presentation] ヒドロシリル化反応によるネットワーク型有機無機ハイブリッドポリマーの合成と物性2009

    • Author(s)
      石川貴啓, 渡辺明, 宮下徳治
    • Organizer
      第59回ネットワークポリマー講演討論会
    • Place of Presentation
      吹田
    • Year and Date
      2009-10-15
  • [Presentation] Plasmon Enhanced Luminescence using Polymer Nanosheet Assembly2009

    • Author(s)
      M. Mitsuishi, H. Tanaka, T. Miyashita
    • Organizer
      2nd Japanese German Joint Seminar Molecular Imaging Technology for Interdisciplinary Research
    • Place of Presentation
      Germany
    • Year and Date
      2009-09-01
  • [Presentation] Optical Properties of Organogermanium Polymer2009

    • Author(s)
      R. Fujii, A. Watanabe, T. Miyashita
    • Organizer
      KJF2009
    • Place of Presentation
      Korea
    • Year and Date
      2009-08-25
  • [Presentation] 液-液界面を用いたπ共役系ナノ材料の集積化2008

    • Author(s)
      柴田俊明, 松井淳, 横山喬大, 増原陽人, 笠井均, 及川英俊, 宮下徳治
    • Organizer
      第61回コロイドおよび界面化学討論会
    • Place of Presentation
      福岡
    • Year and Date
      2008-09-07
  • [Presentation] Organic Nano-Electronics based on Polymer Nano-Sheet Assemblies2008

    • Author(s)
      T. Miyashita
    • Organizer
      US-Japan Polymat 2008 Summit
    • Place of Presentation
      USA
    • Year and Date
      2008-08-12
  • [Presentation] Optical Second Harmonic Generation from Polymer Nanosheet Assembly Organized with Gold Nanoparticles2008

    • Author(s)
      M. Ishifuji, M. Mitsuishi, T. Miyashita
    • Organizer
      MACRO2008
    • Place of Presentation
      Taiwan
    • Year and Date
      2008-07-03
  • [Presentation] 金ナノ粒子-高分子ナノシート積層体の非線形光学特性2008

    • Author(s)
      石藤美紀, 三ツ石方也, 宮下徳治
    • Organizer
      第55回応用物理学関係連合講演会
    • Place of Presentation
      船橋
    • Year and Date
      2008-03-28
  • [Presentation] Photoinduced Network Formation of Hybrid Nanosheet Consisting of Silsesquioxane2007

    • Author(s)
      Y. Kim, F. Zhao, M. Mitsuishi, A. Watanabe, T. Miyashita
    • Organizer
      KJF 2007
    • Place of Presentation
      Korea
    • Year and Date
      2007-09-27
  • [Presentation] シルセスキオキサンを含むハイブリッドナノシートの光照射によるシリコン酸化膜の作製2007

    • Author(s)
      Kim Yeji, 趙峰, 三ツ石方也, 渡辺明, 宮下徳治
    • Organizer
      第68回応用物理学会学術講演会
    • Place of Presentation
      札幌
    • Year and Date
      2007-09-07
  • [Presentation] Functionalization of Inorganic Nanoparticles based on Reactive polymer Shell2007

    • Author(s)
      Parvin Salina, 佐藤絵理子, 松井淳, 宮下徳治
    • Organizer
      第56回高分子学会年次大会
    • Place of Presentation
      京都
    • Year and Date
      2007-05-31
  • [Presentation] Electrochemical Transistor Fabricated by Polythiophene Polymer Nano-sheets2006

    • Author(s)
      J. Matsui, Y. Sato, T. Mikayama, T. Miyashita
    • Organizer
      MRS Fall Meeting 2006
    • Place of Presentation
      USA
    • Year and Date
      2006-11-29
  • [Presentation] 親水性側鎖を有する高分子LB膜の表面モルフォロジーの検討2006

    • Author(s)
      宮田拡, 松井淳, 宮下徳治
    • Organizer
      第55回高分子討論会
    • Place of Presentation
      富山
    • Year and Date
      2006-09-22
  • [Presentation] 金属ナノ粒子-酸素応答性高分子ナノシートハイブリッド集積体の構築2006

    • Author(s)
      田中宏幸, 高橋昌弘, 三ツ石方也, 宮下徳治, 小幡誠, 矢野重信
    • Organizer
      第55回高分子討論会
    • Place of Presentation
      富山
    • Year and Date
      2006-09-21
  • [Presentation] ナノスケールの周期構造を有する自己支持性高分子ナノ薄膜の作製2006

    • Author(s)
      遠藤洋史, 三ツ石方也, 宮下徳治
    • Organizer
      第55回高分子討論会
    • Place of Presentation
      富山
    • Year and Date
      2006-09-21
  • [Presentation] 導電性高分子ナノシートを用いた電気化学トランジスタの検討2005

