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2007 Fiscal Year Final Research Report Summary

Preparation of capsule particles by self-assembling phase separated polymer method and its application

Research Project

Project/Area Number 17201025
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials/Nanobioscience
Research InstitutionKobe University

Principal Investigator

OKUBO Masayoshi  Kobe University, Graduate School of Engineering, professor (30031131)

Co-Investigator(Kenkyū-buntansha) MINAMI Hideto  Kobe University, Graduate School of Engineering, Associate Professor (20283872)
ZETTERLUND Per B  Kobe University, Graduate School of Engineering, Associate Professor (20322365)
SUZUKI Toyoko  Kobe University, Graduate School of Engineering, Research associate (40314504)
Project Period (FY) 2005 – 2007
Keywords(Multi-) Hollow Polymer Particles / Capsule Particle / Sapsep Method / Polvdivinvlbenzene / Heat Storage Materials / Hexadecane / Micro-Suspension Polymerization / Self-Assembling
Research Abstract

We have proposed the preparation method for micron-sized, cross-linked polystyrene/polydivinylbenzene (PS/PDVB) particles having a single hollow. The mechanism for the hollow polymer particles was based on the Self-assembling of Phase Separated Polymer at an interface with aqueous media, which was named the SaPSeP method. Recently, when the SaPSeP method was applied in the presence of sodium dodecyl sulfate (SDS), it was found that a single hole was formed in the shell of the hollow PS/PDVB composite particles.
In this research, in order to clarify such a strange phenomenon, preparations of capsule particles were examined in detail. It was clarified that the phase separation in the droplets in the early stage of the polymerization was one of key factors for the formation of the single hole. Hole was most likely formed as a result of reduced microgel adsorption at oil-water interface domains of high SDS content. Moreover, we succeeded in preparing submicrometer-sized hollow PS particles, microcapsules containing curing agent for epoxy resin, and PDVB particles with encapsulated titanium oxide or n-hexadecane (HD)by micro-suspension polymerization utilizing the SaPSeP method. HD is useful for heat storage materials. The encapsulation of HD has many advantages that provide large heat transfer area and control the volume change of the heat storage materials. However, there were some problems in encapsulated HD such as decrease of the heat of solidification and supercooling. In this research, the problem in the application of the polymer particles with encapsulated HD as heat storage material was improved by the copolymerization of hydrophilic acrylic monomer. This seems to be based on that the copolymerizations of hydrophilic monomer enhance the phase separation of copolymer chains and HD, eventually resulting in the complete isolation of the HD core from the polymer shell.

  • Research Products

    (71 results)

All 2008 2007 2006 2005 Other

All Journal Article (22 results) (of which Peer Reviewed: 11 results) Presentation (49 results)

  • [Journal Article] Preparation of divinylbenzene copolymer particles with encapsulated hexadecane for heat storage application2008

    • Author(s)
      Preeyaporn Chaiyasat, Yumiko Ogino, Toyoko Suzuki, Hideto Minami, Masayoshi Okubo
    • Journal Title

      Colloid Polym. Sci. 286

      Pages: 217-223

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Preparation of divinylbenzene copolymer particles with encapsulated hexadecane for heat storage application2008

    • Author(s)
      Preeyapom, Chaiyasat, Yumiko, Ogino, Toyoko, Suzuki, Hideto, Minami, Masayoshi, Okubo
    • Journal Title

      Colloid Polym. Sci 286 (3)

      Pages: 217-223

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Incorporation of nonionic emulsifier inside methacrylic polymer particles in emulsion polymerization2007

    • Author(s)
      Amorn Chaiyasat, Hiroshi Kobayashi, Masayoshi Okubo
    • Journal Title

      Colloid Polym. Sci., 285

      Pages: 557-562

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Preparation of poly (divinylbenzene) particles with encapsulated hexadecane for heat storage application2007

    • Author(s)
      Yumiko Ogino, Toyoko Suzuki, Masayoshi Okubo
    • Journal Title

      Kobunshi Ronbunshu 64

      Pages: 171-176

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Mechanical properties of cross-linked polymer particles prepared by nitroxide-mediated radical polymerization in aqueous micro-suspension2007

    • Author(s)
      Takuya Tanaka, Toyoko Suzuki, Yuichi Saka, Per B. Zetterlund, Masayoshi Okubo
    • Journal Title

      Polymer 48

      Pages: 3836-3843

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Preparation of multihollow polymer particles by seeded emulsion polymerization using seed particles with incorporated nonionic emulsifier2007