    • Author(s)
      佐藤吉隆, 松井淳, 三箇山毅, 宮下徳治
    • Organizer
      第54回高分子討論会
    • Place of Presentation
      山形
    • Year and Date
      2005-09-20
  • [Presentation] 高分子ナノシート接着剤を用いたポリイミド表面への微細銅配線作製2005

    • Author(s)
      久保田康介, 角裕子, 松井淳, 宮下徳治
    • Organizer
      第54回高分子討論会
    • Place of Presentation
      山形
    • Year and Date
      2005-09-20
  • [Presentation] 光伝導性高分子ナノシートを用いた有機フォトトランジスタの作製2005

    • Author(s)
      三箇山毅, 新沢達朗, 松井淳, 宮下徳治
    • Organizer
      第66回応用物理学会学術講演会
    • Place of Presentation
      徳島
    • Year and Date
      2005-09-11
  • [Book] ソフトマター 分子設計・キャラクタリゼーションから機能性材料まで(単分子膜と Langmuir-Blodgett(LB) 膜)2009

    • Author(s)
      宮下徳治, 三ツ石方也, 松井淳
    • Total Pages
      31-39
    • Publisher
      丸善
  • [Book] Nanohybridization of Organic-Inorganic Materials(Chapter 5 Polymer Nanoassemblies and Their Nanohybridization with Metallic Nanoparticles)2009

    • Author(s)
      M. Mitsuishi, J. Matsui, T. Miyashita
    • Total Pages
      103-123
    • Publisher
      Springer
  • [Book] 超分子サイエンス&テクノロジー, 高分子ナノシート2009

    • Author(s)
      三ツ石方也, 宮下徳治
    • Total Pages
      385-392
    • Publisher
      NTS出版
  • [Book] 自己組織化ナノマテリアル(第4章2高分子LB膜)2007

    • Author(s)
      宮下徳治, 三ツ石方也
    • Total Pages
      137-143
    • Publisher
      フロンティア出版
  • [Book] 機能物質の集積膜と応用展開(第22章 金属ナノ粒子の精密集積と光機能)2006

    • Author(s)
      三ツ石方也, 宮下徳治
    • Total Pages
      243-256
    • Publisher
      シーエムシー出版
  • [Book] Functional Nanomaterials (Photofunctional Supramolecular Systems Based on Polymer Nanosheets)2006

    • Author(s)
      T. Miyashita, J. Matsui, M. Mitsuishi
    • Total Pages
      361-375
    • Publisher
      American Scientific Publishers
  • [Book] ナノコンポジットマテリアル(高分子ナノシートと粒子系ハイブリッド)2005

    • Author(s)
      宮下徳治, 三ツ石方也
    • Total Pages
      272-277
    • Publisher
      フロンティア出版
  • [Book] ナノハイブリッド材料の最新技術(LB法によるハイブリッド集積体)2005

    • Author(s)
      宮下徳治
    • Total Pages
      51-59
    • Publisher
      CMC出版
  • [Remarks] ホームページ等

    • URL

      http://www.tagen.tohoku.ac.jp/labo/miyashita/index-j.html

  • [Remarks] 東北大学の新世紀「新素材!高分子超薄膜を作る」2008年7月28日放映

    • URL

      http://www.tohoku100-tv.jp/thisweek/080728/index.html

  • [Remarks] 第27回東北大学サイエンスカフェ「折れ曲がる電子製品を作る」2007年10月26日

    • URL

      http://cafe.tohoku.ac.jp/html/koen_2007.html#27

  • [Patent(Industrial Property Rights)] 共重合体の単分子膜または積層膜およびそれらの製造方法2007

    • Inventor(s)
      宮下徳治, 三ツ石方也, Kim Yeji, 三谷清樹
    • Industrial Property Rights Holder
      国立大学法人東北大学, チッソ株式会社
    • Patent Publication Number
      特許権特開2008-232853
    • Filing Date
      2007-11-09
  • [Patent(Industrial Property Rights)] 高分子ナノシート集積電解質膜2007

    • Inventor(s)
      川角昌弥, 福嶋喜章, 宮下徳治, 松井淳
    • Industrial Property Rights Holder
      トョタ中央研究所, 国立大学法人東北大学
    • Patent Publication Number
      特許権特開2009-76331
    • Filing Date
      2007-09-20
  • [Patent(Industrial Property Rights)] 局在表面プラズモン励起型超薄膜発光型センサー2007

    • Inventor(s)
      宮下徳治, 三ツ石方也, 田中宏幸
    • Industrial Property Rights Holder
      国立大学法人東北大学
    • Patent Publication Number
      特許権特開2008-232853
    • Filing Date
      2007-03-20

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Published: 2011-06-18   Modified: 2016-04-21  

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