    • Author(s)
      Hiroshi Kobayashi, Emi Miyanaga, Masayoshi Okubo
    • Journal Title

      Langmuir 23

      Pages: 8703-8708

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Influence of hydrophilic-lipophilic balance of nonionic emulsifiers onemulsion copolymerization of styrene and methacrylic acid2007

    • Author(s)
      Masayoshi Okubo, Amorn Chaiyasat, Masahiro Yamada, Toyoko Suzuki, Hiroshi Kobayashi
    • Journal Title

      Colloid Polym. Sci. 285

      Pages: 1755-1761

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Incorporation of nonionic emulsifier inside methacrylic polymer particles in emulsion polymerization2007

    • Author(s)
      Amom, Chaiyasat, Hiroshi, Kobayashi, Masayoshi, Okubo
    • Journal Title

      Colloid Polym. Sci 285 (5)

      Pages: 557-562

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation of poly(divinylbenzene) particles with encapsulated hexadecane for heat storage application2007

    • Author(s)
      Yumiko, Ogino, Toyoko, Suzuki, Masayoshi, Okubo
    • Journal Title

      Kobunshi Ronbunshu 64

      Pages: 171-176

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Mechanical properties of cross-linked polymer particles prepared by nitroxide-mediated radical polymerization in aqueous micro-suspension2007

    • Author(s)
      Takuya, Tanaka, Toyoko, Suzuki, Yuichi, Saka, Per B., Zetterlund, Masayoshi, Okubo
    • Journal Title

      Polymer 48

      Pages: 3836-3843

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation of multihollow polymer particles by seeded emulsion polymerization using seed particles with incorporated nonionic emulsifier2007

    • Author(s)
      Hiroshi, Kobayashi, Emi, Miyanaga, Masayoshi, Okubo
    • Journal Title

      Langmuir 23

      Pages: 8703-8708

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Influence of hydrophilic-lipophilic balance of nonionic emulsifiers on emulsion copolymerization of styrene and methacrylic acid2007

    • Author(s)
      Masayoshi, Okubo, Amom, Chaiyasat, Masahiro, Yamada, Toyoko, Suzuki, Hiroshi, Kobayashi
    • Journal Title

      Colloid Polym. Sci 285 (15)

      Pages: 1755-1761

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation of hollow polymer particles with single hole in the shell by SaPSeP2005

    • Author(s)
      Hideto Minami, Hiroshi Kobayashi, Masayoshi Okubo
    • Journal Title

      Langmuir 21

      Pages: 5655-5658

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Production of cured epoxy resin particles having one hollow by polyaddition reaction2005

    • Author(s)
      Hideto Minami, Masayoshi Okubo, Yoshiteru Oshima
    • Journal Title

      Polymer 46

      Pages: 1051-1056

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Preparation of hollow polymer particles with single hole in the shell by SaPSeP2005

    • Author(s)
      Hideto, Minami, Hiroshi, Kobayashi, Masayoshi, Okubo
    • Journal Title

      Langmuir 21

      Pages: 5655-5658

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Production of cured epoxy resin particles having one hollow by polyaddition reaction2005

    • Author(s)
      Hideto, Minami, Masayoshi, Okubo, Yoshiteru, Oshima
    • Journal Title

      Polymer 46

      Pages: 1051-1056

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Thermal properties of hexadecane encapsulated in cross-linked poly (divinylbenzene) capsule particles with water and/or air domains

    • Author(s)
      Masayoshi Okubo, Preeyaporn Chaiyasat, Toyoko Suzuki, Hide to Minami.
    • Journal Title

      J. Appl. Polym. Sci. (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Preparation of hollow poly (divinyl benzene) particles with multiple holes in the shell by microsuspension polymerization with the SaPSeP method

    • Author(s)
      Yuko Hata, Toyoko Suzuki, Hideto Minami, Masayoshi Okubo
    • Journal Title

      Colloid Polym. Sci. (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Preparation of hollow polystyrene/poly (ethylene glycol dimethacrylate) particles with a single hole in the shell

    • Author(s)
      Mizuki Ito, Yumiko Furukawa, Hideto Minami, Masayoshi Okubo
    • Journal Title

      Colloid Polym. Sci. (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Thermal properties of hexadecane encapsulated in cross-linked poly(divinylbenzene) capsule particles with water and/or air domains

    • Author(s)
      Masayoshi, Okubo, Preeyapom, Chaiyasat, Toyoko, Suzuki, Hideto, Minami
    • Journal Title

      J. Appl. Polym. Sci (submitted)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation of hollow poly (divinyl benzene) particles with multiple holes in the shell by microsuspension polymerization with the SaPSeP method

    • Author(s)
      Yuko, Hata, Toyoko, Suzuki, Hideto, Minami, Masayoshi, Okubo
    • Journal Title

      Colloid Polym. Sci (submitted)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation of hollow polystyrene/poly(ethylene glycol dimethacrylate) particles with a single hole in the shell

    • Author(s)
      Mizuki, Ito, Yumiko, Furukawa, Hideto, Minami, Masayoshi, Okubo
    • Journal Title

      Colloid Polym. Sci (submitted)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Effect of stirring conditions on the incorporation of nonionic emulsifier inside polymer particles prepared by emulsion copolymerization2007

    • Author(s)
      Hiroshi Kobayashi, Maiko Murai, Toyoko Suzuki, Masayoshi Okubo
    • Organizer
      第10回環太平洋高分子国際会議(PPC10)
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      20071200
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Influence of water domain formed in hexadecane core inside cross-linked capsule particle on thermal properties for heat storage application2007

    • Author(s)
      Preeyaporn Chaiyasat, Yumiko Ogino, Toyoko Suzuki, Masayoshi Okubo
    • Organizer
      第10回環太平洋高分子国際会議(PPC10)
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      20071200
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Incorporation behavior of nonionic emulsifiers inside styrene and methacrylic acid copolymer particles prepared by emulsion copolymerization2007

    • Author(s)
      Amorn Chaiyasat, Masahiro Yamada, Hiroshi Kobayashi, Masayoshi Okubo
    • Organizer
      第10回環太平洋高分子国際会議(PPC10)
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      20071200
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Effects of end groups derived from initiator and nonionic emulsifier on formation of multihollow structure inside polystyrene particles by heat treatment2007

    • Author(s)
      Mineho Moritaka, Hiroshi Kobayashi, Eri Takano, Toyoko Suzuki, Masayoshi Okubo
    • Organizer
      第10回環太平洋高分子国際会議(PPC10)
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      20071200
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Effect of stirring conditions on the incorporation of nonionic emulsifier inside polymer particles prepared by emulsion copolymerization2007

    • Author(s)
      Hiroshi, Kobayashi, Maiko, Murai, Toyoko, Suzuki, Masayoshi, Okubo
    • Organizer
      The 10th Pacific Polymer Conference(PPC10)
    • Place of Presentation
      Kobe, Japan
    • Year and Date
      20071200
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Influence of Water Domain Formed in Hexadecane Core inside Cross-linked Capsule Particle on Thermal Properties for Heat Storage Application2007

    • Author(s)
      Preeyapom, Chaiyasat, Yumiko, Ogino, Toyoko, Suzuki, Masayoshi, Okubo
    • Organizer
      The 10th Pacific Polymer Conference(PPC10)
    • Place of Presentation
      Kobe, Japan
    • Year and Date
      20071200
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Incorporation behavior of nonionic emulsifiers inside styrene and methacrylic acid copolymer particles prepared by emulsion copolymerization2007

    • Author(s)
      Amon, Chaiyasat, Masahiro, Yamada, Hiroshi, Kobayashi, Masayoshi, Okubo
    • Organizer
      The 10th Pacific Polymer Conference(PPC10)
    • Place of Presentation
      Kobe, Japan
    • Year and Date
      20071200
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Effects of end groups derived from initiator and nonionic emulsifier on formation of multihollow structure inside polystyrene particles by heat treatment2007

    • Author(s)
      Mineho, Moritaka, Hiroshi, Kobayashi, Eri, Takano, Toyoko, Suzuki, Masayoshi, Okubo
    • Organizer
      The 10th Pacific Polymer Conference(PPC10)
    • Place of Presentation
      Kobe, Japan
    • Year and Date
      20071200
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] 乳化共重合系における撹拌条件がノニオン性乳化剤の吸蔵化現象及び重合機構に与える影響2007

    • Author(s)
      小林 博, 村井 麻衣子, 鈴木 登代子, 大久保 政芳
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      20070900
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Preparation of PDVB-based capsule particles containing hexadecane as heat storage materials by the SaPSeP method2007

    • Author(s)
      Preeyaporn Chaiyasat, Yumiko Ogino, Toyoko Suzuki, Masayoshi Okubo
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      20070900
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Modelling and controlling morphology of composite polymer particles2007

    • Author(s)
      Masayoshi Okubo
    • Organizer
      1st Unilever International Conference on Multi-scale Structures and Dynamics of Complex Systems
    • Place of Presentation
      北京
    • Year and Date
      20070800
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Modelling and controlling morphology of composite polymer particles2007

    • Author(s)
      Masayoshi, Okubo
    • Organizer
      1st Unilever Intemational Conference on Multi-scale Structures and Dynamics of Complex Systems
    • Place of Presentation
      Beijing, China
    • Year and Date
      20070800
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] 開口部を有する中空橋かけ高分子微粒子の合成2007

    • Author(s)
      伊藤 みづき, 古川 裕美子, 南 秀人, 大久保 政芳
    • Organizer
      第53回高分子研究発表会(神戸)
    • Place of Presentation
      兵庫県中央労働センター
    • Year and Date
      20070700
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] マイクロサスペンション重合法による開口部を有する高分子微粒子の合成2007

    • Author(s)
      畠 裕子, 鈴木 登代子, 南 秀人, 大久保 政芳
    • Organizer
      第53回高分子研究発表会(神戸)
    • Place of Presentation
      兵庫県中央労働センター
    • Year and Date
      20070700
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Preparation of cross-linked polymer particles with encapsulated hexadecane for heat storage application2007

    • Author(s)
      Preeyaporn Chaiyasat, Yumiko Ogino, Toyoko Suzuki, Masayoshi Okubo
    • Organizer
      ICAPP2007-The 2nd International Conference on Advances in Petrochemicals and Polymers
    • Place of Presentation
      バンコク
    • Year and Date
      20070600
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Influence of HLB value of nonionic emulsifiers on the distribution of carboxyl groups within styrene-methacrylic acid copolymer particles prepared by emulsion copolymerization2007

    • Author(s)
      Amorn Chaiyasat, Masahiro Yamada, Toyoko Suzuki, Hiroshi Kobayashi, Masayoshi Okubo
    • Organizer
      ICAPP2007-The 2nd International Conference on Advances in Petrochemicals and Polymers
    • Place of Presentation
      バンコク
    • Year and Date
      20070600
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] ノニオン性乳化剤が吸蔵された高分子微粒子の熱処理による中空構造の形成2007

    • Author(s)
      宮永 絵美, 小林 博, 大久保 政芳
    • Organizer
      第45回日本接着学会年次大会発表
    • Place of Presentation
      東京大学
    • Year and Date
      20070600
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] SaPSeP法によるヘキサデカン内包カプセル粒子の作製とその蓄熱物性2007

    • Author(s)
      荻野 由美子, 鈴木 登代子, Preeyapom Chaiyasat, 大久保 政芳
    • Organizer
      第56回高分子学会年次大会
    • Place of Presentation
      京都国際会議場
    • Year and Date
      20070500
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] SaPScP法による開口部を有する単中空高分子微粒子の作製2007

    • Author(s)
      古川 裕美子, 南 秀人, 大久保 政芳
    • Organizer
      第56回高分子学会年次大会
    • Place of Presentation
      京都国際会議場
    • Year and Date
      20070500
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] 乳化剤含有高分子微粒子の熱処理による中空構造の形成2006

    • Author(s)
      宮永 絵美, 小林 博, 大久保 政芳
    • Organizer
      第14回高分子ミクロスフェア討論会
    • Place of Presentation
      繊協ビル8階繊協閣ホール
    • Year and Date
      20061100
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] ノニオン性界面活性剤を用いた中空高分子微粒子の合成における重合温度の影響2006

    • Author(s)
      大久保 政芳, 小林 博, 宮永 絵美, 森高 峰穂
    • Organizer
      第14回高分子ミクロスフェア討論会
    • Place of Presentation
      繊協ビル8階繊協閣ホール
    • Year and Date
      20061100
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] ニトロキシル制御/リビングラジカル共重合によるミクロンサイズの橋架け高分子微粒子の合成と橋架け構造2006

    • Author(s)
      田中 琢也, 鈴木 登代子, 大久保 政芳
    • Organizer
      第14回高分子ミクロスフェア討論会
    • Place of Presentation
      繊協ビル8階繊協閣ホール
    • Year and Date
      20061100
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] 相分離自己組織化(SaPSeP)法を用いた高光散乱TiO_2含有複合中空高分子微粒子の合成2006

    • Author(s)
      南 秀人, 河田 洋嗣, 大久保 政芳
    • Organizer
      第15回ポリマー材料フォーラム
    • Place of Presentation
      千里ライフサイエンスセンター
    • Year and Date
      20061100
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] 相分離自己組織化(SaPSeP)法によるヘキサデカン含有カプセル粒子の合成と蓄熱材への応用2006

    • Author(s)
      荻野 由美子, 鈴木 登代子, 大久保 政芳
    • Organizer
      第15回ポリマー材料フォーラム
    • Place of Presentation
      千里ライフサイエンスセンター
    • Year and Date
      20061100
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] 相分離自己組織化(SaPSeP)法を用いたマイクロサスペンション重合による単中空高分子微粒子の合成2006

    • Author(s)
      古川 裕美子,南 秀人, 大久保 政芳
    • Organizer
      第15回ポリマー材料フォーラム
    • Place of Presentation
      千里ライフサイエンスセンター
    • Year and Date
      20061100
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Preparation of functional hollow polymer particles2006

    • Author(s)
      Hideto Minami
    • Organizer
      Kobe Conference on Development of Novel Functional Materials and Production Processes with Reduced Environmental Impact
    • Place of Presentation
      神戸大学
    • Year and Date
      20061000
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] 中空微粒子創製法とその応用2006

    • Author(s)
      南 秀人
    • Organizer
      第59回コロイドおよび界面化学討論会
    • Place of Presentation
      北海道大学
    • Year and Date
      20060900
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Preparation of P (DVB-BA) capsules particles containing hexadecane as heat storage materials by the SaPSeP method2006

    • Author(s)
      Preeyaporn Chaiyasat, Yumiko Ogino, Toyoko Suzuki, Masayoshi Okubo
    • Organizer
      第52回高分子研究発表会(神戸)
    • Place of Presentation
      兵庫県中央労働センター
    • Year and Date
      20060700
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] ノニオン性乳化剤を用いた乳化重合による高分子微粒子の合成2006

    • Author(s)
      森高 峰穂, 小林 博, 宮永 絵美, 大久保 政芳
    • Organizer
      第52回高分子研究発表会(神戸)
    • Place of Presentation
      兵庫県中央労働センター
    • Year and Date
      20060700
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] 水媒体不均-系制御/リビングラジカル重合による橋かけ高分子微粒子の合成2006

    • Author(s)
      田中 琢也, 鈴木 登代子, 坂 祐一, 大久保 政芳
    • Organizer
      第52回高分子研究発表会(神戸)
    • Place of Presentation
      兵庫県中央労働センター
    • Year and Date
      20060700
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Polyaddition reaction of epoxy resin with the SaPSeP method for the preparation of micron-sized, cross-linked capsule particle2006

    • Author(s)
      Hideto Minami, Hiroyuki Kanamori, Masayoshi Okubo
    • Organizer
      Asia Polymer Symposium (APOSYM/2006)
    • Place of Presentation
      東国大学校,ソウル,韓国
    • Year and Date
      20060600
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Incorporation of nonionic emulsifier inside polystyrene particles during emulsion polymerization2006

    • Author(s)
      Hiroshi Kobayashi, Masayoshi Okubo
    • Organizer
      Asia Polymer Symposium (APOSYM/2006)
    • Place of Presentation
      東国大学校,ソウル,韓国
    • Year and Date
      20060600
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Polyaddition reaction of epoxy resin with the SapSep method for the preparation of micron-sized, cross-linked capsule particle2006

    • Author(s)
      Hideto, Minami, Hiroyuki, Kanamori, Masayoshi, Okubo
    • Organizer
      Asia Polymer Symposium(APOSYM)
    • Place of Presentation
      Seoul, Korea
    • Year and Date
      20060600
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Incorporation of nonionic emulsifier inside polystyrene particles during emulsion polymerization2006

    • Author(s)
      Hiroshi, Kobayashi, Masayoshi, Okubo
    • Organizer
      Asia Polymer Symposium(APOSYM)
    • Place of Presentation
      Seoul, Korea
    • Year and Date
      20060600
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Preparation of cross-linked polymer particles with encapsulated hexadecane for heat storage application2006

    • Author(s)
      Preeyapom, Chaiyasat, Yumiko, Ogino, Toyoko, Suzuki, Masayoshi, Okubo
    • Organizer
      ICAPP2007-The 2nd Intemational Conference on Advances in Petrochemicals and Polymers
    • Place of Presentation
      Bangkok, Thailand
    • Year and Date
      20060600
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Influence of HLB value of nonionic emulsifiers on the distribution of carboxyl groups within styrene-methacrylic acid copolymer particles prepared by emulsion copolymerization2006

    • Author(s)
      Amom, Chaiyasat, Masahiro, Yamada, Toyoko, Suzuki, Hiroshi, Kobayashi, Masayoshi, Okubo
    • Organizer
      ICAPP2007-The 2nd Intemational Conference on Advances in Petrochemicals and Polymers
    • Place of Presentation
      Bangkok, Thailand
    • Year and Date
      20060600
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Incorporation of nonionic emulsifier inside methacrylic polymer particles in emulsion polymerization2006

    • Author(s)
      Amom Chaiyasat, Hiroshi Kobayashi, Masayoshi Okubo
    • Organizer
      第55回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      20060500
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] SaPSeP法を用いた重付加反応によるマイクロカプセルの合成とその応用2005

    • Author(s)
      南 透人, 大久保 政芳, 金森 博之
    • Organizer
      第54回高分子学会討論会
    • Place of Presentation
      山形大学
    • Year and Date
      20050900
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Incorporation behavior of nonionic emulsifier inside polymer particles in the process of emulsion polymerization2005

    • Author(s)
      Hiroshi Kobayashi, Yoshiteru Oshima, Masayoshi Okubo
    • Organizer
      2005 Gordon Research conference
    • Place of Presentation
      Tilton school
    • Year and Date
      20050700
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] SaPSeP法によるパラフィン含有カプセル粒子の合成2005

    • Author(s)
      荻野由美子, 鈴木 登代子, 大久保 政芳
    • Organizer
      第51回高分子研究発表会(神戸)
    • Place of Presentation
      兵庫県中央労働センター
    • Year and Date
      20050700
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] SaPSeP法による単中空高分子微粒子の合成2005

    • Author(s)
      古川裕美子, 南 秀人, 大久保 政芳
    • Organizer
      第51回高分子研究発表会(神戸)
    • Place of Presentation
      兵庫県中央労働センター
    • Year and Date
      20050700
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] 吸蔵化乳化剤を利用した中空高分子微粒子の合成2005

    • Author(s)
      宮永 絵差, 小林 博, 大久保 政芳
    • Organizer
      第51回高分子研究発表会(神戸)
    • Place of Presentation
      兵庫県中央労働センター
    • Year and Date
      20050700
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Incorporation behavior of nonionic emulsifier inside polymer particles in the process of emulsion polymerization2005

    • Author(s)
      Hiroshi, Kobayashi, Yoshiteru, Oshima, Masayoshi, Okubo
    • Organizer
      2005 Gordon Research conference
    • Place of Presentation
      Tilton, NH, USA
    • Year and Date
      20050700
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] SaPSeP法を用いた重付加反応による硬化剤内包型マイクロカプセルの調整2005

    • Author(s)
      金森 博之, 南 秀人, 大久保 政芳
    • Organizer
      第43回日本接着学会年次大会
    • Place of Presentation
      関西大学
    • Year and Date
      20050600
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] スチレンーメタクリル酸乳化共重合過程におけるノニオン性界面活性剤の高分子微粒子中への吸蔵化機構2005

    • Author(s)
      大島 由照, 小林 博, 大久保 政芳
    • Organizer
      第54回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      20050500
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] 懸濁重合法による高光散乱性高分子微粒子の合成2005

    • Author(s)
      大久保 政芳, 南 秀人, 河田 洋嗣
    • Organizer
      第54回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      20050500
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] 開口部を有する中空高分子微粒子の合成2005

    • Author(s)
      南 秀人, 小林 博, 古川 裕美子, 大久保 政芳
    • Organizer
      第54回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      20050500
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Preparation of micron-sized, cured epoxy resin capsules by polyaddition reaction using the SaPSeP method2005

    • Author(s)
      Hideto Minami, Hiroyuki Kanamori, Masayoshi Okubo
    • Organizer
      第2回ミクロスフェア国際討論会
    • Place of Presentation
      福井ワシントンホテル
    • Year and Date
      20050300
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Preparation of micron-sized, cured epoxy resin capsules by polyaddition reaction using the SapSep method2005

    • Author(s)
      Hideto, Minami, Hiroyuki, Kanamori, Masayoshi, Okubo
    • Organizer
      2nd Intemational Symposium on Polymeric Microspheres
    • Place of Presentation
      Fukui, Japan
    • Year and Date
      20050300
    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2010-02-04  

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